全文获取类型
收费全文 | 580篇 |
免费 | 4篇 |
国内免费 | 3篇 |
专业分类
化学 | 474篇 |
晶体学 | 4篇 |
力学 | 3篇 |
数学 | 19篇 |
物理学 | 87篇 |
出版年
2020年 | 3篇 |
2018年 | 3篇 |
2014年 | 10篇 |
2013年 | 24篇 |
2012年 | 20篇 |
2011年 | 26篇 |
2010年 | 18篇 |
2009年 | 18篇 |
2008年 | 23篇 |
2007年 | 25篇 |
2006年 | 27篇 |
2005年 | 22篇 |
2004年 | 16篇 |
2003年 | 20篇 |
2002年 | 19篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 7篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1996年 | 19篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 8篇 |
1990年 | 9篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 16篇 |
1984年 | 13篇 |
1983年 | 12篇 |
1982年 | 9篇 |
1981年 | 8篇 |
1980年 | 15篇 |
1979年 | 12篇 |
1978年 | 11篇 |
1977年 | 12篇 |
1976年 | 7篇 |
1975年 | 9篇 |
1974年 | 8篇 |
1973年 | 3篇 |
1972年 | 9篇 |
1970年 | 2篇 |
1969年 | 5篇 |
1968年 | 4篇 |
1967年 | 3篇 |
1965年 | 2篇 |
排序方式: 共有587条查询结果,搜索用时 15 毫秒
1.
Takayuki Yaegashi Shinya Yodoya Masahiko Nakamura Hiroki Takeshita Katsuhiko Takenaka Tomoo Shiomi 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):999-1007
Free‐radical homo‐ and copolymerization behavior of N,N‐diethyl‐2‐methylene‐3‐butenamide (DEA) was investigated. When the monomer was heated in bulk at 60 °C for 25 h without initiator, rubbery, solid gel was formed by the thermal polymerization. No such reaction was observed when the polymerization was carried out in 2 mol/L of benzene solution with with 1 mol % of azobisisobutyronitrile (AIBN) as an initiator. The polymerization rate (Rp) equation was Rp ∝ [DEA]1.1[AIBN]0.51, and the overall activation energy of polymerization was calculated 84.1 kJ/mol. The microstructure of the resulting polymer was exclusively a 1,4‐structure where both 1,4‐E and 1,4‐Z structures were included. From the product analysis of the telomerization with tert‐butylmercaptan as a telogen, the modes of monomer addition were estimated to be both 1,4‐ and 4,1‐addition. The copolymerizations of this monomer with styrene and/or chloroprene as comonomers were also carried out in benzene solution at 60 °C. In the copolymerization with styrene, the monomer reactivity ratios obtained were r1 = 5.83 and r2 = 0.05, and the Q and e values were Q = 8.4 and e = 0.33, respectively. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 999–1007, 2004 相似文献
2.
Hyperfine interaction constants (HFICs) of dangling bonds for CN and SiN films were calculated by density-functional theory. The averaged 14N isotropic HFICs for C dangling bonds are almost equal to those for Si dangling bonds. The anisotropic 14N HFICs calculated for C dangling bonds are larger than those for Si dangling bonds by a factor 2. The calculated results were compared with experimental results obtained by electron spin resonance and electron nuclear double resonance. It was indicated that the carbon dangling bonds are located such that they avoid N atoms in CN films. 相似文献
3.
Syun-ichi Kiyooka Yushi Takeshita Yoshinori Tanaka Takafumi Higaki Yosuke Wada 《Tetrahedron letters》2006,47(26):4453-4456
A dicationic ((−)-sparteine)palladium complex underwent a superior catalytic enantioselective aldol reaction of aldehydes with 1-phenyl-1-trimethylsilyloxyethene performing satisfactorily, starting with ((−)-sparteine)PdCl2 and AgSbF6 as catalyst precursors (1 mol % loading) in the presence of 3 Å molecular sieves over the reaction. 相似文献
4.
Photochemical deprotection of nitro-substituted benzenesulfenates via photoinduced electron transfer
Kan Wakamatsu Mitsuru Kouda Kazuyoshi Shimaoka Haruo Yamada 《Tetrahedron letters》2004,45(34):6395-6398
The photochemical deprotection of alkyl 2,4-dinitrobenzenesulfenate or alkyl 2-nitrobenzenesulfenate was successfully achieved by addition of triethylamine, while it was unsuccessful without triethylamine. The sulfur-oxygen bond cleavage is thought to occur heterolytically in the sulfenate anion radical produced by photoinduced electron transfer with triethylamine. 相似文献
5.
Tomoji Kumano Yoshifumi Ohata Norikazu Fujii Yoshiyuki Ushigami Tetsuro Takeshita 《Journal of magnetism and magnetic materials》2006
All kinds of high-permeability GO are manufactured using AlN as the main inhibitor. From a purely metallurgical viewpoint, three types of inhibitor preparation for high-permeability GO have been shown. They include a complete solution without nitriding, a complete precipitation with nitriding and a partial precipitation with nitriding. In this study, another possibility, i.e., a complete solution method with nitriding, was investigated to avoid the extra high-temperature slab reheating and to examine the effect of nitriding on GO bearing Al. This method can also provide the sharp Goss texture, and nitriding is shown to be very useful for changing the inhibitor intensity, depending on the primary grain size. 相似文献
6.
Haruo Sato 《Hyperfine Interactions》1990,57(1-4):2089-2094
Mössbauer spectra of ferrocene adsorbed on silica gel were measured in order to study the state of adsorption. Ferrocene adsorbed on silica gel tended to oxidize in air and form ferricenium ion. It is assumed that the oxidation of adsorbed ferrocene was caused by surface hydroxyls on the silica gel and O2 in air. It was observed that ferrocene adsorbed weakly at 293 K, although the ferricenium ion adsorbed strongly at 293 K. Thus the adsorption states of ferrocene depend on the experimental condition. 相似文献
7.
8.
9.
Tomonari Wakabayashi Daisuke Kasuya Haruo Shiromaru Shinzo Suzuki Koichi Kikuchi Yohji Achiba 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):414-417
Systematic fractional change in the yield of various isomers of fullerenes was revealed to strongly depend on temperature of a buffer gas. A new kinetic consideration is proposed for understanding the observed temperature- and pressure-dependence of yield of fullerenes. The model consists of three competitive reactions in consideration of plausible behaviors of a precursor, (1) decomposition into smaller fragments, (2) isomerization leading to formation of a stable fullerene cage, and (3) growth into a larger carbon cluster. Arrhenius activation energy of formation of stable fullerenes was determined to be 0.8 eV for both C60 and C70, while a higher energy of 2.0?3.3 eV for seven different isomers of higher fullerenes ranging from C76 to C84. Correlation in the activation energy is noted for a series of higher fullerenes with different sizes, suggesting the existence of a specific precursor in their formation processes. 相似文献
10.
Sulfate ion in river water is determined by flow injection analysis at a rate of 30 samples per hour; the sulfate contents are typically less than 30 ppm. The reagent solution contains dimethylsulfonazo-III, barium chloride, potassium nitrate and chloroacetate buffer in 70% () ethanol, and is saturated with barium sulfate. The aqueous carrier stream is also saturated with barium sulfate. The sample is filtered and treated with Amberlite IR120-B cation-exchanger before injection into the carrier stream, and the decoloration of the barium—dimethylsulfonazo-III complex by sulfate is measured at 662 nm. The calibration graph is linear over the range 0–30 μg ml-1 for sulfate in water. 相似文献