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John A. Wells Glen W. Hedrick 《Journal of polymer science. Part A, Polymer chemistry》1973,11(3):661-670
Thermoplastic polyurethane elastomers incorporating the resin acid-derived 12-hydroxymethylabietanol (12-HMA) were prepared, and some physical properties are reported. A polyester macroglycol was prepared from 12-HMA, adipic acid, and ethylene glycol. This macroglycol then was combined with either poly(tetramethylene adipate) glycol (PTAd) or poly(ethylene adipate) glycol (PEAd) and 1,4-butanediol to give a glycol blend of 300 average hydroxyl equivalent weight (OHE). The glycol mixture then was combined with diphenylmethane 4,4′-diisocyanate (MDI) (NCO/OH = 1.0) to give urethane polymers soluble in tetrahydrofuran. Polymers were prepared with 0, 5, 10, 15, 20, and 25%, by weight, 12-HMA with PTAd as the other macroglycol and with 0, 10, 15, and 20% 12-HMA with PEAd as the other macroglycol. At 15% 12-HMA, polymers were made from glycol mixtures having 275 and 350 average OHE to demonstrate the effect of changing the hard-segment concentration. The presence of 12-HMA is shown to have its maximum effect on tensile properties at 15–20% in the PTAd series and at 10% in the PEAd series. In general, this effect is an increase in tensile strength and modulus and a decrease in elongation when compared with a similar polymer without the 12-HMA. 相似文献
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Matthew Myers Eric F. Connor Thierry Glauser Andreas Mck Gregory Nyce James L. Hedrick 《Journal of polymer science. Part A, Polymer chemistry》2002,40(7):844-851
A new metal‐free synthetic approach to the controlled ring‐opening polymerization (ROP) of lactide with nucleophilic phosphines as transesterification catalysts is described. P(Bu)3, PhPMe2, Ph2PMe, PPh3, and related phosphines are commercially available, inexpensive catalysts that generate narrowly dispersed polylactides with predictable molecular weights. These organic catalysts must be used in combination with an initiator, such as an alcohol, to generate an alcoholate ester α‐end group upon ROP. A likely polymerization pathway is through a monomer‐activated mechanism, with minimal active species, facilitating narrow molecular weight distributions. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 844–851, 2002; DOI 10.1002/pola.10168 相似文献
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James L. Hedrick W. Volksen Dillip K. Mohanty 《Journal of polymer science. Part A, Polymer chemistry》1992,30(10):2085-2097
Imide-aryl ether ketone block copolymers were prepared and their morphology and thermal and mechanical properties investigated. Two aryl ether ketone blocks were incorporated; the first was an amorphous block derived from bisphenol–A and the second block was a semi-crystalline poly(aryl ether ether ketone) prepared from a soluble and amorphous ketimine precursor. Bis(amino) aryl ether ketone and aryl ether ketimine oligomers were prepared via a nucleophilic aromaic substitution reaction with molecular weights ranging from 6,000 to 12,000 g/mol. The oligomers were co-reacted with 4,4′-oxydianiline (ODA) and pyromellitic dianhydride (PMDA) diethyl ester diacyl chloride in N-methyl–2-pyrrolidone (NMP) in the presence of N-methylmorpholine. The copolymer compositions, determined by H-NMR, of the resulting amic ester based copolymers ranged from 8 to 50 wt % aryl ether ketone or ketimine content. Prior to imide formation, the ketimine moiety of the aryl ether ketimine block was hydrolyzed (p-toluene sulfonic acid) to the ketone form producing the aryl ether ether ketone block. Compositions of this block were maintained low to retain solubility. Solutions of the copolymers were cast and cured to effect imidization, producing clear films with high moduli (ca. 2200 MPa) and elongations (33–100%). The copolymers displayed good thermal stability with decomposition temperatures in excess of 450°C. Multiphase morphologies were observed irrespective of the co-block type, block length or composition. © 1992 John Wiley & Sons, Inc. 相似文献
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Yan Li Dr. Kazuki Fukushima Dr. Daniel J. Coady Dr. Amanda C. Engler Dr. Shaoqiong Liu Yuan Huang Dr. John S. Cho Dr. Yi Guo Dr. Lloyd S. Miller Dr. Jeremy P. K. Tan Dr. Pui Lai Rachel Ee Dr. Weimin Fan Prof. Yi Yan Yang Dr. James L. Hedrick 《Angewandte Chemie (International ed. in English)》2013,52(2):674-678
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C. J. G. Plummer J. L. Hedrick S. Hauert J. G. Hilborn H.-H. Kausch 《Journal of Polymer Science.Polymer Physics》1996,34(13):2177-2192
We have prepared triblock copolymers of poly(phenylene oxide) (PPO) and polysulphone (PSF) of the form PPO–PSF–PPO in order to assess their intrinsic mechanical properties and their potential as interfacial compatibilizers in polystyrene/PSF blends. For sufficiently long polysulphone block lengths, we observed microphase separation both in the triblock copolymers and in their blends with polystyrene. The triblock polymers, nevertheless, showed very similar microdeformation behavior to the PPO homopolymer, suggesting the phase separation to play a minor role. On the other hand, the compatibility of the poly(phenylene oxide) blocks and polystyrene ensured a high degree of interphase adhesion in blends containing both polystyrene and free PSF, even for relatively high homopolymer molecular weights. © 1996 John Wiley & Sons, Inc. 相似文献
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A concise, efficient approach to the total synthesis of ningalin B (1) based on a heterocyclic azadiene Diels-Alder strategy (1,2,4,5-tetrazine-->1,2,-diazine-->pyrrole) ideally suited for construction of the densely functionalized pyrrole core found in the natural product is detailed. Examination of the natural product and a number of synthetic intermediates revealed that while lacking inherent cytotoxic activity, many reverse the multidrug-resistant (MDR) phenotype, resensitizing a human colon cancer cell line (HCT116/VM46) to vinblastine and doxorubicin at lower doses than the prototypical agent verapamil. 相似文献