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Chiral Schiff base complexes are very efficient for a wide range of reactions, including expoxidation[1], epoxide ring opening[2], Diels-Alder reaction[3], aldol reaction[4], etc. However, there are only few examples of P-N chelate Schiff bases being used as the chiral ligands in the asymmetric transfer hydrogenation of ketones. Recently, Gao et al[5] reported a series of P,N,N,P Schiff base ligands that have relatively low enantioselectivity in the asymmetric transfer hydrogenation of ketones. 相似文献
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本研究旨在分析脑胶质瘤患者的磁共振弥散张量成像(DTI)参数与病变组织血管内皮生长因子(VEGF)和基质金属蛋白酶-9(MMP-9)表达的相关性,以及DTI参数对脑胶质瘤进行分级诊断的价值.根据病理分级将102例脑胶质瘤患者分为低级别组(47例)和高级别组(55例),均行MRI和DTI检查,定量测定表观弥散系数(ADC... 相似文献
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Huicong Yang Prof. Lichang Yin Dr. Ji Liang Dr. Zhenhua Sun Yuzuo Wang Hucheng Li Kuang He Lipo Ma Prof. Zhangquan Peng Siyao Qiu Chenghua Sun Prof. Hui‐Ming Cheng Prof. Feng Li 《Angewandte Chemie (International ed. in English)》2018,57(7):1898-1902
The electrochemical performance of the aluminum‐sulfur (Al‐S) battery has very poor reversibility and a low charge/discharge current density owing to slow kinetic processes determined by an inevitable dissociation reaction from Al2Cl7? to free Al3+. Al2Cl6Br? was used instead of Al2Cl7? as the dissociation reaction reagent. A 15‐fold faster reaction rate of Al2Cl6Br? dissociation than that of Al2Cl7? was confirmed by density function theory calculations and the Arrhenius equation. This accelerated dissociation reaction was experimentally verified by the increase of exchange current density during Al electro‐deposition. Using Al2Cl6Br? instead of Al2Cl7?, a kinetically accelerated Al‐S battery has a sulfur utilization of more than 80 %, with at least four times the sulfur content and five times the current density than that of previous work. 相似文献
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The growth of lanthanum conversion coatings on the zinc powder modified by ultrasonic immersion is deeply investigated by Auger electron spectroscopy, X-ray photoelectron spectroscopy, spectrophotometrical and other characterization techniques. The conversion kinetics of La element and the growth mechanism of lanthanum conversion layers are also reported and proposed. The influence of the lanthanum conversion coatings on the discharge properties and cycle behaviors of zinc electrodes is evaluated through charge–discharge measurements and cycle voltammetry. It is found that La2O3 and ZnO compose the lanthanum conversion films and trace content of La element in modified zinc powder can be controlled by varying the ultrasonic power. Furthermore, the superior performance of zinc electrode using the zinc powder coated with lanthanum conversion films is clearly established by low capacity loss and high cycle stability. The great improvement over the electrochemical properties of zinc electrodes should be ascribed to the physical shielding effect of lanthanum conversion layers. 相似文献
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We fabricated mesoporous hybrid dual-metal Co and Fe containing metallic organic framework (Co/Fe-MOF), Fe-MOF, and Co-MOF in the ionic liquid (IL)/supercritical CO2 (SC)/surfactant emulsion system, and then studied the electrochemical properties of the three MOFs systematically. 相似文献
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1-(Z)-[2-(三芳基锡基)乙烯基]环戊醇及其衍生物的合成及生物活性 总被引:1,自引:0,他引:1
合成了14种新的(Z)-[2-(三芳基锡基)乙烯基]环戊醇类有机锡化合物,通过元素分析,IR、^1H NMR 对所合成的化合物进行了表征,结果表明(Z)-[2-(三芳基锡基)乙烯基]环戊醇类有机锡化合物中乙烯式双键为顺式构型,分子内羟基与锡原子发生配位,形成五元螯合环。生物活性测定结果表明,二卤化物在抗癌,免疫及受体作用等方面具有优良的活性。 相似文献
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Huicong Li 《Journal of Dynamics and Differential Equations》2018,30(4):1775-1795
This paper is concerned with the steady state problem of a chemotaxis model with singular sensitivity function in a one dimensional spatial domain. Using the chemotactic coefficient \(\chi \) as the bifurcation parameter, we perform local and global bifurcation analysis for the model. It is shown that positive monotone steady states exist as long as \(\chi \) is larger than the first bifurcation value \(\bar{\chi }_1.\) We further obtain asymptotic profiles of these steady states, as \(\chi \) becomes large. In particular, our results show that the cell density function forms a spike, which models the important physical phenomenon of cell aggregation. 相似文献
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通过1[(Z)2(三苯基锡基)乙烯基]环戊醇与Br2反应制得了新化合物1[(Z)2(苯基二溴化锡基)乙烯基]环戊醇.通过元素分析、锡含量测定、IR、1HNMR对其进行了表征并用X射线衍射法测得了所合成化合物的晶体结构.该化合物属正交晶系,P212121空间群,晶胞参数:a=08675(4)nm,b=12523(7)nm,c=14009(8)nm;Z=4,V=15219nm3,Dc=2.39cm3,u=23.72cm-1.结构分析表明,标题化合物分子为畸变的三角双锥构架,双键的两个氢取顺式结构,分子中O与Sn配位,形成五元螯合环结构 相似文献
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Ren Xinyi Liu Song Li Huicong Ding Jie Liu Linghui Kuang Zhichong Li Ling Yang Hongbin Bai Fuquan Huang Yanqiang Zhang Tao Liu Bin 《中国科学:化学(英文版)》2020,63(12):1727-1733
Science China Chemistry - Electrochemical carbon dioxide reduction reaction (CO2RR) powered by renewable electricity offers an attractive approach to reduce carbon emission and at the same time... 相似文献