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制备了甘氨酸-壳聚糖复合膜修饰玻碳电极(Gly-CTS/GCE),研究了抗坏血酸(AA)和尿酸(UA)在该修饰电极上的电化学行为。结果表明在pH=5.59的磷酸盐缓冲溶液中,AA、UA在Gly-CTS/GCE上均产生灵敏的不可逆氧化峰,其峰电流与浓度在一定范围内呈良好的线性关系。对AA和UA混合溶液平行测定7次,相对标准偏差分别为4.6%、2.9%,表明该电极重现性和稳定性良好。AA、UA在Gly-CTS/GCE电极上的氧化峰峰电位相差340mV,据此可实现对二者的同时检测,并可应用于实际样品测定。 相似文献
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Brian Houlden 《The Journal of the Operational Research Society》1979,30(8):681-690
This paper presents views based on experiences as team member, project leader and Director of a large O.R. group, followed by observing the performance of several O.R. groups and finally as a user of O.R. in the position of part-time director of several companies. It looks at the importance of sponsorship, finding the right sponsor and ensuring that he is well-motivated and understood, the importance of management skills at the project leader level, correct definition of the project objective, thorough planning, selection and presentation of recommendations, implementation and checking the actual pay off. It also discusses the O.R. group as a whole, its place in the organisation, the portfolio of projects, development of O.R. staff and some thoughts on how the method of charging the organisation for O.R. projects may affect the long-term development of this activity. Finally, it presents symptoms of inefficiency and of impending failure of O.R. groups. 相似文献
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C70X2(X=H,F, Cl)的稳定性和电子光谱 总被引:1,自引:0,他引:1
用INDO方法研究C70H2四种异构体的稳定性, 表明其最稳定异构体为1, 9-C70H2和7, 8-C70H2, 两者能量差为16.3KJ.mol^-^1, 与实验值及ab initio计算值接近; 光谱计算表明, 其特征吸收峰与实验值一致。在此基础上预测C70F2和C70Cl2的稳定性和电子光谱, 表明C70F2四种异构体的稳定性顺序与C70H2一致, 而C70Cl2则以21, 42-异构体最为稳定。二者的电子光谱与C70H2极其相似只是在500nm以上有细微差别。 相似文献
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An extensive series of CI calculations have been carried out for the BH molecule using averaged natural orbitals. It is shown that energy profiles yielding accurate spectroscopic constants are obtainable for several states simultaneously. Energy values and spectroscopic data for the five lowest singlet states X 1Σ+, A 1Π, C 1Δ, B 1Σ+, and C 1σ+have been calculated. 相似文献
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Hindered Ureas as Masked Isocyanates: Facile Carbamoylation of Nucleophiles under Neutral Conditions
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The use of average natural orbitals is compared to some better known methods of performing limited and restricted CI calculations. It is found that a moderately extensive restricted valence shell CI computation using a subset of these orbitals is an efficient and accurate method for the calculation of state wavefunctions. Total and electronic excitation energies have been calculated for the BH molecule.Taken in part from a Ph. D. thesis submitted to the University of Toronto in 1971. 相似文献
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P.L. Woodwarth D. Treille A.S. Thompson R. Strub P. Sonderegger C. Palazzi-Cerrina W.A. Mitaroff R. Kumar I.R. Kenyon G. Irwin J.R. Hubbard M. Houlden B.R. French L. Fluri G. De Rosny M. Cribier J.K. Bienlein 《Physics letters. [Part B]》1976,65(1):89-91
We have observed φ production in π?p interactions at 19 GeV/c with (44±10) events in the final state φπ+π?π?p and (45±9) events in φK+K?π?p. The production ratios φπ+π?π?p/ωπ+π?π?p ≈ 0.005 and φK+K?π?p/?°K+K?π?p ≈ 0.45 agree with Zweig-rule expectations. 相似文献