排序方式: 共有47条查询结果,搜索用时 15 毫秒
1.
Yu. F. Zuev A. B. Mirgorodskaya L. A. Kudryavtseva B. Z. Idiyatullin R. N. Khamidullin 《Russian Journal of General Chemistry》2004,74(7):1051-1056
The structure of water/cetyltrimethylammonium bromide/n-butanol/hexane microemulsions was studied by conductometry, viscometry, and Fourier transform 1H NMR spectroscopy with pulse magnetic field gradient. The regions of phase inversion from inverse micelles in hexane through a bicontinual structure to a dispersion of normal micelles in water were determined. The influence of the structure of the microemulsions on the rate of hydrolysis of carboxylic acid p-nitrophenyl esters was analyzed. The hydrolysis rate constants considerably increase in going from inverse to normal microemulsions. 相似文献
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Idiyatullin D Daragan VA Mayo KH 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,171(1):4-9
Here, we report a method to simultaneously determine CH2 cross-correlation spectral densities and T1 relaxation times in the laboratory and rotating frames. To accomplish this, we have employed an indirect approach that is based on measurement of differences in relaxation rates acquired with and without cross-correlation terms. The new method, which can be employed using multidimensional NMR and standard relaxation pulse sequences, is validated experimentally by investigation of a selectively 13C-enriched hexadecapeptide and the uniformly 13C-enriched immunoglobulin-binding domain of streptococcal protein G (GB1). Use of this approach makes determination of CH2 cross-correlation spectral densities in uniformly 13C-enriched proteins now routine and provides novel information concerning their internal motions. 相似文献
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Yu. F. Zuev N. N. Vylegzhanina B. Z. Idiyatullin A. B. Mirgorodskaya 《Applied magnetic resonance》2003,25(1):65-77
The effect of solubilized dodecylamine (DDA) on the structure of the cetylpyridinium bromide-n-butanol-hexane-water microemulsions has been studied by the Fourier-transform pulsed-gradient spin-echo1H nuclear magnetic resonance and the electron spin resonance spin label method. The sample compositions were chosen to examine three different microemulsion structures: oil-in-water, water-in-oil and bicontinuous. In all systems the DDA molecules are shown to be incorporated into the oil-water interface, resulting in essential changes in the microemulsion structure. In the micellar systems the DDA emergence in the interface causes an increase of the micelle size and a redistribution of butanol and water between micelle and bulk phases. In the oil-in-water microemulsions of amine-containing systems the quantity of micellized butanol and water decreases. In the water-in-oil microemulsions the introduction of DDA leads to an increase of butanol and water involved in the micelle formation. The redistribution of butanol and water between polar and organic phases in the microemulsions would be expected to cause changes in the bicontinuous structure. 相似文献
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The properties of passive Q-switched short-cavity dye lasers (SCDL) and passive Q-switched distributed-feedback dye lasers (DFDL) are investigated theoretically by using rate-equation models. The calculations, in agreement with experimental results, predict a significant decrease of the pulse energy fluctuation and the pulse duration of both the SCDL and DFDL, when passive Q-switching is used. 相似文献
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L. R. Bogdanova O. I. Gnezdilov B. Z. Idiyatullin R. Kh. Kurbanov Yu. F. Zuev O. G. Us’yarov 《Colloid Journal》2012,74(1):1-6
NMR self-diffusion, tensiometry, and measurement of solubilization capacity are employed to comparatively study micellization
in aqueous solutions of a facial amphiphilic compound, sodium deoxycholate (NaDC), and a conventional micelle-forming sodium
dodecyl sulfate. Based on the two-state model, which is commonly used to analyze the data of NMR diffusometry, a method is
proposed for determining variable sizes of NaDC micelles. It is shown that, in the concentration range from the critical micelle
concentration to 0.1 M, the sizes of NaDC micelles monotonically increase. At comparable sizes of molecules of the examined
surfactants, NaDC micelles are characterized by noticeably smaller aggregation numbers and solubilization capacity than sodium
dodecyl sulfate due to the rigid structure of NaDC molecules, their facial amphiphilicity, and a low value of hydrophilic-lipophilic
balance. 相似文献
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The possibilities of the Fourier transform pulsed-gradient spin-echo1H nuclear magnetic resonance approach in the structural study of surfactant-based microheterogeneous liquid systems are examined by the example of cetyltrimethylammonium bromide microemulsions under a large scale alterations in the water-to-oil ratio. The advantages of this approach to study the structure of microcompartmentalized systems with different phase manifestations are shown. The obtained structural information is used to analyze the microenvironment of the reacting species and the kinetic data on the basic hydrolysis of carbon acids esters in the microemulsion reaction medium. 相似文献
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We study the functionb(n, d), the maximal number of atoms defined byn d-dimensional boxes, i.e. parallelopipeds in thed-dimensional Euclidean space with sides parallel to the coordinate axes.
We characterize extremal interval families definingb(n, 1)=2n-1 atoms and we show thatb(n, 2)=2n
2-6n+7.
We prove that for everyd,
exists and
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Moreover, we obtainb*(3)=8/9. 相似文献
10.
Mayo KH Daragan VA Idiyatullin D Nesmelova I 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,146(1):188-195
NMR relaxation-derived spectral densities provide information on molecular and internal motions occurring on the picosecond to nanosecond time scales. Using (13)C and (15)N NMR relaxation parameters [T(1), T(2), and NOE] acquired at four Larmor frequencies (for (13)C: 62.5, 125, 150, and 200 MHz), spectral densities J(0), J(omega(C)), J(omega(H)), J(omega(H) + omega(C)), J(omega(H) - omega(C)), J(omega(N)), J(omega(H) + omega(N)), and J(omega(H) - omega(N)) were derived as a function of frequency for (15)NH, (13)C(alpha)H, and (13)C(beta)H(3) groups of an alanine residue in an alpha-helix-forming peptide. This extensive relaxation data set has allowed derivation of highly defined (13)C and (15)N spectral density maps. Using Monte Carlo minimization, these maps were fit to a spectral density function of three Lorentzian terms having six motional parameters: tau(0), tau(1), tau(2), c(0), c(1), and c(2), where tau(0), tau(1) and tau(2) are correlation times for overall tumbling and for slower and faster internal motions, and c(0), c(1), and c(2) are their weighting coefficients. Analysis of the high-frequency portion of these maps was particularly informative, especially when deriving motional parameters of the side-chain methyl group for which the order parameter is very small and overall tumbling motions do not dominate the spectral density function. Overall correlation times, tau(0), are found to be in nanosecond range, consistent with values determined using the Lipari-Szabo model-free approach. Internal motional correlation times range from picoseconds for methyl group rotation to nanoseconds for backbone N-H, C(alpha)-H, and C(alpha)-C(beta) bond motions. General application of this approach will allow greater insight into the internal motions in peptides and proteins. 相似文献