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排序方式: 共有263条查询结果,搜索用时 0 毫秒
1.
J. P. Bucher D. C. Douglass P. Xia B. Haynes L. A. Bloomfield 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,19(4):251-254
A new apparatus for measuring the magnetic properties of metal clusters has been constructed. The technique involves the conventional Stern-Gerlach deflection scheme together with modern pulsed laser vaporization source technology and time of flight mass spectrometry. High field seeking monodirectional deflections have been measured for cobalt clusters containing between 40 and 400 atoms. The measured magnetic moments per atom are found to be lower than the known values for the bulk. Special attention has been given to velocity measurements of the metal clusters and the carrier gas atoms in the beam. The residence time of the particles in the source cavity has been measured. 相似文献
2.
J. H. Augustson J. W. Haynes T. W. Sanders 《Journal of Radioanalytical and Nuclear Chemistry》1980,60(2):373-383
A method for the determination of uranium based on235U thermal neutron fission, has been developed and employed on samples of ashed fish tissue and seaweed. The method involves
a post-irradiation ion exchange separation of iodine isotopes. The 884 keV photopeak of134I is used for measurement. Uranium detection limits in the samples concerned have been estimated to be 1·10−8g in terms of natural uranium. The precision achieved in analysing several series of 3–5 samples was 4–10 per cent. The accuracy
of the method was tested by employing an independent neutron activation procedure based on239U measurement. The accuracy of both methods was checked by analysing NBS SRM 1571 ‘Orchard Leaves’. 相似文献
3.
Cooper B Eckert D Andon NL Yates JR Haynes PA 《Journal of the American Society for Mass Spectrometry》2003,14(7):736-741
We describe the identification of a previously uncharacterized plant virus that is capable of infecting Nicotiana spp. and Arabidopsis thaliana. Protein extracts were first prepared from leaf tissue of uninfected tobacco plants, and the proteins were visualized with two-dimensional electrophoresis (2-DE). Matching gels were then run using protein extracts of a tobacco plant infected with tobacco mosaic virus (TMV). After visual comparison, the proteins spots that were differentially expressed in infected plant tissues were cut from the gels and analyzed by high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). Tandem mass spectrometry data of individual peptides was searched with SEQUEST. Using this approach we demonstrated a successful proof-of-concept experiment by identifying TMV proteins present in the total protein extract. The same procedure was then applied to tobacco plants infected with a laboratory viral isolate of unknown identity. Several of the differentially expressed protein spots were identified as proteins of potato virus X (PVX), thus successfully identifying the causative agent of the uncharacterized viral infection. We believe this demonstrates that HPLC-MS/MS can be used to successfully characterize unknown viruses in infected plants. 相似文献
4.
Quantum chemical calculations were carried out to study the interaction of hydrogen sulfide with molecular oxygen in the gas phase. The basic mechanism, the rates of reaction, and the potential energy surface were calculated. Isomers and transition states that connect the reactants with intermediates and products of reaction were identified using the G2 method and B3LYP/6-311+G(3df,2p) functional. Hydrogen abstraction to form HO2 + SH is the dominant product channel and proceeds through a loose transition state well-described at the level of calculation employed. The temperature dependence of the rate coefficient in the range 300-3000 K has been determined on the basis of the ab initio potential energy surface and with variational transition-state theory. The reaction is 169.5 kJ mol(-1) endothermic at 0 K with a rate constant given by 2.77 x 10(5) T(2.76) exp(-19 222/T) cm3 mol(-1) s(-1) and should proceed slowly under atmospheric thermal conditions, but it offers a route to the initiation of H2S combustion at relatively low temperatures. 相似文献
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Clayton A. Whitmore Mariam I. Boules William J. Behof Justin R. Haynes Dmitry Koktysh Adam J. Rosenberg Mohammed N. Tantawy Wellington Pham 《Molecules (Basel, Switzerland)》2021,26(8)
Promethazine, an antihistamine drug used in the clinical treatment of nausea, has been demonstrated the ability to bind Abeta in a transgenic mouse model of Alzheimer’s disease. However, so far, all of the studies were performed in vitro using extracted tissues. In this work, we report the design and synthesis of a novel [11C]promethazine PET radioligand for future in vivo studies. The [11C]promethazine was isolated by RP-HPLC with radiochemical purity >95% and molar activity of 48 TBq/mmol. The specificity of the probe was demonstrated using human hippocampal tissues via autoradiography. 相似文献
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9.
Asner DM Dytman SA Mehrabyan S Mueller JA Nam S Savinov V Huang GS Miller DH Pavlunin V Sanghi B Shibata EI Shipsey IP Adams GS Chasse M Cummings JP Danko I Napolitano J Cronin-Hennessy D Park CS Park W Thayer JB Thorndike EH Coan TE Gao YS Liu F Stroynowski R Artuso M Boulahouache C Blusk S Butt J Dambasuren E Dorjkhaidav O Haynes J Menaa N Mountain R Muramatsu H Nandakumar R Redjimi R Sia R Skwarnicki T Stone S Wang JC Zhang K Mahmood AH Csorna SE Bonvicini G Cinabro D Dubrovin M Bornheim A 《Physical review letters》2004,92(14):142001
We report on the observation of the eta(')(c)(2(1)S0), the radial excitation of the eta(c)(1(1)S0) ground state of charmonium, in the two-photon fusion reaction gammagamma-->eta(')(c)-->K(0)(S)K+/-pi(-/+) in 13.6 fb(-1) of CLEO II/II.V data and 13.1 fb(-1) of CLEO III data. We obtain M(eta(')(c))=3642.9+/-3.1(stat)+/-1.5(syst) MeV and M(eta(c))=2981.8+/-1.3(stat)+/-1.5(syst) MeV. The corresponding values of hyperfine splittings between 1S0 and 3S1 states are DeltaM(hf)(1S)=115.1+/-2.0 MeV and DeltaM(hf)(2S)=43.1+/-3.4 MeV. Assuming that the eta(c) and eta(')(c) have equal branching fractions to K(S)Kpi, we obtain Gamma(gammagamma)(eta(')(c))=1.3+/-0.6 keV. 相似文献
10.
Alan Haynes 《Journal of Number Theory》2004,107(1):95-104
We will examine the subset of Farey fractions of order Q consisting of those fractions whose denominators are not divisible by a fixed prime p. In particular, we will provide an asymptotic result on the distribution of H-tuples of consecutive fractions in , as Q→∞. 相似文献