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The intramolecular and long-range ferromagnetic coupling between p-phenylenediamine radical cations in head-to-tail coupled oligo(1, 4-phenyleneethynylene)s and oligo(1,4-phenylenvinylene)s between neighbors and next-nearest neighbors is described. UV/vis/near-IR experiments show that the radical cations are localized in the pendant p-phenylenediamine units of the conjugated oligomers. The ESR spectra of these oligo(1,4-phenyleneethynylene) and oligo(1, 4-phenylenvinylene) di(radical cation)s are consistent with those of a triplet state. A linear behavior is observed for the doubly integrated ESR intensity of the DeltaM(s) = +/-1 and DeltaM(s) = +/-2 signals with the inverse temperature (I approximately 1/T), consistent with Curie's law. This behavior indicates a triplet ground-state diradical with a large triplet-singlet energy gap or possibly a degeneracy of singlet and triplet states. 相似文献
3.
P. M. Hergenrother S. J. Havens 《Journal of polymer science. Part A, Polymer chemistry》1989,27(4):1161-1174
In a continuation of our effort on polyimides containing carbonyl and ether connecting groups between aromatic rings, several new polyimides were prepared and characterized. A few of these polymers were semi-crystalline. Glass transition temperatures ranged from 164 to 258°C and crystalline melt temperatures were observed between 350 and 424°C. The semi-crystalline polyimide from the reaction of 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 1,3-bis(4-aminophenoxy-4′-benzoyl)benzene provided transparent orange films with excellent tensile properties, exceptional resistance to solvents and strong base, and high thermooxidative stability. In addition, this polyimide provided excellent adhesive strength for joining titanium (6A1–4V) to titanium. 相似文献
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J. W. Connell P. M. Hergenrother 《Journal of polymer science. Part A, Polymer chemistry》1991,29(11):1667-1674
Poly(arylene ether imidazole)s were prepared by the aromatic nucleophilic displacement reaction of a bisphenol imidazole with activated aromatic dihalides. The polymers had glass transition temperatures ranging from 230 to 318°C and number-average molecular weights as high as 82,000 g/mol. Thermogravimetric analysis showed a 5% weight loss occurring ~ 400°C in air and ~ 500°C in nitrogen. Typical neat resin mechanical properties obtained at room temperature included tensile strength and tensile modulus of 14.2 and 407 ksi and fracture energy (Glc) of 23 in. lb/in.2 Titanium-to-titanium tensile shear strengths measured at 23 and 200°C were 4800 and 3000 psi, respectively. In addition, preliminary data were obtained on carbon fiber laminates. The chemistry, physical, and mechanical properties of these polymers are discussed. 相似文献
8.
M. S. Sinsky R. G. Bass J. W. Connell P. M. Hergenrother 《Journal of polymer science. Part A, Polymer chemistry》1986,24(9):2279-2295
Novel poly(enamine-ketones) were prepared with inherent viscosities as high as 1.99 dL/g using the Michael-type addition of various diamines to 1,1′-(1,3 or 1,4-phenylene)bis(3-phenyl-2-propyn-1-one) in m-cresol at 60–130°C. Tough, clear, amber films with tensile strengths of 12, 400 psi and tensile moduli of 397, 000 psi were cast from solutions of the polymers in chloroform. The polymers exhibited Tgs as high as 235°C and weight losses of 14% after aging at 232°C in circulating air for 60 h. The synthesis and characterization of several poly(enamine-ketones) are discussed. 相似文献
9.
Martinez-Diaz MV Rodriguez-Morgade MS Feiters MC van Kan PJ Nolte RJ Stoddart JF Torres T 《Organic letters》2000,2(8):1057-1060
[formula: see text] New unsymmetrically substituted DB24C8-phthalocyanines, which are able to form complexes with suitable dialkylammonium cations, have been prepared. These complexes most probably have a pseudorotaxane geometry. 相似文献
10.
J. W. Connell R. G. Bass M. S. Sinsky R. O. Waldbauer P. M. Hergenrother 《Journal of polymer science. Part A, Polymer chemistry》1987,25(9):2531-2542
Two types of polypyrazoles, unsubstituted and phenylated, were prepared by a novel synthetic route involving the cyclopolycondensation of aromatic dihydrazines and aromatic dipropynones. The polymers had inherent viscosities as high as 1.05 dL/g and were soluble in N, N-dimethylacetamide, chloroform (phenylated polypyrazoles only), and sulfuric acid. The polymers exhibited glass transition temperatures ranging from 202 to 266°C and polymer decomposition temperatures (10% weight loss) as measured by thermogravimetric analysis of 400–500°C in air and 465–512°C in nitrogen. The synthesis and characterization of several polypyrazoles are discussed. 相似文献