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Collocation Methods for Weakly Singular Second-kind Volterra Integral Equations with Non-smooth Solution 总被引:2,自引:0,他引:2
Collocation type methods are studied for the numerical solutionof the weakly singular Volterra integral equation of the secondkind:
where the solution (t) is assumedto have the form f(t) = x(t)+r?(t), x and being sufficientlysmooth. The solution is approximated near zero by a linear combinationof powers of t?, and away from zero by the usual polynomialrepresentation. Convergence is proved and many numerical experimentsare carried out with examples from the literature. A comparisonis made with a method of Brunner & Norsett (1981), originallydeveloped for (1) with a smooth solution. Special attentionis paid to the numerical approximation of the so-called momentintegrals which emerge in the collocation scheme. 相似文献
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无机酸洗脱对胜利褐煤微晶结构及其自燃倾向性的影响 《燃料化学学报》2016,44(9):1059-1065
利用XRD、Raman、XPS和FT-IR表征技术,研究无机酸洗脱(HCl、H2SO4、HCl-HF)处理的胜利褐煤微晶结构的变化,采用自行设计的表面吸附仪-GC联用装置,对样品进行不同温度的低温脉冲氧化实验,考察了煤样在不同温度下氧吸附量的变化规律,通过低温脉冲氧吸附规律与TG/DTG和固定床燃烧实验关联,考察了煤样的自燃倾向。结果表明,无机酸洗脱对矿物质的脱除使得煤结构的有序度增加,石墨化程度提高,无机酸洗脱煤样与原煤相比吸氧量明显下降。随着吸附温度的升高,各煤样吸氧量明显增加,且随着脱除矿物质程度的增加,吸氧量呈减小的趋势,导致自燃倾向降低。 相似文献
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Ignatyuk VV 《The Journal of chemical physics》2012,136(18):184104
A temperature behavior of the frustrated translational mode (T-mode) of a light particle, coupled by different regimes of ohmicity to the surface, is studied within a formalism of the generalized diffusion coefficients. The memory effects of the adsorbate motion are considered to be the main reason of the T-mode origin. Numerical calculations yield a thermally induced shift and broadening of the T-mode, which is found to be linear in temperature for Ohmic and super-Ohmic systems and nonlinear for strongly sub-Ohmic ones. We obtain analytical expressions for the T-mode shift and width at weak coupling for the systems with integer "ohmicity" indexes n = 0÷2 in zero temperature and high temperature limits. We provide an explanation of the experimentally observed blue- or redshifts of the T-mode on the basis of a comparative analysis of two typical times of the system evolution: a time of decay of the "velocity-velocity" autocorrelation function, and a correlation time of the thermal bath random forces. A relation of the T-mode to the multiple jumps of the adsorbate is discussed, and generalization of conditions of the multiple hopping to the case of quantum surface diffusion is performed. 相似文献
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Trknyi F. Hermanne A. Ignatyuk A. V. Takcs S. Capote R. 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(3):1163-1206
Journal of Radioanalytical and Nuclear Chemistry - The IAEA Nuclear Data Section has coordinated several actions to setup and improve a database for recommended cross sections and nuclear decay... 相似文献
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The development of a scheme to treat two-dimensional electromagneticscattering by electrically large, perfectly conducting bodiesis described. It incorporates the effects of surface curvatureand non-local phenomena and has the potential to provide thebasis for a general technique yielding more accurate predictionsthan the widely used physical optics method. 相似文献
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The structures of copper poly[3,3′-dithiobis(2,4-pentanedionate)], obtained from 3,3′-dithiobis(2,4-pentanedione) and copper
chloride, and chromium oligo-3,3′-dithiobis(2,4-pentanedionate), obtained by treating chromium tris(3-chlorosulfenyl-2,4-pentanedionate)
with butyl magnesium bromide, are studied by comparing the calculated and experimental X-ray scattering functions. Optimal
models for the copper and chromium polychelate structures are suggested. The structure of the macromolecular chain depends
on the mutual arrangement of metallochelate nuclei, which is similar to that in a crystal matrix of a monomer, rather than
on the stereochemistry of the disulfide bond.
Far-East State University, Vladivostok. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 1, pp. 152–156, January–February, 1995.
Translated by I. Izvekova 相似文献