首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   44751篇
  免费   6641篇
  国内免费   5798篇
化学   33191篇
晶体学   609篇
力学   2316篇
综合类   522篇
数学   4985篇
物理学   15567篇
  2024年   114篇
  2023年   718篇
  2022年   1303篇
  2021年   1331篇
  2020年   1561篇
  2019年   1526篇
  2018年   1283篇
  2017年   1198篇
  2016年   1915篇
  2015年   1888篇
  2014年   2351篇
  2013年   3142篇
  2012年   3769篇
  2011年   3813篇
  2010年   2722篇
  2009年   2619篇
  2008年   3066篇
  2007年   2814篇
  2006年   2648篇
  2005年   2176篇
  2004年   1857篇
  2003年   1651篇
  2002年   1684篇
  2001年   1359篇
  2000年   1155篇
  1999年   1132篇
  1998年   834篇
  1997年   763篇
  1996年   736篇
  1995年   647篇
  1994年   557篇
  1993年   523篇
  1992年   442篇
  1991年   363篇
  1990年   365篇
  1989年   262篇
  1988年   185篇
  1987年   153篇
  1986年   149篇
  1985年   112篇
  1984年   67篇
  1983年   60篇
  1982年   50篇
  1981年   36篇
  1980年   21篇
  1979年   9篇
  1978年   11篇
  1977年   7篇
  1976年   9篇
  1973年   7篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
2.
Zhu  Jie-Xiang 《Potential Analysis》2021,55(1):167-188
Potential Analysis - We establish some exact asymptotic results for a matching problem with respect to a family of beta distributions. Let X1,…,Xn be independent random variables with common...  相似文献   
3.
Journal of Optimization Theory and Applications - We consider a distributionally robust formulation of stochastic optimization problems arising in statistical learning, where robustness is with...  相似文献   
4.
Zhang  Junyu  Hong  Mingyi  Zhang  Shuzhong 《Mathematical Programming》2022,194(1-2):901-935
Mathematical Programming - In this paper, we study the lower iteration complexity bounds for finding the saddle point of a strongly convex and strongly concave saddle point problem: $$\min _x\max...  相似文献   
5.
Hua  Saixiang  Zhu  Huichao  Wang  Xiao  Wu  Mingyuan  Wu  Qingyun  Liu  Jiuyi  Yang  Jianjun  Zhang  Jianan 《Cellulose (London, England)》2022,29(13):7465-7475
Cellulose - Ultraviolet (UV) protective cotton fabric is a convenient and reliable way to protect human body from sunlight. Herein, a polymerizable UV-absorber,...  相似文献   
6.
Li  Mingjun  Zhu  Li 《应用数学和力学(英文版)》2021,42(8):1171-1182
This study is to numerically test the interfacial instability of ferrofluid flow under the presence of a vacuum magnetic field. The ferrofluid parabolized stability equations(PSEs) are derived from the ferrofluid stability equations and the Rosensweig equations, and the characteristic values of the ferrofluid PSEs are given to describe the ellipticity of ferrofluid flow. Three numerical models representing specific cases considering with/without a vacuum magnetic field or viscosity are created to mathematically examine the interfacial instability by the computation of characteristic values. Numerical investigation shows strong dependence of the basic characteristic of ferrofluid Rayleigh-Taylor instability(RTI) on viscosity of ferrofluid and independence of the vacuum magnetic field.For the shock wave striking helium bubble, the magnetic field is not able to trigger the symmetry breaking of bubble but change the speed of the bubble movement. In the process of droplet formation from a submerged orifice, the collision between the droplet and the liquid surface causes symmetry breaking. Both the viscosity and the magnetic field exacerbate symmetry breaking. The computational results agree with the published experimental results.  相似文献   
7.
Photoelectrochemical (PEC) cytosensors, a combination of the PEC process and the living-cell assay, have emerged as a powerful tool in the analytical and biological science. This mini review provides a brief introduction of this arena and summaries the key steps about the development of PEC cytosensors with representative examples, followed by future prospects based on our own opinions.  相似文献   
8.
Incorporating nanoscale Si into a carbon matrix with high dispersity is desirable for the preparation of lithium-ion batteries (LIBs) but remains challenging. A space-confined catalytic strategy is proposed for direct superassembly of Si nanodots within a carbon (Si NDs⊂C) framework by copyrolysis of triphenyltin hydride (TPT) and diphenylsilane (DPS), where Sn atomic clusters created from TPT pyrolysis serve as the catalyst for DPS pyrolysis and Si catalytic growth. The use of Sn atomic cluster catalysts alters the reaction pathway to avoid SiC generation and enable formation of Si NDs with reduced dimensions. A typical Si NDs⊂C framework demonstrates a remarkable comprehensive performance comparable to other Si-based high-performance half LIBs, and higher energy densities compared to commercial full LIBs, as a consequence of the high dispersity of Si NDs with low lithiation stress. Supported by mechanic simulations, this study paves the way for construction of Si/C composites suitable for applications in future energy technologies.  相似文献   
9.
Understanding the thermal aggregation behavior of metal atoms is important for the synthesis of supported metal clusters. Here, derived from a metal–organic framework encapsulating a trinuclear FeIII2FeII complex (denoted as Fe3) within the channels, a well-defined nitrogen-doped carbon layer is fabricated as an ideal support for stabilizing the generated iron nanoclusters. Atomic replacement of FeII by other metal(II) ions (e.g., ZnII/CoII) via synthesizing isostructural trinuclear-complex precursors (Fe2Zn/Fe2Co), namely the “heteroatom modulator approach”, is inhibiting the aggregation of Fe atoms toward nanoclusters with formation of a stable iron dimer in an optimal metal–nitrogen moiety, clearly identified by direct transmission electron microscopy and X-ray absorption fine structure analysis. The supported iron dimer, serving as cooperative metal–metal site, acts as efficient oxygen evolution catalyst. Our findings offer an atomic insight to guide the future design of ultrasmall metal clusters bearing outstanding catalytic capabilities.  相似文献   
10.
An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号