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Pavla Fialová Inmaculada Robina Petr Sedmera Lucie Petrásková-Hušáková 《Tetrahedron letters》2005,46(50):8715-8718
Glycosyl azides are new efficient donors for glycosidases. Their high water solubility facilitates transglycosylations with comparable or better yields than common O-glycosides. The azido group totally changes the β-GalNAc-ase/β-GlcNAc-ase ratio in β-N-acetylhexosaminidases (from the usual 0.3-1.0 to <0.01), contrary to all known aglycons. 相似文献
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B. Savo P. Romano A. Nigro R. Di Leo 《Physica C: Superconductivity and its Applications》2002,370(4):275-280
The flat voltage noise component of current biased, high-transparency Nb/AlOx/Nb superconducting tunnel junctions has been investigated at frequencies up to 70 kHz. Several aspects of the analyzed phenomena suggest the presence of current noise effects induced by the discreteness of the charge carriers. At subgap voltages, where excess currents occur, a behavior coherent with a multiple Andreev reflection-assisted transport through the tunnel barrier has been found. However, the measured charge values exceed any theoretical prediction. 相似文献
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An approach called Schramm–Loewner evolution (SLE) provides a new method for dealing with a wide variety of scale-invariant problems in two dimensions. This approach is based upon an older method called Loewner Evolution (LE), which connects analytic and geometrical constructions in the complex plane. In this paper, the bases of LE and SLE are described and some simple applications are discussed in relatively non-technical form. A bibliography of the subject is presented. 相似文献
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J. A. Murillo J. M. Lemus L. F. García 《Analytical and bioanalytical chemistry》1994,349(10-11):761-767
First-derivative spectrophotometric method with a “zero-crossing” technique of measurement has been used for the quantification of two-components mixtures of cephalothin and clavulanic acid. As the absorption bands of these drugs overlap, both direct and derivative spectrophotometric methods have been investigated and evaluated by a rigorous statistical analysis of the experimental data. The first-derivative spectrophotometric method was found to be more accurate, direct and reproducible. Beer's law was valid over the concentration range 2.0–28.0 mg/l for both compounds. The detection limits of cephalothin and clavulanic acid, at a 0.05 level of significance, were calculated to be 0.13 and 0.15 mg/l. The method was applied for determining these antibiotics in mixtures, some of them containing inject-able dosage forms of cephalothin, and so to determine both compounds in saline and glucosed physiological sera. 相似文献
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2,6- and 2,7-Dimethylanthracenes were reduced seriatim with lithium in liquid ammonia and lithium in methylamine to their 1,4,5,8,9,10-hexahydro derivatives. Two-fold epoxidation of these tetraenes provided the cis and trans diepoxides resulting from electrophilic attack at the inner double bonds. Trans diepoxide 1 has the very unusual characteristic of lacking a σ plane of symmetry but possessing an inversion center. As a consequence, the 1H NMR spectrum of C1-symmetric 1 is simplified relative to those of its isomers 5, 9, and 10. 相似文献
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E. Alfinito M. Leo R. A. Leo M. Palese G. Soliani 《Letters in Mathematical Physics》1994,32(3):241-248
The Estabrook-Wahlquist prolongation method is applied to the (compact and noncompact) continuous isotropic Heisenberg model in 1 + 1 dimensions. Using a special realization (an algebra of the Kac-Moody type) of the arising incomplete prolongation Lie algebra, a whole family of nonlinear field equations containing the original Heisenberg system is generated. 相似文献
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