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1.
Abstract— The Stern-Volmer constants for fluorescence quenching by tetramethylethylene decrease in the order DMC ≫ DHP > F-2 > 8-MOP. The same order was observed for the quantum yields of [2+2] cycloaddition reaction with tetramethylethylene on direct irradiation. In [2+2] photocycloaddition of F-2 with tetramethylethylene in ethanol, the ratio of quantum yields deduced from singlet and triplet states of F-2; φ3 0 /φ1 0 , is about 5. The excited triplet state is the reactive state for the [2+2] photocycloaddition of F-2 with tetramethylethylene in solution but the excited singlet state of F-2 becomes very important in biological conditions. 相似文献
2.
Kwok-Pun HO 《数学物理学报(B辑英文版)》2021,(4):1263-1274
Boyd's interpolation theorem for quasilinear operators is generalized in this pa-per,which gives a generalization for both the Marcinkiewicz interpolation theor... 相似文献
3.
It is shown that in the pion induced double charge exchange reaction on Jp=O+→O+ nuclei,there exists a possible new reaction mechanism π+(Δ0,Δ++)π- or π+(Δ-,Δ+)π- in so-called single step process,while that old speculative mechanism π+(N,Δ)π- or π+(N,Δ)π- is firbidden by a well-known selection rule which has been indicated in the theory of the nuclear 2β-decay. 相似文献
4.
我们用爱氏光源(低电流交流电弧)作高速钢的光谱分析时,发现样品的组织结构对于分析结果有影响。为了对这个现象得到进一步的了解,我们选择了10种含碳量不同的铬钢进行热处理试验和光谱分析。一系列实验的结果指出,用小电流(5安)电弧光源时,铬的光谱分析结果由于试样是退火组织或淬火组织而有差别,这个差别又随着钢中含碳量的增加而增加。我们认为,这种影响是由于碳在试样中存在状态的不同所引起的。在低功率光源中,这种不同使合金元素被蒸发和被激发的情况有所差别,因而就影响了光谱分析的结果。这种影响由于合金元素之不同而有程度上的不同,对铬的影响很显著,对锰和矽的影响则很小。此外,所选择的分析线对是弧线还是火花线,对于这种组织结构的效应也有显著的影响。曾经进行了一些消除组织结构影响的实验。发现在应用低功率光源时,增加预燃时间并不能消除这个效应。用火花光源或大电流(8安)电弧光源时,这种影响大为减小。 相似文献
5.
In this paper, three hotly discussed problems, namely the neutrino bursts, the blue progenitor, and the mixing phenomenon, observed in SN1987A are summarized. But it is pointed that while all the observations on SN1987A do not favour a twice-banged scenario, we have found three historical cases from ancient Chinese documents that might be interpreted as twice- or even multi-explosions of a supernova. Finally in a one-dimensional simulation we demonstrate that an induced gravitational collapse b possible. 相似文献
6.
The cross sections of
Ω+Ω→(ΩΩ)Jπ=0++X
are studied by using an effective Hamiltonian method. The results
are σΩ+Ω→(ΩΩ)0++γ=0.03~0.16×10-29 cm2 for
pΩ=100~400 MeV, and
the cross sections of η production are about 10-28 cm2 for
pΩ > 880 MeV. 相似文献
7.
We present an ultra compact and high resolution free space optical spectrometer and demonstrate it by using FDTD simulations. The miniature interferometer-based speetrometer is a series of submicron phase objects on a polymethyl methacrylate(PMMA) film with a CCD as the detector. The speetrum is obtained by solving a system of simultaneous linear equations. The Tikhonov regularization method is used to achieve a resolution at the picometer level. Compared with conventional speetrometers, the proposed device is low-cost and easy to fabricate due to its simple structure. Furthermore, its compact feature renders the device ideal for miniaturization and integration as the systems in microfluidics architectures and lab-on-chip designs. 相似文献
8.
A new mathematical formulation, called the pseudovorticity–velocity formulation, of the three-dimensional incompressible Navier–Stokes equations is presented as an alternative to the vorticity–velocity approach. For the model lid-driven cavity flow problem in two and three dimensions, combined with an explicit mixed spectral /finite different numerical scheme the proposed formulation is found to be efficient and very accurate as compared with the results available in the literature. In particular, the simulation results demonstrate an attractive feature of the present formulation compared with the vorticity–velocity approach, namely that the divergence-free condition of the velocity field can always be achieved on a non-staggered mesh. 相似文献
9.
以三苯胺、咔唑、4,4′-二羧基联吡啶为原料,设计并合成了两个联吡啶铱(III)配合物Ir1和Ir2,其结构经1H NMR, 13C NMR和HR-MS(MALDI-TOF)表征。并利用紫外可见光谱(UV-Vis)、荧光发射光谱(Photoluminescence)和循环伏安法研究了化合物的光学和电学性质。结果表明:Ir1和Ir2的紫外可见光吸收波长分别位于456 nm 和448 nm,相应的发射波长分别为645 nm和678 nm,说明其均能利用可见光; Ir1和Ir2的HOMO电位为-5.125~-5.510 eV, LOMO电位为-2.880~-0.310 eV,满足作为光敏剂的基本条件。研究了化合物在可见光照射下光催化水分解产生氢气的效果。结果表明:Ir1和Ir2的氢气值TONs(turnover numbers)达到2 827和1 908。 相似文献
10.
SHA Chin-Kang CHIU Rei-Torng LIH Shinn-Horng SANTHOSH K.C CHANG Ching-Jung TSENG Wei-Hong HO Wen-Yueh 《高等学校化学研究》2001,17(3)
Intramolecular radical cyclization reactions are now used routinely to synthesize carbocyclic and heterocyclic structures. We have reported that α-carbonyl radicals 1, generated from the corresponding iodo ketones or enones, underwent intramolecular radical cyclization smoothly to afford products 2.1, 2,3 相似文献