Preliminary estimate of the cost of ethanol production for ssf technology

The Solar Energy Research Institute (SERI) recently completed a detailed engineering and economic analysis of the simultaneous saccharification and fermentation (SSF) based wood-to-ethanol process. The reference-case design was based on a plant capacity of 1920 dry t/d and a wood cost of $42/dry t. For this case, the preliminary estimate of the production cost of the ethanol product is about $1.22/gal. The combined effects of optimizing SSF enzyme loading, increasing plant capacity to 10,000 dry t/d, and reducing wood cost to $34/dry t are to reduce the preliminary estimate of the production cost to about $0.95/gal. Other technological improvements may further reduce the production cost. Certain technical assumptions, inherent in the analysis, are being investigated further.

     

Density of the Medvedev lattice of Π<Superscript>0</Superscript><Subscript>1</Subscript> classes

The partial ordering of Medvedev reducibility restricted to the family of ⁰₁ classes is shown to be dense. For two disjoint computably enumerable sets, the class of separating sets is an important example of a ⁰₁ class, which we call a ``c.e. separating class'. We show that there are no non-trivial meets for c.e. separating classes, but that the density theorem holds in the sublattice generated by the c.e. separating classes. Mathematics Subject Classification (2000): 03D30, 03D25     

Zur Titerstellung in der Alkalimetrie und Acidimetrie

Ohne Zusammenfassung     

Use of net present value analysis to evaluate a publicly funded biomass-to-ethanol research,development, and demonstration program and valuate expected private sector participation

One of the functions of government is to invest tax dollars in programs, projects, and properties that will result in greater public benefit than would have resulted from leaving the tax dollars in the private sector or using them to pay off the public debt. This paper describes the use of Net Present Value(npv) as an approach to analyze and select investment opportunities for government money in public research, development, and demonstration (RD&D) programs and to evaluate potential private sector participation in the programs. This approach is then applied to a specific biomass-to-ethanol opportunity in California.     

Net present value analysis to select public r&d programs and valuate expected private sector participation

Applied Biochemistry and Biotechnology - One of the main functions of government is to invest taxpayer dollars in projects, programs, and properties that will result in social benefit. Public...     

Dielectric study of relaxations and polymorphism in poly(diethyl siloxane)

The dielectric behavior of poly(diethyl siloxane) supports the adiabatic calorimetric findings of Beatty and Karasz. In particular, a sub-T_g transition is observed near ?180°C at 100 Hz, the glass transition near ?135°C at 100 Hz, and a first-order transition near ?70°C (crystal–crystal transformation). This glass-transition temperature is the lowest reported polymeric glass transition for polymers.     

Finite termination games with tie

We consider the class of finite two-person games with perfect information in which the last player who can make a legal move either wins or ends the game in a tie. We define an equivalence relation over this class and exhibit a complete set of representatives for the equivalence classes defined in terms of one-pile Nim games. We are grateful to Dana Scott for suggesting this problem and this formulation of it.     

Degrees of difficulty of generalized r.e. separating classes

Important examples of classes of functions are the classes of sets (elements of ^ω 2) which separate a given pair of disjoint r.e. sets: . A wider class consists of the classes of functions f ∈ ^ω k which in a generalized sense separate a k-tuple of r.e. sets (not necessarily pairwise disjoint) for each k ∈ ω: . We study the structure of the Medvedev degrees of such classes and show that the set of degrees realized depends strongly on both k and the extent to which the r.e. sets intersect. Let denote the Medvedev degrees of those such that no m + 1 sets among A ₀,...,A _k-1 have a nonempty intersection. It is shown that each is an upper semi-lattice but not a lattice. The degree of the set of k-ary diagonally nonrecursive functions is the greatest element of . If 2 ≤ l < k, then 0 _M is the only degree in which is below a member of . Each is densely ordered and has the splitting property and the same holds for the lattice it generates. The elements of are exactly the joins of elements of for . Supported by National Science Foundation grants DMS 0554841, 0532644 and 0652732.     

Properties of the polyhydride anions [WH5(PMe2Ph)3]- and [ReH4(PMePh2)3]- and periodic trends in the acidity of polyhydride complexes

The new anionic complexes [K(18-crown-6)][WH5(PMe2Ph)3], [K(1,10-diaza-18-crown-6)][WH5(PMe2Ph)3], [K(2,2,2-crypt)][ReH4(PMePh2)3], and [K(1,10-diaza-18-crown-6)][ReH4(PMePh2)3] were prepared by reaction of KH/crown or KH/crypt with the appropriate neutral polyhydride WH6(PMe2Ph)3 or ReH5(PMePh2)3. The rate of deprotonation of the rhenium hydride in THF is much greater for the reaction involving crypt compared with that of crown. The structure of [ReH4(PMePh2)3]- is distorted pentagonal bipyramidal as determined by an X-ray diffraction study of the crypt salt. No hydridic-protonic M-H...HN bonding is detected between the hydrides of the anionic hydrides and the amino hydrogens of the cations [K(1,10-diaza-18-crown-6)]+ suggesting that stronger M-H...K interactions are present. Acid dissociation constants Ka of polyhydride complexes in THF, approximately corrected for ion pairing, are determined by NMR in order to better understand the periodic trends of metal hydrides. The pKalphaTHF of (WH6(PMe2Ph)3/[WH5(PMe2Ph)3]-) is 42+/-4 according to the equilibrium set up by reacting WH6(PMe2Ph)3 with [K(2,2,2-crypt)][ReH6(PCy3)2]. The pKalphaTHF for ReH5(PMePh2)3 can be estimated as greater than the pKalphaTHF of 38 for HNPh2 and less than the pKalphaTHF of 41 for ReH7(PCy3)2. Reaction of the phosphazene base P4-tBu with ReH7(PCy3)2 gave an equilibrium with [HP4-tBu]+[ReH6(PCy3)2]- whereas reaction with WH6(PMe2Ph)3 gave an equilibrium with [HP4-tBu]+[WH5(PMe2Ph)3]-. From these and a related equilibrium, the pKalphaTHF of [HP4-tBu]+ is found to be 40+/-4. In general, neutral complexes MHx(PR3)n (M=W, Re, Ru, Os, Ir; n=3, 2) studied to date have pKalphaTHF values from 30 to 44 on going from phenyl-substituted to alkyl-substituted phosphine ligands whereas MHx(PR3)n+ (M=Re, Fe, Ru, Os, Co, Rh, Ni, Pd, Pt; n=4, 3), including diphosphine ligands ((PR3)2=PR2-PR2), have values from 12 to 23. From the equilibrium established from the reaction of [HP2-tBu][BPh4] and [K(2,2,2-crypt)][OP(OEt)2NPh], [HP2-tBu]+ was calculated to have a pKalphaTHF of 30+/-4. The equilibrium constant for the similar deprotonation reaction with [K(18-crown-6)][{ReH2(PMePh2)2}2(mu-H)3] confirmed this value.