首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   64209篇
  免费   5659篇
  国内免费   5295篇
化学   36839篇
晶体学   712篇
力学   3191篇
综合类   386篇
数学   13498篇
物理学   20537篇
  2024年   74篇
  2023年   565篇
  2022年   791篇
  2021年   1061篇
  2020年   1316篇
  2019年   1279篇
  2018年   2264篇
  2017年   2433篇
  2016年   2310篇
  2015年   2144篇
  2014年   2357篇
  2013年   3271篇
  2012年   6130篇
  2011年   5443篇
  2010年   4117篇
  2009年   3685篇
  2008年   3088篇
  2007年   2891篇
  2006年   2660篇
  2005年   6156篇
  2004年   5435篇
  2003年   3630篇
  2002年   2005篇
  2001年   1511篇
  2000年   1072篇
  1999年   1021篇
  1998年   713篇
  1997年   653篇
  1996年   596篇
  1995年   532篇
  1994年   453篇
  1993年   350篇
  1992年   488篇
  1991年   421篇
  1990年   358篇
  1989年   281篇
  1988年   198篇
  1987年   164篇
  1986年   153篇
  1985年   118篇
  1984年   86篇
  1983年   68篇
  1982年   45篇
  1981年   43篇
  1976年   88篇
  1975年   44篇
  1974年   46篇
  1973年   55篇
  1972年   41篇
  1969年   38篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
3.
Zhang  Junyu  Hong  Mingyi  Zhang  Shuzhong 《Mathematical Programming》2022,194(1-2):901-935
Mathematical Programming - In this paper, we study the lower iteration complexity bounds for finding the saddle point of a strongly convex and strongly concave saddle point problem: $$\min _x\max...  相似文献   
4.
A graphic sequence π =(d1, d2,..., dn) is said to be forcibly k-edge-connected if every realization of π is k-edge-connected. In this paper, we obtain a new sufficient degree condition for π to be forcibly k-edgeconnected. We also show that this new sufficient degree condition implies a strongest monotone degree condition for π to be forcibly 2-edge-connected and a conjecture about a strongest monotone degree condition for π to be forcibly 3-edge-connected due to...  相似文献   
5.
Gao  Zhigen  Guo  Jianhua  Ma  Yanyuan 《中国科学 数学(英文版)》2021,64(8):1905-1916
Science China Mathematics - Linear factor models are familiar tools used in many fields. Several pioneering literatures established foundational theoretical results of the quasi-maximum likelihood...  相似文献   
6.
Understanding the thermal aggregation behavior of metal atoms is important for the synthesis of supported metal clusters. Here, derived from a metal–organic framework encapsulating a trinuclear FeIII2FeII complex (denoted as Fe3) within the channels, a well-defined nitrogen-doped carbon layer is fabricated as an ideal support for stabilizing the generated iron nanoclusters. Atomic replacement of FeII by other metal(II) ions (e.g., ZnII/CoII) via synthesizing isostructural trinuclear-complex precursors (Fe2Zn/Fe2Co), namely the “heteroatom modulator approach”, is inhibiting the aggregation of Fe atoms toward nanoclusters with formation of a stable iron dimer in an optimal metal–nitrogen moiety, clearly identified by direct transmission electron microscopy and X-ray absorption fine structure analysis. The supported iron dimer, serving as cooperative metal–metal site, acts as efficient oxygen evolution catalyst. Our findings offer an atomic insight to guide the future design of ultrasmall metal clusters bearing outstanding catalytic capabilities.  相似文献   
7.
In the paper, the authors establish several integral representations for the generating functions of the large and little Schröder numbers and for the large and little Schröder numbers.  相似文献   
8.
9.
A class of acceptor–donor–acceptor chromophoric small-molecule non-fullerene acceptors, 1–4, with difluoroboron(iii) β-diketonate (BF2bdk) as the electron-accepting moiety has been developed. Through the variation of the central donor unit and the modification on the peripheral substituents of the terminal BF2bdk acceptor unit, their photophysical and electrochemical properties have been systematically studied. Taking advantage of their low-lying lowest unoccupied molecular orbital energy levels (from −3.65 to −3.72 eV) and relatively high electron mobility (7.49 × 10−4 cm2 V−1 s−1), these BF2bdk-based compounds have been employed as non-fullerene acceptors in organic solar cells with maximum power conversion efficiencies of up to 4.31%. Moreover, bistable resistive memory characteristics with charge-trapping mechanisms have been demonstrated in these BF2bdk-based compounds. This work not only demonstrates for the first time the use of a boron(iii) β-diketonate unit in constructing non-fullerene acceptors, but also provides more insights into designing organic materials with multi-functional properties.

Boron(iii) β-diketonates have been demonstrated to serve as multi-functional materials in NFA-based OPVs and organic resistive memories.  相似文献   
10.
In this communication, we report the synthesis of small‐sized (<10 nm), water‐soluble, magnetic nanoparticles (MNPs) coated with polyhedral oligomeric silsesquioxanes (POSS), which contain either polyethylene glycol (PEG) or octa(tetramethylammonium) (OctaTMA) as functional groups. The POSS‐coated MNPs exhibit superparamagnetic behavior with saturation magnetic moments (51–53 emu g?1) comparable to silica‐coated MNPs. They also provide good colloidal stability at different pH and salt concentrations, and low cytotoxicity to MCF‐7 human breast epithelial cells. The relaxivity data and magnetic resonance (MR) phantom images demonstrate the potential application of these MNPs in bioimaging.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号