全文获取类型
收费全文 | 489篇 |
免费 | 10篇 |
国内免费 | 4篇 |
专业分类
化学 | 323篇 |
晶体学 | 2篇 |
力学 | 7篇 |
数学 | 52篇 |
物理学 | 119篇 |
出版年
2018年 | 5篇 |
2016年 | 7篇 |
2015年 | 10篇 |
2014年 | 7篇 |
2013年 | 8篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 10篇 |
2009年 | 8篇 |
2008年 | 12篇 |
2007年 | 12篇 |
2006年 | 11篇 |
2005年 | 11篇 |
2004年 | 19篇 |
2003年 | 10篇 |
2002年 | 14篇 |
2001年 | 10篇 |
2000年 | 13篇 |
1999年 | 6篇 |
1998年 | 7篇 |
1997年 | 11篇 |
1996年 | 10篇 |
1995年 | 18篇 |
1994年 | 7篇 |
1993年 | 14篇 |
1992年 | 6篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 5篇 |
1985年 | 12篇 |
1984年 | 11篇 |
1983年 | 12篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 13篇 |
1977年 | 9篇 |
1976年 | 14篇 |
1975年 | 10篇 |
1974年 | 13篇 |
1973年 | 14篇 |
1972年 | 9篇 |
1971年 | 9篇 |
1970年 | 13篇 |
1969年 | 10篇 |
1968年 | 10篇 |
1966年 | 5篇 |
排序方式: 共有503条查询结果,搜索用时 15 毫秒
1.
2.
Since the early demonstrations of our concept of pulsed microwave catalysis in chemistry, we have witnessed the coming of age of the technique as an enabling technology in the industrial world, despite the inadequate understanding of the basic mechanisms of how microwaves interact with metallic surface sites and the subsequent energy transfer. We shall present here some very recent developments of the microwave-induced acoustic technique and its applications to a better understanding of the basic surface heating and energy transfer phenomena in pulsed microwave catalytic systems. 相似文献
3.
4.
Bilevich K. A. Bubnov N. N. Ioffe N. T. Kalinkin M. I. Okhlobystin O. Yu. Petrovskii P. V. 《Russian Chemical Bulletin》1971,20(8):1707-1708
Russian Chemical Bulletin - 相似文献
5.
A. V. Kalinin Yu. A. Strelenko É. T. Apasov S. L. Ioffe 《Russian Chemical Bulletin》1991,40(9):1789-1795
Functionally substituted N-nitrohydrazines were studied by heteronuclear NMR. It was shown that all the investigated products from nitration of the trimethylsilyl derivatives of functionally substituted hydrazines contain the N-NO2 fragment. The chemical shift of the nitrogen atoms of the hydrazine fragment in the15N NMR spectra and the
spin-spin coupling constants were used as the main tests for structural identification. It was established that the number of recordable conformers decreases in the transition from the trimethylsilyl phenylhydrazine derivatives to the nitrohydrazines as a result of the conformational flexibility of the N(NO2)CO fragment.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2024–2031, September, 1991. 相似文献
6.
Smirnov O. Yu. Churakov A. M. Tyurin A. Yu. Strelenko Yu. A. Ioffe S. L. Tartakovsky V. A. 《Russian Chemical Bulletin》2002,51(10):1849-1856
Nucleophilic substitution in nitro- and bromobenzo-1,2,3,4-tetrazine 1,3-dioxides (BTDOs) was studied. In most cases, the bromo and nitro groups are replaced by methylamino, dimethylamino, azido, and methoxy groups without opening of the tetrazine ring. It was illustrated with the reactions of dibromo-BTDOs with sodium methoxide that the reactivity of positions 5 to 8 in their benzene ring as regards nucleophilic substitution changes in the following order: 6 > 8 > 7 > 5. The structures of the BTDOs obtained were confirmed by 1H, 13C, and 14N NMR data. 相似文献
7.
A. M. Churakov A. Yu. Tyurin E. L. Goncharova S. L. Ioffe Yu. A. Strelenko V. A. Tartakovsky 《Russian Chemical Bulletin》1995,44(5):890-896
The addition of 1-aryl-2-bromodiazene 1-oxides to olefins yields 1-aryl-2-(2-bromoalkyl)diazene 1-oxides (4). A radical mechanism of the reaction has been suggested. Compounds4 decompose to give bromohydrazones of formaldehyde and aldehydes. The structural factors that affect the rate of this process are discussed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 917–923, May, 1995.The work was carried out in the Scientific Educational Center of the Institute of Organic Chemistry of the RAS with financial support of the Russian Foundation for Basic Research (Project No. 93-03-18461). 相似文献
8.
The corresponding 1-alkoxyaziridines were synthesized by oxidation of methoxy-, ethoxy-, and isopropoxyamines with lead tetraacetate in the presence of 2-methyl-2-butene and 2,3-dimethyl-2-butene. The PMR spectra of the oxidation products were investigated, and the high pyramidal stability of nitrogen in these compounds was confirmed. The individual invertomers 1-alkoxy-2,2,3-trimethylaziridines were isolated by preparative gas-liquid chromatography.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1514–1519, November, 1972.The authors thank A. A. Potekhin, I. N. Somin, R. R. Kostikov, M. I. Komendantov, and M. A. Kuznetsov for their useful discussions. 相似文献
9.
10.