Effects of length and number of aromatic rings in carboxylic acid ligands on structure and optical properties of lead(II) coordination polymers

Research on Chemical Intermediates - To systematically examine the effects of the length and number of aromatic rings in carboxylic acid ligands on the structure and properties of lead(II)...     

Preparation of tin oxide (IV) nanoparticles by a green chemistry method and investigation of its role in the removal of organic dyes in water purification

Research on Chemical Intermediates - In this research, tin oxide nanoparticles (SnO2-nanoparticles) are synthesized using sol–gel method in polymeric bed and considering the principals of...     

Variable density formation by intense microwave beams near the critical density

Modification of electron density of an inhomogeneous, unmagnetized plasma by the relativistic ponderomotive force of intense microwave beams near the critical density is studied. Using the Maxwell and fluid equations and taking into account the relativistic mass, relativistic ponderomotive force, linear inhomogeneity for electron temperature, and tangential inhomogeneity for electron density, the non‐linear electron density, non‐linear dielectric permittivity, and non‐linear wave equations are derived. Results show that positive and negative values of σ₁ and σ₂ (degree of inhomogeneity of the background electron density and electron temperature, respectively) parameters can affect the electric and magnetic field profiles. In addition, profiles of the non‐linear electron density indicate that by decreasing the σ₁ parameter, the amplitude of the peaks increases near the critical density. For positive values of the σ₂ parameter, by increasing this parameter the amplitude of the peaks increases, while for negative values of the σ₂ parameter, by decreasing this parameter the amplitude of the peaks increases.     

Surfactant-Free Hydrothermal Synthesis of Mesoporous Niobia Samples and Their Photoinduced Decomposition of Terephthalic Acid (TPA)

This study introduces a low temperature surfactant-free hydrothermal method to synthesize mesoporous Nb₂O₅ photocatalysts using NbCl₅ and H₂O₂ as precursors that are subsequently calcinated at 300, 400 and 450 °C and are assigned as mNb₂O₅-300, mNb₂O₅-400 and mNb₂O₅-450, respectively. Commercial niobia sample was used as reference sample for comparison purpose. All of materials were characterized by XRD, SEM, UV–Vis DRS, FTIR, TG/DTG and BET techniques. The synthesized Nb₂O₅ particles especially mNb₂O₅-300 sample shows a high surface area (240 m²/g), a large pore volume (0.21 cm³/g) and an identifying morphology of these features. Photocatalytic decomposition of terephthalic acid was evaluated using UV–Vis spectrophotometer. The photocatalytic reactions followed pseudo-first-order kinetics with an apparent rate constant of k = 105 × 10^?3 min^?1 for mNb₂O₅-300 sample with the highest activity among all samples at natural pH (pH = 6). Meanwhile, it was observed that optimum pH of 4 resulted in fast photocatalytic reaction for mNb₂O₅-300 sample.     

Enhancement of electron density in the interaction of high-power electromagnetic waves with inhomogeneous magnetized plasma

Propagation characteristics of a high-power electromagnetic wave through an inhomogeneous magnetized plasma is investigated. Considering the momentum transfer equations for electrons and ions and taking into account the ponderomotive force, the distribution of electron density and dielectric permittivity are obtained. Using non-linear dielectric permittivity and Maxwell's equations in the absence of external current and charge densities, non-linear wave equations are achieved. The results indicate that the external static magnetic field can modify the profiles of both the electric and magnetic fields. It is also shown that the external static magnetic field enhances the amplitude of the electron density and the non-linear dielectric permittivity.     

Characterization of water-soluble,cationic polyelectrolytes as exemplified by poly(acrylamide-co-trimethylammoniumethylethacryate chloride) and the establishment of structure-property relationships

The cationic copolymerization products of poly (acrylamide-co-trimethylammoniumethylmethacrylate chloride (PTMAC) having cationic monomer percentages of 8%, 25%, and 50% as well as the cationic homopolymer, were characterized with respect to their molecular dimensions. The light-scattering and viscometric measurements were carried out for molecular weights ranging from 200 000 to 12 800 000 g/mol in 1 M NaCl solution at 25°C. It was possible to establish a relationship between the molecular weight and the two parameters: intrinsic viscosity and radius of gyration, for all four polymers.Rheological investigations of the flow properties in 1 M NaCl solution were also carried out using the polymer with a cationic monomer of 50% (PTMAC 50). Structure-property relationships were formulated which made it possible to describe and predict the shear viscosity, both in the zero-shear region (Newtonian region) and in the shear-dependent region (non-Newtonian region) as a function of the polymer concentration, the molecular weight, and shear rate.Abbreviations a exponent of the []-M relationship - A ₂ 2^nd virial coefficient/mol·cm³·g^–2 - AAm acrylamide - b slope of the flow-curve in the shear-rate dependent region - c concentration/g·cm^–3 - dn/dc refractive index increment/cm³·g^–1 - f function - K constant of the []-M relationship/cm³·g^t-1 - m _c proportion of cationic monomers/mol % - M molecular weight/g·mol^–1 - M _w weight-average molecular weight/g·mol^–1 - M _n number-average molecular weight/g·mol^–1 - NaCL sodium chloride - PAAm polyacrylamide - PS polystyrene - PTMAC poly(acrylamide-co-trimethylammoniumethylme thacrylate chloride) - R_G ^20.5 radius of gyration/nm - TMAC trimethylammoniumethylmethacrylate chloride - shear rate/s^–1 - critical shear rate/s^–1 - viscosity/Pa·s - 0 zero-shear viscosity/Pa·s - _s solvent viscosity/Pa·s - _sp specific viscosity - [] intrinsic viscosity/cm³·g^–1 - relaxation time/s     

Triethylammonium Fluorochromate—A New,Mild, Stable,and Inexpensive Chromium (VI) Oxidant

Triethylammonium fluorochromate was prepared and was used to quantitatively oxidize a number of organic substrates. Triethylammonium fluorochromate is a versatile reagent ensuring effective and selective oxidation of organic compounds, in particular of alcohols, under mild conditions.     

Ligand preferences in ytterbium ions complexation with carboxylate-based metal-organic frameworks

Two coordination polymers of ytterbium were synthesized by employing 4,4′,4″-s-triazine-2,4,6-triyl-tribenzoic acid (H₃TATB), 4,4′,4-benzene-1,3,5-triyl-tribenzoic acid (H₃BTB), and 3,5-pyridinedicarboxylic acid (3,5-PDC) ligands and were characterized by single-crystal X-ray diffraction analysis. Reaction of ytterbium(III) chloride in the presence of H₃BTB and 3,5-PDC ligands gives preferred complexation with the 3,5-PDC ligand, producing [Yb₂(3,5-PDC)(ClO₄)₃][NH(Me)₃] (1). However, under exactly the same reaction conditions, reaction of ytterbium(III) chloride in the presence of 3,5-PDC and H₃TATB resulted in complexation with H₃TATB to form [(CH₃)₂NH₂][Yb₄(TATB)₄(HCO₂)(H₂O)₂]·3H₂O (2). The crystal structure results showed a layered structure for 1 and a metal-organic framework structure for 2. This indicates that the complexation preference of the ytterbium ion is H₃TATB ≥ 3,5-PDC ≥ H₃BTB. Conversely, the uncomplexed ligand in the metal-organic framework (2) is an auxiliary agent during the synthesis, which shows polytopic linker controls crystal properties, to form suitable crystals for single-crystal structure determination. The prepared coordination compounds were used as heterogeneous catalysts in an oxidation amidation reaction with different aldehydes and benzylamine hydrochloride.