2,5-二(2-菲基)-[3,2-b]并二噻吩的合成、表征及在有机薄膜晶体管中的应用

本文合成了2,5-二(2-菲基)-[3,2-b]并二噻吩(PhTT), 表征了其基本的物理和化学性质, 制备了相应的有机薄膜晶体管.     

混合式教学应用于校通识课的探索与实践——以“奇妙的化学世界”为例

“奇妙的化学世界”是天津师范大学面向全校非化学专业的本科生开设的一门通识选修课。课程主要采用启发式教学模式、案例式教学模式、互动式教学模式等相结合的混合式教学模式，涉及当今活跃的科研领域和生活实际。课程采用多种方式如图片展示、教学辅助视频、小组讨论、调查问卷等，调动学生的积极性和主动性，使学生在较为轻松的状态下掌握课程内容。此外，力求做到集知识性、实用性、趣味性于一体，避免了化学专业课程中的复杂多变的化学结构描述。     

Highly Selective Synthesis of Methyl 1-Phenyl-1-(9-hydro-)fullerenylacetate

Isomerically pure methyl 1-phenyl-1-(9-hydro-)fullerenylacetat is synthesized in 75% yield by the reaction of C₆₀ with the carbanions of methyl phenylacetate in C₆H₆/THF mixed solvent under a purified N₂ atmosphere at 20°C.     

Detection of mutant p53 using field-effect transistor biosensor

We assessed the abilities of wild p53 and mutant p53 proteins to interact with the consensus DNA-binding sequence using a MOSFET biosensor. This is the first report in which mutant p53 has been detected on the basis of DNA-protein interaction using a FET-type biosensor. In an effort to evaluate the performance of this protocol, we constructed the core domain of wild p53 and mutant p53 (R248W), which is DNA-binding-defective. After the immobilization of the cognate DNA to the sensing layer, wild p53 and mutant p53 were applied to the DNA-coated gate surface, and subsequently analyzed using a semiconductor analyzer. As a consequence, a significant up-shift in drain current was noted in response to wild p53, but not mutant p53, thereby indicating that sequence-specific DNA-protein interactions could be successfully monitored using a field-effect-based biosensor. These data also corresponded to the results obtained using surface plasmon resonance (SPR) measurements. Taken together, our results show that a FET-type biosensor might be promising for the monitoring of mutant p53 on the basis of its DNA-binding activity, providing us with very valuable insights into the monitoring for diseases, particularly those associated with DNA-protein binding events.     

Thermal annealing effects on the dynamic photoresponse properties of Al-doped ZnO nanowires network

In this study, UV photodetectors based on a network of aluminium-doped zinc oxide (AZO) nanowires were manufactured at a low cost; for this purpose, a fast and simple fabrication process that involved dropping nanowires dispersion solution was employed instead of the conventional e-beam lithography process that is used to manufacture single nanowire–based UV photodetectors. It was demonstrated that nanowire network–based UV photodetectors provide a much faster UV photoresponse than conventional single nanowire–based UV photodetectors. The fast UV photoresponse of the fabricated UV photodetector can be attributed to the fact that the potential barriers formed in the nanowire network junctions effectively block the flow of electrons during the process of photocurrent decay. Furthermore, the UV photoresponse under illumination by a 254 nm UV source was studied as a function of the annealing temperature of the AZO nanowires network at a bias of 5 V. The fabricated UV photodetector showed the fastest response of 2 s to UV illumination in air when the sample was annealed in air for 1 h at 300 °C.     

Estimates for correlations in billiards with large arcs

Bunimovich billiards are ergodic and mixing. However, if the billiard table contains very large arcs on its boundary then if there exist trajectories experience infinitely many collisions in the vicinity of periodic trajectories on the large arc. The hyperbolicity is nonuniform and the mixing rate is very slow. The corresponding dynamics are intermittent between regular and chaotic, which makes them particularly interesting in physical studies. The study of mixing rates in intermittent chaotic systems is mo...     

Averaged Mappings and the Gradient-Projection Algorithm

It is well known that the gradient-projection algorithm (GPA) plays an important role in solving constrained convex minimization problems. In this article, we first provide an alternative averaged mapping approach to the GPA. This approach is operator-oriented in nature. Since, in general, in infinite-dimensional Hilbert spaces, GPA has only weak convergence, we provide two modifications of GPA so that strong convergence is guaranteed. Regularization is also applied to find the minimum-norm solution of the minimization problem under investigation.     

AuNPs/Sol-gel复合膜法固定乙酰胆碱酯酶生物传感器检测有机磷农药

基于有机磷农药对乙酰胆碱酯酶(Acetylcholinesterase,AChE)的抑制作用,用金纳米粒子(Au nanoparticles,AuNPs)与壳聚糖/SiO2杂化溶胶-凝胶构成复合固酶基质,将AChE固定于玻碳电极表面,制备了电流型AChE生物传感器选用久效磷进行实验,以氯化硫代乙酰胆碱为底物,建立了电化...     

New approach to differential equations with countable impulses

This paper provides a new approach to study the solutions of a class of generalized Jacobi equations associated with the linearization of certain singular flows on Riemannian manifolds with dimension n + 1.A new class of generalized differential operators is defined.We investigate the kernel of the corresponding maximal operators by applying operator theory.It is shown that all nontrivial solutions to the generalized Jacobi equation are hyperbolic,in which there are n dimension solutions with exponential...     

A Functional Analytic Approach to Perturbations of the Lorentz Gas

We present a functional analytic framework based on the spectrum of the transfer operator to study billiard maps associated with perturbations of the periodic Lorentz gas. We show that recently constructed Banach spaces for the billiard map of the classical Lorentz gas are flexible enough to admit a wide variety of perturbations, including: movements and deformations of scatterers; billiards subject to external forces; nonelastic reflections with kicks and slips at the boundaries of the scatterers; and random perturbations comprised of these and possibly other classes of maps. The spectra and spectral projections of the transfer operators are shown to vary continuously with such perturbations so that the spectral gap enjoyed by the classical billiard persists and important limit theorems follow.