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A β‐barrel protein hybrid catalyst was prepared by covalently anchoring a Grubbs–Hoveyda type olefin metathesis catalyst at a single accessible cysteine amino acid in the barrel interior of a variant of β‐barrel transmembrane protein ferric hydroxamate uptake protein component A (FhuA). Activity of this hybrid catalyst type was demonstrated by ring‐opening metathesis polymerization of a 7‐oxanorbornene derivative in aqueous solution.  相似文献   
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Two new butanolides, subamolide D (1) and subamolide E (2), and a new secobutanolide, secosubamolide A (3), along with 21 known compounds were isolated from the leaves of Cinnamomum subavenium. The structures of 1-3 were determined by spectroscopic analysis. Propidium iodide staining and cytometry analysis were used to evaluate the cell cycle progression of the treated SW480 cells and it was found that 1 and 2 caused DNA damage in a dose- and time-dependent manner.  相似文献   
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YR Waghmare 《Pramana》2002,58(1):27-30
It has been a long standing problem to find the connection between the realistic nucleon-nucleon interaction and the interaction between two nucleons when they are embedded inside a nuclear medium, the so-called ‘effective interaction’. On the one hand various many-body approaches have been employed, while on the other hand, information is sought on the basis of static nuclear properties. Both provide partial information. An attempt is made to understand if there is an inherent link, a bridge, which connects all these informations, through the study of heavy ion fusion reactions.  相似文献   
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Cinnamophilin A (1), a new Cinnamomum lignan, has been isolated from Cinnamomum philippinense (Merr.) Chang (Lauraceae), and its structure was characterized and identified by physical and spectral evidence.  相似文献   
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The design for the deployment of artistic statues in an exhibition area comes from the designer's experience, and whether such a design is adequate having no simple applicable criterion. The proposed model, deploying statues (DSs) model, not only applies the fractal dimension to measure the spatial complexity as its objective but also considers the traffic flow zone, the number of DSs, the average diameter of the statue, and the minimum allowable distance of adjacent artistic statues to arrange the spatial configuration in an exhibition area. The minimal complexity (fractal dimension) is mainly focused on because exhibiting designers deem that the spatial simplicity of an exhibition area leads to comfortable vision for a visitor. Indeed, this paper describes an applicable aspect of fractals. A computational intelligence written in Fortran Program to perform the spatial arrangement of artistic statues in an exhibition area is provided, and its adaptability has been explored by pilot tests of benchmark cases. Then, a case study through visual reality deployment for the Hosanna Museum at Chiayi Taiwan is followed. This study indeed provides a valuable tool in conducting the pre-stage of thinking process for exhibiting designers in deploying exhibits.  相似文献   
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