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A four-step synthesis starting from tri-O-acetyl-D-glucal leads to chiral trioxadecalin compounds containing a cyano group. The mesogenic properties of a homologous series of liquid crystals are reported; for two derivatives a helix inversion of the cholesteric phase is observed.  相似文献   
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We present a homologeous series of liquid crystalline trioxadecalin compounds having a terminal alkoxy chain and a nitro group. The (1S, 3R, 6R,8R)-3-(4'-nitrophenyl)-8-(4'-octoxyphenyl)-2,4, 7-trioxabicyclo [4.4.0]decane 2 c shows a temperature-dependent inversion of the cholesteric helix at lower temperatures. For higher temperatures, the reciprocal helical pitch reaches a minimum, then it increases, tending to a second inversion point just above the clearing point. An additional chiral centre in the side chain leads for nitro compounds 3 to non-mesomorphic behaviour. For the cyano compounds 4, the change in the cholesteric helix is suppressed, for the R configuration, but for the S configuration helical inversion occurs at high temperatures and selective reflection above the transition to the TGBA phase.  相似文献   
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Ohne Zusammenfassung Vorgelegt von L. Collatz Die vorliegende (zweiteilige) Abhandlung ist eine Überarbeitung der Habilitationsschrift des Verfassers.  相似文献   
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We have investigated the behaviour of chiral carbohydrate-based trioxadecalines with a cyano group in mixed systems. The mixture of a trioxadecaline having a Ch phase and a trioxadecaline having a Ch, SA and a S*Cphase sequence induces a re-entrant TGBA and Ch phase. Below the stabilized S*C phase, a re-entrant Ch phase is observed. In the mixture of the cholesteric trioxadecaline with CCH7, itself only showing a nematic phase, a TGBA phase and a broad range SA phase are induced from two non-smectic compounds. Both mixtures show a blue phase with a pitch ranging from the UV to red depending on the molar fraction.  相似文献   
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