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Homo-apioneplanocin A was efficiently synthesized via stereoselective hydroxymethylation, regio- and chemoselective hydroboration, and chemoselective oxidation as key steps from d-ribose. 相似文献
3.
Sang Hyun Kwon Yoshio Okamoto Chiyo Yamamoto Wonjo Cheong Myeonghee Moon Jung Hag Park 《Analytical sciences》2006,22(12):1525-1529
Porous zirconia particles are very robust material and have received considerable attention as a stationary phase support for HPLC. We prepared cellulose dimethylphenylcarbamate-bonded carbon-clad zirconia (CDMPCCZ) as a chiral stationary phase (CSP) for separation of enantiomers of a set of 14 racemic compounds in normal phase (NP) and reversed-phase (RP) liquid chromatography. Retention and enantioselectivity on CDMPCCZ were compared to those on CDMPC-coated zirconia (CDMPCZ) to see how the change in immobilization method of the chiral selector affects the retention and chiral selectivity. In NPLC, retention was longer and the number of resolved racemates was smaller on CDMPCCZ than on CDMPCZ. However, chiral selectivity factors for some resolved racemates were better on CDMPCCZ than on CDMPCZ. The longer retention on CDMPCCZ is likely due to strong, non-chiral discriminating interactions with the carbon layer on CDMPCZ. In RPLC only two racemates were resolved on CDMPCCZ, but retention times were shorter than, and resolutions were comparable to, those in NPLC, indicating a potential for improving chromatographic performance of the CDMPCCZ column in RPLC with optimized column preparation and separation conditions. 相似文献
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Al2O3 incorporated HfO2 films grown by atomic layer deposition (ALD) were investigated by high-resolution X-ray photoelectron spectroscopy (HRXPS). The core level energy state of a 15 Å thick film showed a shift to higher binding energy, as the result of a silicate formation and Al2O3 incorporation. The incorporation of Al2O3 into the HfO2 film had no effect on silicate formation at the interface between the film and Si, while the ionic bonding characteristics and hybridization effects were enhanced compared to a pure HfO2 film. The dissociation of the film in an ultrahigh vacuum (UHV) is effectively suppressed compared to a pure HfO2 film, indicating an enhanced thermal stability of Hf-Al-O. Any dissociated Al2O3 on the film surface was completely removed into the vacuum by vacuum annealing treatment over 850 °C, while HfO2 contributed to Hf silicide formation on the film surface. 相似文献
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We obtain various results involving the centroid branches of randomly chosen trees from simply generated families. 相似文献
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Kim HJ Kim W Lough AJ Kim BM Chin J 《Journal of the American Chemical Society》2005,127(48):16776-16777
A cobalt(III)-salen complex (3) with an axial substituent on the diamine backbone has been synthesized. Crystal structure reveals that the axial substituent (p-nitrophenyl group) is positioned in close proximity to the metal binding site. The stereoselectivity of the cobalt complex for binding amino alcohols increases with increasing steric bulk of the amino alcohol from alaninol (2.9) to valinol (6.2) and t-leucinol (36.0). 相似文献
10.
In an attempt to elucidate the underlying mechanisms for iron toxicity in plants, the combined effects of iron overload and light intensities on the photosynthetic capacity of leaves were particularly focussed upon in this study, using mung bean seedlings grown under varied conditions regarding the supply of light and iron. The seedlings, when supplied with excess iron (up to 1.0 m M ) and low light (40 W/m2 ), did not suffer any loss of photosynthesis; further, the typical symptoms of iron toxicity, as shown in the leaves grown in sunlight at ca 450 W/m2 on an average, were not seen in those. Nonetheless, excess iron supply resulted in a marked increase in photosensitivity of the low light-adapted seedlings. A large portion of iron accumulated in chloroplasts by the supply of excess iron was found to be incorporated into thylakoids as nonheme iron (NHI), which acts as a potent sensitizer, photogenerating singlet oxygen (1 O2 ). The generation rate of 1 O2 from thylakoids linearly increased with increasing content of NHI; this was in parallel with the NHI content dependence of photoinactivation rates of photosynthetic electron transport and key enzymes of the Calvin cycle in chloroplasts. The results suggest that Fe-dependent photosensitization reactions, occurring via the 1 O2 mechanism, may be deeply involved in cellular processes leading to developing iron toxicity symptoms in plants. 相似文献