Non-covalently lactose imprinted polymers and recognition of saccharides in aqueous solutions

The aim of this work was to prepare lactose imprinted polymer and study of its selectivity for the recognition of different mono- and disaccharides. A series of molecularly imprinted polymers (MIPs) against lactose were synthesized and their binding properties were compared with a Blank non-imprinted polymer. Methacrylamide (MAAM) and ethylene glycol dimethacrylate were used as functional monomer and cross-linker, respectively. Dimethylsulfoxide was also applied as polymerization solvent. Different lactose:MAAM ratios were applied and optimized MIP was selected in a conventional batch adsorption study. The dissociation constant and maximum binding sites of polymer were determined using the Scatchard analysis. The selectivity of MIP for different mono- and disaccharides was also evaluated. The results indicated that the shape of cavity and orientation of functional monomers in binding sites and the spatial arrangement of hydroxyl groups in saccharide structure were responsible for the selectivity of lactose imprinted polymer.     

Calculation of relativistic nucleon-nucleon potentials in three dimensions

The European Physical Journal A - In this paper, we have applied a three-dimensional approach for the calculation of the relativistic nucleon-nucleon potential. The quadratic operator relation...     

New enclosure algorithms for the verified solutions of nonlinear Volterra integral equations

This paper is concerned with new algorithms which provide the sharp bounds that are guaranteed to contain the exact solutions of nonlinear Volterra integral equations. We develop new enclosure algorithms based on the interval methods which was first introduced by Moore in [24] together with the Taylor polynomials to improve the accuracy of the scheme by reducing the width of interval solutions. The modified methods calculate a priori bound automatically in parallel with the computation of solutions of integral equations. We will show that the accuracy of the proposed algorithms is dependent on the number of interval subdivisions. Some numerical experiments are also included to demonstrate the validity and applicability of the scheme and showing a marked improvement in comparison with the recent existing numerical results.     

Neutron elastic scattering from 116,118,120,122,124Sn

Accurate measurements of neutron differential elastic cross sections have been obtained from even isotopes of Sn. Data are presented for the elastic scattering of 11 MeV neutrons from ^{116, 118, 120, 122, 124}Sn, the elastic scattering for 24 MeV neutrons from ^{116, 118, 124}Sn and the neutron total cross section from ^{118, 120, 122, 124}Sn in the energy ranges 5.0–10.6 MeV and 20.0–26.0 MeV. The elastic scattering data are analyzed in terms of an empirical optical-model potential. The obtained optical-potential parameters are analyzed in terms of energy and isospin dependence and compared with those obtained from proton elastic scattering on even Sn isotopes.     

Three-Dimensional Low-Momentum Interaction in Two-Body Bound State Calculations

The deuteron binding energy and wave function are calculated by using the recently developed three-dimensional form of low-momentum nucleon–nucleon (NN) interaction. The homogeneous Lippmann–Schwinger equation is solved in momentum space by using the low-momentum two-body interaction, which is constructed from Malfliet–Tjon potential. The results for both, deuteron binding energy and wave function, obtained with low-momentum interaction, are compared with the corresponding results obtained with bare potential.     

Four-Boson Systems Close to a Universal Regime

Universal properties of weakly-bound four-boson systems near the scaling limit are discussed by considering recent results obtained from the solution of Faddeev-Yakubovsky (FY) equations, which confirm a previous conjecture on a four-body scale dependence. In the present contribution, within a discussion on our numerical results obtained for the binding energies of two consecutive tetramer states, we are analyzing the relative relevance of the two possible configurations of the four-body system.     

Syntheses of substituted pyrrolo[2,3-d]imidazoles

Starting from the readily available 5-hydroxymethyl-2-mercapto-1-methylimidazole (1) substituted pyrrolo[2,3-d]imidazoles were prepared.     

Syntheses of substituted pyrrolo[2,3‐d]imidazole‐5‐carboxylates and substitued pyrrolo[3,2‐d]imidazole‐5‐carboxylates

Starting from readily available p‐substituted‐benzylamines a series of ethyl 2‐alkylthio‐1‐substituted‐ben‐zylpyrrolo[2,3‐d]imidazole‐5‐carboxylates was prepared. In addition, starting from 2‐alkyl‐4(or 5)‐formylimidazoles and methyl 4′‐bromomethylbiphenyl‐2‐carboxylate a series of methyl substituted‐pyrrolo[2,3‐d]imidazole‐5‐carboxylates and methyl substituted‐pyrrolo[3,2‐d]imidazole‐5‐carboxylates was prepared.     

Four-Body Bound-State Calculations in Three-Dimensional Approach

The four-body bound state with two-body interactions is formulated in three-dimensional approach, a recently developed momentum-space representation which greatly simplifies the numerical calculations of few-body systems without performing the partial wave decomposition. The obtained three-dimensional Faddeev-Yakubovsky integral equations are solved with two-body spin-independent and spin-averaged potentials. This is the first step toward the calculations of the four-nucleon bound-state problem in three-dimensional approach. Results for four-body binding energies are in good agreement with achievements of the other methods.     

Neutron inelastic scattering to octupole states in single-closed-shell nuclei

Differential cross sections for the excitation of the first octupole-vibrational state in the closed- neutron-shell nuclides ⁸⁸Sr and ⁹⁰Zr and in the closed-proton shell-nuclei ^{116, 118, 120, 124}Sn by 11 MeV neutrons are presented. The distorted-wave Born approximation is used to obtain deformation lengths, σ(3^?), for each state. Results are compared with earlier measurements of inelastic proton scattering to the same states. Although limited resolution in the neutron time- of-flight spectrometer complicates the interpretation of the Sn data, the overall conclusion that σ_nn′(3^?) ≈ σ_pp′(3^?) is supported by all of the measurements.