全文获取类型
收费全文 | 83篇 |
免费 | 2篇 |
专业分类
化学 | 61篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 4篇 |
物理学 | 17篇 |
出版年
2022年 | 2篇 |
2020年 | 2篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2013年 | 1篇 |
2011年 | 3篇 |
2010年 | 1篇 |
2009年 | 1篇 |
2008年 | 1篇 |
2007年 | 3篇 |
2006年 | 7篇 |
2005年 | 3篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1981年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1959年 | 3篇 |
1957年 | 2篇 |
1956年 | 2篇 |
1952年 | 1篇 |
1944年 | 1篇 |
1942年 | 2篇 |
1938年 | 1篇 |
1927年 | 2篇 |
1924年 | 2篇 |
排序方式: 共有85条查询结果,搜索用时 15 毫秒
1.
The effect of susceptibility differences between fluid and fibers on the properties of DTI fiber phantoms was investigated. Thereto, machine-made, easily producible and inexpensive DTI fiber phantoms were constructed by winding polyamide fibers of 15 microm diameter around a circular acrylic glass spindle. The achieved fractional anisotropy was 0.78+/-0.02. It is shown by phantom measurements and Monte Carlo simulations that the transversal relaxation time T(2) strongly depends on the angle between the fibers and the B(0) field if the susceptibilities of the fibers and fluid are not identical. In the phantoms, the measured T(2) time at 3 T decreased by 60% for fibers running perpendicular to B(0). Monte Carlo simulations confirmed this result and revealed that the exact relaxation time depends strongly on the exact packing of the fibers. In the phantoms, the measured diffusion was independent of fiber orientation. Monte Carlo simulations revealed that the measured diffusion strongly depends on the exact fiber packing and that field strength and -orientation dependencies of measured diffusion may be minimal for hexagonal packing while the diffusion can be underestimated by more than 50% for cubic packing at 3 T. To overcome these effects, the susceptibilities of fibers and fluid were matched using an aqueous sodium chloride solution (83 g NaCl per kilogram of water). This enables an orientation independent and reliable use of DTI phantoms for evaluation purposes. 相似文献
2.
3.
Acoustic attenuation of hybrid silencers 总被引:1,自引:0,他引:1
The acoustic attenuation of a single-pass, perforated concentric silencer filled with continuous strand fibers is investigated first theoretically and experimentally. The study is then extended to a specific type of hybrid silencer that consists of two single-pass perforated filling chambers combined with a Helmholtz resonator. One-dimensional analytical and three-dimensional boundary element methods (BEM) are employed for the predictions of the acoustic attenuation in the absence of mean flow. To account for the wave propagation in absorbing fiber, the complex-valued characteristic impedance and wave number are measured. The perforation impedance facing the fiber is also presented in terms of complex-valued characteristic impedance and wave number. The effects of outer chamber diameter and the fiber density are examined. Comparisons of predictions with the experiments illustrate the need for multi-dimensional analysis at higher frequencies, while the one-dimensional treatment provides a reasonable accuracy at lower frequencies, as expected. The study also shows a significant improvement in the acoustic attenuation of the silencer due to fiber absorption. Multi-dimensional BEM predictions of a hybrid silencer demonstrate that a reactive component such as a Helmholtz resonator can improve transmission loss at low frequencies and a higher duct porosity may be effective at higher frequencies. 相似文献
4.
Huff TB Hansen MN Zhao Y Cheng JX Wei A 《Langmuir : the ACS journal of surfaces and colloids》2007,23(4):1596-1599
Gold nanorods coated with cetyltrimethylammonium bromide (CTAB), a cationic micellar surfactant used in nanorod synthesis, were rapidly and irreversibly internalized by KB cells via a nonspecific uptake mechanism. Internalized nanorods near the cell surface were monitored by two-photon luminescence (TPL) microscopy and observed to migrate toward the nucleus with a quadratic rate of diffusion. The internalized nanorods were not excreted but formed permanent aggregates within the cells, which remained healthy and grew to confluence over a 5-day period. Nonspecific nanorod uptake could be greatly reduced by displacing the CTAB surfactant layer with chemisorptive surfactants, particularly by the conjugation of poly(ethylene glycol) chains onto nanorods using in situ dithiocarbamate formation. 相似文献
5.
The reaction of bromite with aqueous S(IV) is first order in both reactants and is general-acid catalyzed. The reaction half-lives vary from 5 ms (p[H+] 5.9) to 210 s (p[H+] 13.1) for 0.7 mM excess S(IV) at 25 degrees C. The proposed mechanism includes a rapid reaction (k(1) = 3.0 x 10(7) M(-1) s(-1)) between BrO(2)(-) and SO(3)(2-) to form a steady-state intermediate, (O(2)BrSO(3))(3-). General acids assist the removal of an oxide ion from (O(2)BrSO(3))(3-) to form OBrSO(3)(-), which hydrolyzes rapidly to give OBr(-) and SO(4)(2-). Subsequent fast reactions between HOBr/OBr(-) and SO(3)(2-) give Br(-) and SO(4)(2-) as final products. In contrast, the chlorite reactions with S(IV) are 5-6 orders of magnitude slower. These reactions are specific-acid, not general-acid, catalyzed. In the proposed mechanism, ClO(2)(-) and SO(3)H(-)/SO(2) react to form (OClOSO(3)H)(2)(-) and (OClOSO(2))(-) intermediates which decompose to form OCl(-) and SO(4)(2-). Subsequent fast reactions between HOCl/OCl(-) and S(IV) give Cl- and SO(4)(2-) as final products. SO(2) is 6 orders of magnitude more reactive than SO(3)H-, where k(5)(SO(2)/ClO(2)(-)) = 6.26 x 10(6) M(-1) s(-1) and k(6)(SO(3)H(-)/ClO(2)(-)) = 5.5 M(-1) s(-1). Direct reaction between ClO(2)(-) and SO(3)(2-) is not observed. The presence or absence of general-acid catalysis leads to the proposal of different connectivities for the initial reactive intermediates, where a Br-S bond forms with BrO(2)(-) and SO(3)(2-), while an O-S bond forms with ClO(2)(-) and SO(3)H-. 相似文献
6.
7.
8.
9.
Ohne Zusammenfassung
Auszug aus der Dissertation von K. Huff, Philipps-Universit?t, Philosophische Fakult?t (Marburg/L. 1956).
Ebenso danken wir auch hier nochmals den Firmen Farbenfabriken Bayer, Leverkusen, Badische Anilin & Sodafabriken, Lud-wigshafen,
Norddeutsches See-Kabel-werk, Nordenham, Fa. Kalle & Co., Wies-baden-Biebrich und Organico, Paris/für die freundliche überlassung
des geeigneten Untersuchungsmaterials. 相似文献
10.
The potentialities of computerized pyrolysis mass spectrometry (m.s.) are discussed for applications in process monitoring and quality assurance involving nonvolatile materials such as polymers. The traditional obstacles to more widespread acceptance of pyrolysis m.s. for industrial applications are reviewed in the light of recent developments which provide a major reduction in the cost, size and complexity of the equipment. Rapid advances in computerized data reduction, evaluation and interpretation methods for complex mass-spectral patterns are also transforming the classical “fingerprinting” concept of pyrolysis m.s. into a much more detailed compositional and structural characterization approach. These new developments are illustrated by means of several practial examples ranging from quality control of clinically important polyurethanes to monitoring of wood pulping processes and of growth phenomena in microbial cultures. 相似文献