Analysis of hybrid donor layer in organic solar cells based on SubPc and rubrene

In this paper, photovoltaic characteristics of ITO/PEDOT:PSS/SubPc:Rubrene (mixed ratio R by weight)/C₆₀/Bphen/Ag organic solar cells (OSCs) are analyzed in detail. The intrinsic properties of a SubPc:rubrene doped layer on device performance were discussed based on theoretical analysis of the experimental OSCs. The ratio R was 0, 0.25, 0.5, and 0.75,1, respectively. The results showed that when R was 0.75 performing the best, which owned the highest short circuit current (J _sc ) 6.61 mA/cm² and highest power conversion efficiency (PCE) 2.44%, the FF was 41% and the open circuit current (V _oc ) was 0.905 V. The suitable HOMO level, absorption capacity, carrier transport ability and exciton diffusion length (L _D ) of organic material are very important for the performance of the device.     

r-一致超图Ramsey函数的渐近下界(英文)

本文利用Lovasz局部引理的Spencer形式和对称形式给出r-一致超图Ramsey函数的渐近下界.证明了:对于任意取定的正整数f0,使得当n→∞时,有R~((r))(m~l,n~(k-l))≥(c-o(1))(n~(r-1)/logn)~■.特别地,R~((r))_k(n)≥(1-o(1))n/e k~■(n→∞).对于任意取定的正整数s≥r+1和常数δ>0,α≥0,如果F表示阶为s的r-一致超图,■表示阶为t的r-一致超图,且■的边数满足m(■)≥(δ-o(1))t~r/(logt)α(t→∞),则存在c=c(s,δ,α)>0,使得R~((r))(F,■)≥(c-o(1))(t~(r-1)/(logt)~l+(r-l)α)~(m(F)-l/s-r).     

对于轮和完全图的 Ramsey 数的渐近上界

该文给出:对于偶数m≥4当n→ ∞时 r(W_m,K_n)≤l(1+o(1))C₁(m) (n/logn ) ^(2m-2)/(m-2)对于奇数m≥5当n→∞时r(W_m,K_n)≤(1+o(1))C₂(m) (n^2m/_m+1/^{_{log n)}(m+1)/(m-1)} .特别地,C₂(5)=12. 以及 c(ⁿ/_logn)^5/2≤r(K₄,K_n)≤ (1+o(1)) ^n3_/(logn)².此外,该文还讨论了轮和完全图的 Ramsey 数的一些推广.     

Flag-transitive point-primitive automorphism groups of non-symmetric 2-(<Emphasis Type="Italic">v</Emphasis>, <Emphasis Type="Italic">k</Emphasis>, 3) designs

In this paper, we show that if \({\mathcal {D}}\) is a non-trivial non-symmetric 2-(v, k, 3) design admitting a flag-transitive point-primitive automorphism group G, then G must be an affine or almost simple group.     

Voltammetric determination of DNA based on regulation of DNA strand displacement using an allosteric DNA toehold

An electrochemical biosensor for determination of DNA is described that is based on the reaction of regulated DNA (reg-DNA) first with substrated DNA (subs-DNA) to form a reaction intermediate. The intermediate binds target DNA (T) by hybridization and initiates a branch migration leading to the production of complex of substrated DNA and target DNA (TC). Once TC is produced, it reacts with assisted DNA (ass-DNA) through a toehold exchange mechanism, yielding the product complex of substrated DNA and assisted DNA (CS). The target is then released back into the solution and and catalyzes the next cycle of toehold-exchange with the reaction intermediate of substrated DNA and regulated DNA (CPR). Unlike in a conventional DNA toehold that is hardwired with the branch migration domain, the allosteric DNA toehold is designed into a reg-DNA which is independent of the branch migration domain. Under the optimal experimental conditions and at a working potential as low as 0.18 V, response to DNA is linear in the 1 fM to 1000 pM concentration range, and the detection limit is 0.83 fM. The assay is highly specific and can discriminate target DNA even from a single-base mismatch. It was applied to the analysis of DNA spiked plasma samples.

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Graphical abstract Schematic illustration of the electrochemical strategy for target DNA detection based on regulation of DNA strand displacement using an allosteric DNA toehold strategy. It can be used to analyze DNA-spiked plasma samples and has a low detection limit of 0.83 fM.

     

含有大的悬挂树图的Ramseygoodness结论(英文)

设H是阶为n的连通图.在H的某一个顶点上悬挂一棵阶为j的树,得到图H_j,用H_j表示这样的图形族.本文证明:当j充分大时,有r(G,H_j)=(x(G)-1)(n+j-1)+s(G),其中x(G),s(G)分别表示图G的色数和色数剩余.     

A scheme for the RCP pattern of the nano-structure

IntroductionThe balls-ffeng is a haous and dimcult problem. The meaning is the material ba1lswhich contains in it fill spare. This is an older problem. the Random-Continuous-Pile (RCP)problem. that can be trared bark to the l8th centur};'.. There are man}' unknown mysteriesin the RCP structure. With the materiaJ science de\-elopment. this old RCP problem has bee11paid attention to. Especially. in the nan(pmetre mdterial. bubble fluids. amorphous solid5.tlle RCP problem shows its titali…     

Modification of kaolinite with alkylimidazolium salts

We have demonstrated that the d-spacing and thermal stability of the alkylimidazolium intercalated kaolinite compounds can be controlled by adjusting chain length of the alkyl groups. The composites were synthesized by displacement method using selected imidazolium ionic liquids bearing different short alkyl chains as guest molecules. The effects of the length of alkyl side chain on d-spacing and thermal stability of the ionic liquids–kaolinite intercalations were investigated by XRD and TG-DSC. Results revealed that in these composites, increasing the length of alkyl substituent led to larger d-spacing and decreased thermal stability. Temperature was found to have influence on the intercalation ratio but not on the d-spacing of final product. The present study shows an easy way of tailoring the performance of these intercalations via small variation of guest ionic liquids, providing the possibility of finding “species-specific” modifier for fully exfoliated nanocomposites.     

纳米级造影剂在肿瘤影像学诊疗中的基础应用进展

肿瘤的早期诊断对其生存率及预后有极大的意义,医学成像造影剂的应用可极大地提高肿瘤的早期诊断水平。通过新兴纳米技术开发无毒、成像能力更强、循环时间更长的纳米级造影剂是目前研究的热点。本文综述了纳米级造影剂在MRI、CT、US、PET和SPECT等生物医学成像技术中,对于肿瘤诊疗的基础应用,并列举了部分研究实例。纳米级造影剂具有广阔的临床应用前景,未来的研究重点将会是开发集诊断、治疗于一体的多功能的纳米平台。