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Europium (Eu+) ions were confined in a Paul trap and detected by non-destructive method. Storage time of Eu+ ions achieved in vacuum was improved by orders of magnitude employing buffer gas cooling. The experimentally detected signal
was fitted to the ion response signal and the total number of ions trapped was estimated. It is found that the peak signal
amplitude as well as the product of FWHM and the peak signal amplitude is proportional to the total number of trapped ions.
The trapped ion secular frequency was swept at different rates and its effect on the absorption line profile was studied both
experimentally and theoretically. 相似文献
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Eliene O Kozlowski Paula C Lima Cristina P Vicente Tito Lotufo Xingfeng Bao Kazuyuki Sugahara Mauro SG Pavão 《BMC biochemistry》2011,12(1):1-2
After the publication of the work entitled "Dermatan sulfate in tunicate phylogeny: Order-specific sulfation pattern and the effect of [→4IdoA(2-Sulfate)β-1→3GalNAc(4-Sulfate)β-1→] motifs in dermatan sulfate on heparin cofactor II activity", by Kozlowski et al., BMC Biochemistry 2011, 12:29, we found that the legends to Figures 2 to 5 contain serious mistakes that compromise the comprehension of the work. This correction article contains the correct text of the legends to Figures 2 to 5. 相似文献
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Young Derek S. Chen Xi Hewage Dilrukshi C. Nilo-Poyanco Ricardo 《Advances in Data Analysis and Classification》2019,13(4):1053-1082
Advances in Data Analysis and Classification - Finite mixtures of (multivariate) Gaussian distributions have broad utility, including their usage for model-based clustering. There is increasing... 相似文献
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Jinasena W. Hewage 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2014,68(6):1-11
Molecular dynamics simulation (MD) with Sutton-Chen potential for palladium-palladium, nickel-nickel and palladium-nickel interactions has been used to generate the minimum energy structures and to study the thermodynamic and dynamic properties of mixed transition metal cluster motifs of Ni n Pd(13?n) for n ≤ 13. Thirteen particle icosahedral clusters of neat palladium and nickel atoms were first reproduced accordingly with the results in literature. Then in the palladium icosahedra, each palladium atom has been successively replaced by nickel atom. Calculation is repeated for both palladium-centered and nickel-centered clusters. It is found that the nickel-centered clusters are more stable than the palladium-centered clusters and cohesive energy increases along the palladium end to nickel end. Phase transition of each cluster from one end-species to the other end-species is studied by means of caloric curve, root mean square bond fluctuation and heat capacity. Trend in variation of melting temperature is opposite to the energy trend. Palladium-centered cluster shows a premelting at low temperature due to the solid-solid structural transition. Species-centric order parameters developed by Hewage and Amar is used to understand the dynamic behavior in the solid-solid transition of palladium-centered cluster to more stable nickel-centered cluster (premelting). This species-centric order parameter calculation further confirmed the stability of nickel-centered species over those of palladium-centered species and solid-solid structural transition at low temperature. 相似文献
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J. W. Hewage F. G. Amar M.-F. de Feraudy G. Torchet 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):249-252
Using realistic pair potentials, we investigate the
structures of mixed clusters of argon and nitrogen in order to
interpret the experimental electron diffraction patterns
reported by the Torchet group. Simulations of small clusters
indicate that argon tends to segregate at the center of the
clusters. For larger clusters, in the range of 50 to 200
molecules, MC methods have been used to simulate structures that
are likely to be generated in the molecular beam. By comparing
predicted electron diffraction patterns with those recorded in
the experiments, our models allow us to estimate the average
size and composition of the mixed clusters for a given set of
experimental conditions (nozzle stagnation pressure and Ar
partial pressure). 相似文献
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Marc Bria Alan Cooper Shanika Gunatilaka Hewage Margaret Nutley 《Tetrahedron letters》2007,48(48):8430-8433
This Letter, describes the complexation of α-, β- and γ-cyclodextrins (1-3) with TTF derivative 4 in water. In particular, we show using 1H, 13C NMR, UV-vis spectroscopy and isothermal titration calorimetry that β-cyclodextrin 2 forms an effective complex with 4. Complex 2·4 can be conveniently disassembled upon the addition of 1-adamantanol. 相似文献
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A glow assay technology for the detection of a chemical warfare simulant is presented, which is based on modulating the peroxyoxalate chemiluminescence pathway by way of utilising an oximate super nucleophile that gives an "off-on" glow response. 相似文献