Donor-acceptor complexes of quinoline N-oxides with boron trifluoride

Molecular n-v complexes of quinoline N-oxides with BF₃ have been studied by electronic and IR spectroscopy. In most case the donor centre is the oxygen atom of the N-oxide group.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1087–1092, August, 1994.     

Onset of crater formation during short pulse laser ablation

We report morphologic changes of metallic surfaces at the onset of ablation, starting from gentle ablation to the emergence of ablation craters. The evolution of both observed melting zones and of ablation craters therein are investigated in dependence of the ablation laser fluence for nanosecond ultraviolet laser pulses. Further, consequences of crater formation for cluster synthesis within the released atomic vapor are pointed out. PACS 52.38.Mf; 79.20.Ds; 65.40.De     

Advantages of NIR radiation use for optical determination of skin horny layer thickness with embedded TiO2 nanoparticles during tape stripping procedure

The tape stripping technique is an experimental method frequently used for reconstruction of the in-depth distribution of various topically administered substances within the horny layer of human skin, e.g., compounds contained in sunscreens. Titanium dioxide (TiO₂) nanoparticles (25–200 nm in diameter) are one such compound. Optical techniques which apply blue light are found to be suitable for reconstruction. However, the presence of particles affects the light propagation within the skin and therefore causes incorrect determination of strip thickness, leading to an improper reconstructed distribution of nanoparticle concentration revealed from the experimental data. This study evaluates the errors emerging from the use of blue (400 nm) and NIR (800 nm) radiation and finds the use of longer wavelength light more advantageous. Particles of different diameters are considered, and it is revealed that the application of small particles (25–60 nm) results in the lowest rate of error.     

Portable and Automatic Mössbauer Analysis

A portable Mössbauer spectrometer, developed for extraterrestrial applications, opens up new industrial applications of MBS. But for industrial applications, an available tool for fast data analysis is also required, and it should be easy to handle. The analysis of Mössbauer spectra and their parameters is a barrier for the popularity of this wide-applicable spectroscopic technique in industry. Based on experience, the analysis of a Mössbauer spectrum is time-consuming and requires the dedication of a specialist. However, the analysis of Mössbauer spectra, from the fitting to the identification of the sample phases, can be faster using by genetic algorithms, fuzzy logic and artificial neural networks. Industrial applications are very specific ones and the data analysis can be performed using these algorithms. In combination with an automatic analysis, the Mössbauer spectrometer can be used as a probe instrument which covers the main industrial needs for an on-line monitoring of its products, processes and case studies. Some of these real industrial applications will be discussed.     

The complexity of cutting complexes

This paper investigates the combinatorial and computational aspects of certain extremal geometric problems in two and three dimensions. Specifically, we examine the problem of intersecting a convex subdivision with a line in order to maximize the number of intersections. A similar problem is to maximize the number of intersected facets in a cross-section of a three-dimensional convex polytope. Related problems concern maximum chains in certain families of posets defined over the regions of a convex subdivision. In most cases we are able to prove sharp bounds on the asymptotic behavior of the corresponding extremal functions. We also describe polynomial algorithms for all the problems discussed.Bernard Chazelle wishes to acknowledge the National Science Foundation for supporting this research in part under Grant No. MCS83-03925. Herbert Edelsbrunner is pleased to acknowledge the support of Amoco Fnd. Fac. Dev. Comput. Sci. 1-6-44862.     

Linear Independence of q-Analogues of Certain Classical Constants

Let K be ? or an imaginary quadratic number field, and q ∈ K an integer with ¦q¦ > 1. We give a quantitative version of Σ_n≥1 a_n/(qⁿ ? 1) ? K for non-zero periodic sequences (a_n) in K of period length ≤ 2. As a corollary, we get a quantitative version of the linear independence over K of 1, the q-harmonic series, and a q-analogue of log 2. A similar result on 1, the q-harmonic series, and a q-analogue of ζ(2) is also proved. Mathematics Subject Classification (2000): 11J72, 11J82     

Strangeness saturation: Dependence on system-size, centrality and energy

The dependence of the strangeness saturation factor on the system size, centrality and energy is studied in relativistic heavy-ion collisions.