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1.
Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co+2FeII) and ferricyanides (Co+2FeIII) in an ozone flow. The CN stretching bands occur at 2085 cm–1 for Co+2FeII and at 2160 cm–1 for Co+2FeIII. After the ozonization process of Co+2FeII, an intense band approximately at 2125 cm–1 is detected. This intermediate band must correspond to a mixed valence state of the type: FeII–CN–Co2+–NC–FeIII Mössbauer spectra recorded in situ during the ozonization of Co+2FeII show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co+2FeII after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable. 相似文献
2.
Herbert Edelsbrunner Leonidas Guibas John Hershberger Raimund Seidel Micha Sharir Jack Snoeyink Emo Welzl 《Discrete and Computational Geometry》1989,4(1):433-466
Anarrangement ofn lines (or line segments) in the plane is the partition of the plane defined by these objects. Such an arrangement consists ofO(n
2) regions, calledfaces. In this paper we study the problem of calculating and storing arrangementsimplicitly, using subquadratic space and preprocessing, so that, given any query pointp, we can calculate efficiently the face containingp. First, we consider the case of lines and show that with (n) space1 and (n
3/2) preprocessing time, we can answer face queries in (n)+O(K) time, whereK is the output size. (The query time is achieved with high probability.) In the process, we solve three interesting subproblems: (1) given a set ofn points, find a straight-edge spanning tree of these points such that any line intersects only a few edges of the tree, (2) given a simple polygonal path , form a data structure from which we can find the convex hull of any subpath of quickly, and (3) given a set of points, organize them so that the convex hull of their subset lying above a query line can be found quickly. Second, using random sampling, we give a tradeoff between increasing space and decreasing query time. Third, we extend our structure to report faces in an arrangement of line segments in (n
1/3)+O(K) time, given(n
4/3) space and (n
5/3) preprocessing time. Lastly, we note that our techniques allow us to computem faces in an arrangement ofn lines in time (m
2/3
n
2/3+n), which is nearly optimal.The first author is pleased to acknowledge the support of Amoco Fnd. Fac. Dev. Comput. Sci. 1-6-44862 and National Science Foundation Grant CCR-8714565. Work on this paper by the fifth author has been supported by Office of Naval Research Grant N00014-87-K-0129, by National Science Foundation Grant NSF-DCR-83-20085, by grants from the Digital Equipment Corporation, and the IBM Corporation, and by a research grant from the NCRD—the Israeli National Council for Research and Development. The sixth author was supported in part by a National Science Foundation Graduate Fellowship. This work was begun while the non-DEC authors were visiting at the DEC Systems Research Center. 相似文献
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5.
van den Brand JF Ent R Anthony PL Arnold RG Arrington J Beise EJ Belz JE Bosted PE Bulten H Chapman MS Coulter KP Dietrich FS Epstein M Filippone BW Gao H Gearhart RA Geesaman DF Hansen J Holt RJ Jackson HE Jones CE Keppel CE Kinney ER Kuhn S Lee K Lorenzon W Lung A Makins NC Margaziotis DJ McKeown RD Milner RG Mueller B Napolitano J Nelson J O'Neill TG Papavassiliou V Petratos GG Potterveld DH Rock SE Spengos M Szalata ZM Tao LH van Bibber K Wasson DA White JL Zeidman B 《Physical review D: Particles and fields》1995,52(9):4868-4871
6.
Makins NC Ent R Chapman MS Hansen J Lee K Milner RG Nelson J Arnold RG Bosted PE Keppel CE Lung A Rock SE Spengos M Szalata ZM Tao LH White JL Coulter KP Geesaman DF Holt RJ Jackson HE Papavassiliou V Potterveld DH Zeidman B Arrington J Beise EJ Belz E Filippone BW Gao H Lorenzon W Mueller B McKeown RD O'Neill TG Epstein M Margaziotis DJ Napolitano J Kinney E Anthony PL van Bibber K Dietrich FS Gearhart RA Patratos GG Kuhn SE van den Brand JF Bulten H Jones CE 《Physical review letters》1994,72(13):1986-1989
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8.
Abstract— 5-Methoxyindole is a non-exciplex forming indole, and its excited state behavior is qualitatively different from that of indole and its methyl substituted derivatives. This fact supports the idea that there are two limiting classes of exciplexes, charge-transfer and dipole-dipole stabilized. The fluorescence quantum yield in water is 0.29 with a lifetime of 4.0 ns at 25d?C. The activation energy for fluorescence quenching in water is 15.9 pM 0.5 kJ/mol, which is smaller than for indole and the methyl substituted indoles which have been measured. In cyclohexane at 25d?C, the fluorescence quantum yield is 0.63 with a lifetime of 6.7 ns. The fluorescence is efficiently quenched by electron scavengers, as is the case for other indoles. Some electron ejection to solvent probably occurs in both solvents. 相似文献
9.
R. Lutter O. Häusser D.J. Donahue R.L. Hershberger F. Riess H. Bohn T. Faestermann F.v. Feilitzsch K.E.G. Löbner 《Nuclear Physics A》1974,229(2):230-240
The g-factor of the 480 ns, 9? isomer at 2.237 MeV in 200Pb was measured by the time-differential perturbed angular distribution method. The result, g = ?0.0285±0.0011 confirms the rather pure quasiparticle structure of this state. Half-lives of 480±20 ns, 43±3 ns and 42±4 ns have been measured for the 2237 keV 9?, 2154 keV 7? states in 200Pb and the 2208 keV state in 202Pb, respectively; E2 transitions and g-factors of negative-parity states in even, neutron-deficient Pb isotopes are discussed. 相似文献
10.
We have analyzed the microwave spectrum of 4-methyl-2-oxetanone (β-butyrolactone) in the ground vibrational state and in the first three excited states of the ring puckering mode. The smooth variation of the rotational constants with vibrational quantum number indicates that the ring puckering potential is essentially single minima. In addition, the structural parameters derived from a diagnostic least-squares fit indicate that the equilibrium configuration of the ring is planar within about three degrees in the dihedral angle. These results are in agreement with the far-ir data, but the single minimum is surprising in view of the small barrier found in 2-oxetanone. The ground-state rotational constants are 9267.92 ± 0.15, 2698.357 ± 0.006, and 2380.008 ± 0.03 MHz. The dipole moment is 4.40 ± 0.06 D, with all uncertainties being the standard deviations determined by the least-squares-fitting procedure. 相似文献