排序方式: 共有1条查询结果,搜索用时 0 毫秒
1
1.
Hans-jürgen Buschmann Lucia Mutihac Eckhard Schollmeyer 《Journal of inclusion phenomena and macrocyclic chemistry》2005,53(1-2):85-88
Alkyl amines are able to form complexes with either crown ethers or cyclodextrins or cucurbit[6]uril. The same is known for
polyamines such as spermidine and spermine. However, the simultaneous formation of such polyamines with crown ethers and cucurbit[6]uril
has not been studied. The ability of polyamines such as spermidine and spermine to form mixed complexes with different ligands,
e.g. crown ethers and cucurbit[6]uril has been studied in aqueous solution using pH-metric and calorimetric titrations. The
thermodynamic data of reaction between crown ethers with spermidine, spermine and their cucurbit[6]uril complexes have been
determined. The presence of cucurbit[6]uril on the polyamines has no important influence upon the reaction of these amines
with crown ethers. The reactions between polyamines, cucurbit[6]uril and crown ethers are simple examples for the self organization
of molecules due to specific interactions.
Received in final form: 26 January 2005 相似文献
1