全文获取类型
收费全文 | 215篇 |
免费 | 5篇 |
国内免费 | 2篇 |
专业分类
化学 | 128篇 |
晶体学 | 1篇 |
力学 | 10篇 |
数学 | 51篇 |
物理学 | 32篇 |
出版年
2024年 | 2篇 |
2023年 | 3篇 |
2022年 | 9篇 |
2021年 | 15篇 |
2020年 | 7篇 |
2019年 | 9篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 11篇 |
2015年 | 4篇 |
2014年 | 4篇 |
2013年 | 16篇 |
2012年 | 8篇 |
2011年 | 16篇 |
2010年 | 13篇 |
2009年 | 11篇 |
2008年 | 8篇 |
2007年 | 8篇 |
2006年 | 10篇 |
2005年 | 9篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有222条查询结果,搜索用时 78 毫秒
1.
We consider the rate of convergence for a class of perturbed hemivariational inequalities in reflexive Banach Spaces. Our results can be viewed as an extension and refinement of some previous known results in this area. 相似文献
2.
3.
M. A. Misdaq S. Berrazzouk A. Elharti F. Ait Nouh W. Bourzik 《Journal of Radioanalytical and Nuclear Chemistry》2000,246(2):395-401
Uranium and thorium contents were evaluated in water samples collected from different sources of the piedmont of the Middle Atlas mountains by using two types of solid state nuclear track detectors (SSNTD). In addition, the radon (222Rn) and thoron (220Rn) -activities per unit volume of the water samples were also determined. The influence of the water flow rate and altitude on the radon concentration of the water samples belonging to the piedmont of the Middle Atlas mountains was investigated. The hydraulic exchanges between the Middle Atlas water reservoirs and the Turonian aquifer of the neighbouring Tadla plain have been quantified. The results were compared with data given in literature. 相似文献
4.
5.
Azioune A Slimane AB Hamou LA Pleuvy A Chehimi MM Perruchot C Armes SP 《Langmuir : the ACS journal of surfaces and colloids》2004,20(8):3350-3356
Novel ester-functionalized polypyrrole-silica nanocomposite particles were prepared by oxidative copolymerization of pyrrole and N-succinimidyl ester pyrrole (50/50% initial concentrations), using FeCl3 in the presence of ultrafine silica nanoparticles (20 nm diameter). The N-succinimidyl ester pyrrole monomer was prepared in aqueous solution using 1-(2-carboxyethylpyrrole) and N-hydroxysuccinimide in the presence of 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide. The resulting nanocomposites (N-succinimidyl ester polypyrrole-silica) are raspberry-shaped agglomerates of silica sol particles "glued" together by the insoluble poly(pyrrole-co-N-succinimidyl pyrrole). The N-succinimidyl ester polypyrrole-silica particles were characterized in terms of their size, density, copolymer content, and polydispersity. Scanning electron microscopy and disk centrifuge sedimentometry confirmed that the nanocomposite particles had narrow size distributions. X-ray photoelectron spectroscopy analysis indicated a silica-rich surface and a high surface concentration of N-succinimidyl ester groups. These nanoparticles exhibited good long-term dispersion stability. The chemical stability of the ester functions in aqueous media after several weeks of storage was monitored by FTIR spectroscopy. The functionalized nanocomposites were tested as bioadsorbents of human serum albumin (HSA). The very high amount of immobilized HSA determined by UV-visible spectroscopy is believed to be due to covalent binding. Incubation of the HSA-grafted nanocomposite with anti-HSA resulted in immediate flocculation, an indication that they are alternative candidates for visual diagnostic assays. 相似文献
6.
The inhibition performance of five azomethine derivatives such as: 1-(4-Methyloxy phenylimino)-1-(phenylhydrazono)-propan-2-one (SB1), 1-(4-Methylphenylimino)-1-(phenylhydrazono) propan-2-one (SB2), 1-(phenylimino)-1(phenylhydrazono)-propan-2-one (SB3), 1-(4-Bromo phenylimino)-1(phenylhydrazono)-propan-2-one (SB4) and 1-(4-Chlorophenylimino)-1(phenylhydrazono) -propan-2-on (SB5) as corrosion inhibitors for mild steel in sulfuric acid 0.5 ?M were investigated using different methods. All experimental results demonstrate that these compounds are eficients inhibitors. The inhibition efficiencies () increase with inhibitors concentration. At 7.5 10?5 ?M, the was 97.27%, 96.31%, 94.23%, 93.19 and 91.64% for SB1, SB2, SB3, SB4 and SB5, respectively. The potentiodynamic polarization results indicated that all the studied inhibitors act as mixed type. The adsorption process on mild steel surface obeyed Langmuir isotherm. The associated activation parameters and thermodynamic have been calculated and discussed. The adsorbed film formed on the metal surface was characterized by SEM and EDX. 相似文献
7.
A. Ait Haddou M. Berrada G. Paić 《Journal of Radioanalytical and Nuclear Chemistry》1986,102(1):159-175
The yield and average cross section for the reactions11B(p, n)11C,12C(p, )13N,13C(p, n)13N,
12
12
C(d, n)13N,14N(p, )11C,16O(p, )13N,16O(d, n)17F,16O(t, n)18F, and18O(p, n)18F have been measured in different compounds. The charged particles were created in the samples themselves either through recoil by scattering of 14 MeV neutrons off hydrogen and deuterium, or by the (n, t) reaction on6Li using thermal neutrons. The yields of reactions12C(d, n);16O(p, );16O(t, n) and18O(p, n) have been measured using proton, deuteron and triton spectra generated by 14 MeV neutrons in the reactions D(n, p)2n;6Li(n, d);7Li(n, d) and10B(n, d);7Li(n, t) and10B(n, t), respectively. 相似文献
8.
Tabbi Hanane Amel Bendjeddou Didier Villemin 《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):697-704
AbstractThe synthesis of the title compounds has been carried out by condensation via a Wittig-type reaction of a pyridinium hexafluorophosphate with a phosphonate ester to give the desired (4-nitrophenyl)tetrathiafulvalene the nitro group of which was reduced to an amino group. Reaction of the amine with chlorosulfonyl isocyanate and subsequently with tert-butyl alcohol gave the corresponding open-chain sulfamide. Cyclization under basic conditions and de-protection led to 2-[4-(4′,5′-dipropyltetrathiafulvalen-4-yl)]phenyl-1,2,6-thiadiazinane 1,1-dioxide. Finally, N-alkylated and N-acylated cyclic sulfamides linked to tetrathiafulvalene were obtained. Their electron donor ability was measured by cyclic voltammetry. A detailed DFT study based on B3LYP/6–31G (d,p) of electronic properties is also presented. The calculated molecular electrostatic potential shows that, the negative charge covers the nitro and sulfamide function, while positive charge is located at the hydrogen atoms of the amine and sulfamide rings. The calculated HOMO and LUMO energy reveals that charge transfer occurs within the molecule. The chemical reactivity parameters reveal that tetrathiafulvalene 1 is highly reactive, which facilitates the desired formation of the cyclic sulfamide. The first hyperpolarizability βtot shows that compounds 1 and 5 are good candidates as a NLO material. 相似文献
9.
Zakir O. Ait Karra A. Idouhli R. Elyaagoubi M. Khadiri M. Dikici Burak Aityoub A. Abouelfida A. Outzourhit A. 《Journal of Solid State Electrochemistry》2022,26(10):2247-2260
Journal of Solid State Electrochemistry - In this study, copper (Cu) and silver (Ag)–doped TiO2 nanotubes were fabricated by in situ anodization method to improve their photocatalytic... 相似文献
10.
Gorelik A. M. Venidiktova O. V. Ait A. O. Barachevsky V. A. 《Russian Journal of General Chemistry》2021,91(12):2656-2659
Russian Journal of General Chemistry - The reaction between phenalenon derivatives containing hydroxy group in peri-position to carbonyl and propynol was studied. A new hybrid compound was... 相似文献