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Metal‐Triflate‐Catalyzed Synthesis of Polycyclic Tertiary Alcohols by Cyclization of γ‐Allenic Ketones
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Ilhem Diaf Dr. Gilles Lemière Dr. Elisabet Duñach 《Angewandte Chemie (International ed. in English)》2014,53(16):4177-4180
It has been established that bismuth(III) triflate catalyzes the cyclization of γ‐allenic ketones under mild reaction conditions. This reaction allows the selective formation of polycyclic tertiary alcohols from cyclic ketone derivatives. The resulting dienols can engage in stereoselective cycloadditions to efficiently afford complex polycyclic systems. 相似文献
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Bensaid Ilhem Atik Bekkara Fawzia El Haci Imad Abdelhamid Belarbi Karima Beddou Fawzia Bekhechi Chahrazed 《Natural product research》2018,32(4):481-485
In an extensive search for bioactive compounds from plant sources, the quantitative and qualitative characterisation of the compounds present in Cynoglossum cheirifolium extracts was studied. Total phenolic and flavonoid contents were determined by spectrophotometric techniques. In vitro antioxidant and radical scavenging profiling was determined through DPPH? scavenging activity and Ferric reducing antioxidant power (FRAP). Our study showed that leaves produce more phenolic compounds, followed by flowering aerial part. The butanolic fraction obtained from leaves extract exhibited the highest total phenolics (78.65 ± 3.58 mg GAE/g DW) and flavonoids (22.15 ± 4.66 mg CE/g DW). In contrast, this fraction displayed the highest DPPH? scavenging ability with IC50 values of 0.06 ± 0.003 mg/mL. The RP-HPLC-PDA analysis of phenolic compounds from leaves of C. cheirifolium lets to identify: rosmarinic acid, ferulic acid, caffeic acid, p-coumaric acid, syringic acid, sinapic acid and rutin. The obtained results indicate that this plant represent a valuable source of natural antioxidants. 相似文献
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Background
In Drosophila, cuticular sex pheromones are long-chain unsaturated hydrocarbons synthesized from fatty acid precursors in epidermal cells called oenocytes. The species D. melanogaster shows sex pheromone dimorphism, with high levels of monoenes in males, and of dienes in females. Some biosynthesis enzymes are expressed both in fat body and oenocytes, rendering it difficult to estimate the exact role of oenocytes and of the transport of fatty acids from fat body to oenocytes in pheromone elaboration. To address this question, we RNAi silenced two main genes of the biosynthesis pathway, desat1 and desatF, in the oenocytes of D. melanogaster, without modifying their fat body expression. 相似文献6.
Hajer Chakroun Galai Ilhem Rassas Philippe Namour Anne Bonhomme Gaetan Raimondi Salma Besbes Hentati Nicole Jaffrezic‐Renault 《Electroanalysis》2020,32(4):732-740
In this contribution, a new concept of voltammetric catechol biosensor, based on the encapsulation of laccase (LAC) in a chitosan+lambda‐carrageenan (CHIT+CAR) polyelectrolyte complex (PEC) employing a simple coacervation process is presented. Chitosan (CHIT) was prepared from α‐chitin extracted from shrimp shells and lambda‐carrageenan (CAR) was extracted from red algae, both polysaccharides and PEC being characterized using FTIR spectrometry and electrochemistry. Cyclic voltammetry was utilized to determine the analytical features of the laccase (LAC) biosensor for catechol detection. The linear range was from 10?20 M to 10?14 M with a sensitivity of 1.55 mA/p[catechol] and a limit of detection of 3×10?21 M.The laccase biosensor exhibits good repeatability (RSD 2.38 %) and stability (four weeks). The developed biosensor was tested by applying it to the evaluation of the total polyphenolic content in natural oil samples. 相似文献
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ABSTRACTIn this paper, we consider a nonlinear wave equation with damping and source terms of variable-exponent types. First, we use the stable-set method to prove a global result. Then, by applying an integral inequality due to Komornik, we obtain the stability result. 相似文献
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Wided Mejri Ilhem Ben Salah Mohamed Mouldi Tlili 《Crystal Research and Technology》2015,50(3):236-243
The present work was carried out to investigate separately the effect of Fe2+ and Fe3+ on the precipitation kinetics and the microstructure of CaCO3. For this an experimental procedure was proposed. Precipitation tests were made by using the dissolved‐CO2 degassing method. Both air and nitrogen were employed to strip the CO2 from a Ca(HCO3)2 solution initially rich in this gas. At anoxic medium, it was shown that iron (II) prolongs the nucleation step and decelerates the crystalline growth rate. X‐ray diffraction analysis shows that its presence inhibits calcite and promotes aragonite variety. By using air, the reaction medium is rich in oxygen and iron (II) is rapidly oxidized. Seeing the higher solution pH (> 6.5), iron hydroxide forms before the onset of CaCO3 precipitation and plays a role of seed permitting to initiate CaCO3 nucleation. So, contrary to the observed effect of iron (II), the presence of iron (III) accelerates the precipitation rate of CaCO3. As for iron (II), iron (III) inhibits calcite formation but favored the vaterite variety instead of the aragonite one. 相似文献