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1.
From phasebarograms it is possible to construct phase diagrams. We show on example of the system Bi/Se/O how follow ternary sections from the total pressure measurements in equilibrium and how we can attribute the barogram of the ternary region Bi2Se3/Bi2O2Se/Se to the binary system Bi2Se3/Se. The knowledge of the ternary system Bi/Se/I and its coexistent pressure courses allow to followT-p-x conditions for the chemical transport of phases from this system.
  相似文献   
2.
Dissoziation Behaviour of Dimerie Metal Halides and the Formation of MnAl2Cl8 The thermal dissoziation was measured of the gaseous dimeric metal halides Al2Cl6, Ga2Cl6, In2Cl6, and Mn2I4 and the formation of the gaseous chloride complex MnAl2Cl8 by MnCl2,f and Al2Cl6,g in a membrane manometer. The enthalpy and the entropy of these reactions were derived.  相似文献   
3.
On the Reaction of Germanium with Germanium Tetrachloride and on the Existence of the Oxidechlorides GeOCl2 and GeOCl6 at the Equilibrium The above equilibrium was measured in a Gauge-manometer and the enthalpy of formation and the entropy for GeCl2,g were derived from these results. From total pressure measurements and transport experiments of GeO2 with GeCl4 follows, that the oxidechlorides Ge2OCl6 and GeOCl2 are not present in measurable concentrations, that means the enthalpy of formation of GeOCl2 must be higher than ?327 kJ · mol?1.  相似文献   
4.
Coexistence Relations, Preparation and Properties of Ternary Compounds in the System Cu/Mo/O The phase diagram of the ternary system Cu/Mo/O is presented at 773 K. The compounds CuMoO4, Cu3Mo2O9, Cu4Mo5O17, Cu6Mo5O18, Cu4–xMo3O12, and CuxMoO3 are found to be thermodynamical stable. The homogeneity range of Cu4–xMo3O12 runs to x = 0.1–0.2. Single crystals of CuMoO4 and Cu3Mo2O9 were grown by chemical transport reactions with TeCl4, Cl2, HCl, and Br2 as transport agent. The results were compared with thermochemical calculations. The decomposition of CuMoO4 and Cu3Mo2O9 was investigated with thermal analysis and decompositon pressure measurements.  相似文献   
5.
Chemical Transport of Iron Sulphide. II. Experimental Results on the Transport of FeSx with Iodine It is possible to deposite monocrystals of iron sulphide FeSx by means of CTR method using iodine as transport agent. The presence of sufficient, high sulfur partial pressures is the most important condition for the FeSx being transported, in other words: x must be equal or greater than approximately 1.04. The transport velocity and the shape of the deposited crystals depend on temperature, amount of iodine, and composition of the original material. The expected differences between the composition of the deposited solid and that of the residue can be verified experimentally.  相似文献   
6.
7.
The Chemical Transport of VO2 with Cl2 and HCl + Cl2 and the Influence of the O2-Coexistence Equilibrium Pressure on the Transport Behaviour The transport behaviour of VO2 with Cl2, HCl, and Cl2 was calculated and compared with the experimental results. VO2 with the upper phase boundary transports with HCl and HCl + Cl2 from the colder to the hotter zone, VO2 of the lower phase boundary does not transport with HCl. The composition of the deposited VO2 is near the upper boundary oxygen richer than in the start space. VO2 does not transport with Cl2.  相似文献   
8.
Preparation of Ammonium Rare Earth Halides totally free of Water Ammonium rare earth halides totally free of traces of water were prepared in an one step synthesis from metal, ammonium halide, and halogen in a two step temperature regime.  相似文献   
9.
The ternary phases existing on the quasi binary section CoSi/FeSi and CoSi2/β‐FeSi2 have been investigated by solid state reactions and chemical transport. The solid solution serie CoxFe1‐xSi can be described as a regular solution. The transport behaviour calculated is in good agreement with the experiments. The phases have been characterized by X‐ray powder diffraction, EDX and ICP‐OES. The temperature dependence of the resistivity has been measured from 20 K up to room temperature on single crystals.  相似文献   
10.
We calculate fluctuation effects on Bose condensation type superconductivity in the strong coupling negative U Hubbard model by means of a new loop expansion. Our method is based on a spin-dependent modification of the Popov-Fedotov trick. We replace the Popov-Fedotov chemical potential by a fictitious imaginary magnetic field. This field is absorbed in spindependent semionic Matsubara frequencies, which allows for a mixed statistics representation of the anisotropic quantum spin 1/2 Heisenberg model. We report results at one loop order for the superconducting order parameter , for the critical temperature, for the chemical potential, and for the excitation spectra both above and belowT c. We identify mean field results in zeroth loop order and we find both dimensional and filling (v-)depending singularities in interaction fluctuations at one loop order. Renormalization of dimensional singularities is carried out in 4 dimensions. Divergencies withv (1–v)0 in the dilute limits indicate the breakdown of mean field solutions, but superconductivity persists for arbitrarily smallv(1–v) if our loop expansion is interpreted by exponential behaviour as it is suggested by the abelian nonlinear sigma model.  相似文献   
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