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Yanilkin V. V. Strunskaya E. I. Nastapova N. V. Iaksimyuk N. I. Bredikhina Z. A. Sharafutdinova D. R. Bredikhin A. A. 《Russian Chemical Bulletin》2003,52(4):923-928
Catalytic electroreduction of several substituted gem-dihalocyclopropanes was studied in the presence of metal salen-complexes by polarography, cyclic voltammetry, and preparative electrolysis. Monohalocyclopropanes (54—59%) and the corresponding allene (5—9%) were the main reduction products. The reaction rate constants were determined. The inner-sphere electron transfer was shown to occur under these conditions. 相似文献
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