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The extraction behavior of several alkyl-substituted hydroxamic acids in chloroform solution with several metal ions is described. Among the N-phenylacylhydroxamic acids used, those with o-alkyl substituents on either the phenyl or acyl ring generally do not extract metals, apparently because of steric problems at the O=CNO? chelation site. An improved synthesis of substituted hydroxamic acids is reported. 相似文献
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MM. J. Duflos D. Letouz G. Queguiner P. Pastour 《Journal of heterocyclic chemistry》1973,10(6):1083-1084
This communication describes the synthesis of l-methyl-2,3-diformylpyrrole. This new compound is used to prepare a new heterocycle, l-methylcyclohepta[b]pyrrol-6-one and thus allows a new synthesis of l-methylpyrrolo[2,3-d]pyridazine. 相似文献
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Liquid-liquid extraction and spectrophotometric determination of palladium with 2-mercaptobenz-amide
2-Mercaptobenzamide (MBA) was investigated as a reagent for the extraction of palladium. The palladium complex of MBA was extracted into tributyl phosphate (TBP). The pKa of the ligand was 5.45 with the stability constant of the palladium complex β2=107.1. The composition of the complex in TBP was Pd:MBA:TBP=1:2:2. Addition of sodium chloride accelerated the rate of extraction. Various interfering ions could be masked with EDTA; Ag(I), Au(III), Os(VIII), Se(IV), Te(IV) etc. interfered. The molar absorptivity was 1.59×104 l mol?1 cm?1; 1–35 μg Pd could be determined at pH 6.0. 相似文献
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C. C. Habeger D. W. Coffin B. Hojjatie 《Journal of Polymer Science.Polymer Physics》2001,39(17):2048-2062
Accelerated creep is a curious and poorly understood transient moisture effect. The creep rates of most hydrophilic materials increase greatly with moisture content. However, when these same materials are subjected to creep loads in cyclic humidity environments, they often exhibit much higher creep rates than in a constantly humid state. This is called accelerated creep. Previous experimenters reported that accelerated creep was less likely to occur in polymeric fibers. We demonstrate experimentally that this happened only because of their choice of humidity cycling parameters. New results are given for Kevlar, lyocell, nylon‐6,6, and ramie fibers. Other paper scientists have argued that the absence of accelerated creep in single fibers supports a explanation based on fiber network effects for accelerated creep in paper. We argue here that accelerated creep is a more general phenomenon consistent with sorption‐induced stress‐gradient explanations. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 39: 2048–2062, 2001 相似文献
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MM. P. Duballet A. Godard G. Queguiner P. Pastour 《Journal of heterocyclic chemistry》1973,10(6):1079-1080
This article describes the synthesis of a new heterocycle, pyrido[2,3,f]phtalazine and three new diformylquinolincs. 相似文献
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The synthesis of two new heterocycles is described: pyrido-[2,3-d]-.s-triazolo[ 3,4-f] pyrimidine and pyrido[3,2-d]-.s-triayzolo-[3,4-f] pyrimidine. 4-[I'-Pyrazolyl]pyrido[2,3-d]pyrimidines and 4-[1′-pyrazoly1] pyrido[ 3,2-d] pyrimidine are obtained by the action of 4-hydrazinopyrido[2,3-d]pyrimidine and 4-hydrazinopyrido-[3,2-d]pyrimidine with several β-diketones. 相似文献
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