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排序方式: 共有119条查询结果,搜索用时 15 毫秒
1.
R.A. Gunasekaran M. Agarwal A. Singh P. Dubasi P. Coane K. Varahramyan 《Optics and Lasers in Engineering》2005,43(6):1086
A novel small fluid controlled optical lens system that is capable of displaying dynamic variation of its focal length and field-of-view (FOV) is designed and fabricated. In this active lens system, appropriate volume of the optical fluid can be pumped into or out of the lens chamber to provide double-convex (DCX) or double-concave (DCV) lens effect. Simple optical imaging experiments were performed using different sets of glass lenses with fixed focal lengths to determine the optimum lens configuration required for designing a dynamic optical lens system. The experimental results obtained from the glass lenses demonstrate that a combination of a single DCX lens with three DCV lenses provides a wider FOV. The flexible membranes for fluid controlled lenses were fabricated using polydimethylsiloxane polymer material, which has good optical transparency and elasticity. A simple fluid injection system is used to vary the radius of curvature of the lenses, and thereby to change the focal length. A dynamic optical lens system with a combination of one DCX and multiple variable focal length DCV lenses as designed here can image an object with a wide range of focal length and FOV. With this fluid controlled optical system, the FOV and focal length could be continuously varied and a maximum FOV of 118.3° could be achieved. The smallest f-number (f/#) for this fluid controlled single lens system was found to be 1.3, which corresponds to the numerical aperture value of 0.35. 相似文献
2.
Ananthakrishnan Gunasekaran Thiruvalam Jayachandran Joseph H. Boyer Mark L. Trudell 《Journal of heterocyclic chemistry》1995,32(4):1405-1407
The reaction of glyoxime ( 4 ) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime ( 5 ). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan ( 1 ) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative 8 . 相似文献
3.
The complete force field for carbon suboxide has been evaluated. The optimum geometry, stretching and interaction force constants are obtained from a combination of the CNDO/force molecular orbital method and the compliance constant formalism. 相似文献
4.
Titanium oxide on silica-alumina support is described to be an efficient regenerable catalyst for alkylation of aromatic compounds with alkyl halides, alcohols and olefins, and the reaction is proposed to be initiated by the protonated metal active species present in the catalyst. 相似文献
5.
A new nonlinear optical organic crystal l-tryptophan p-nitrophenol (LTPNP) of dimension 19 mm × 2 mm × 1.5 mm has been grown from an aqueous solution for the first time by slow evaporation technique at ambient temperature. The crystal structure of LTPNP was confirmed by single crystal X-ray diffraction. LTPNP crystallizes in non-centrosymmetric monoclinic system with space group P21. The recorded FTIR spectrum confirms the presence of various functional groups in the grown crystal and confirms the formation of LTPNP. Thermal stability and melting temperature of the LTPNP crystal were identified from TG/DTA analysis. The optical absorption study confirms the suitability of the crystal for device applications. LTPNP exhibits SHG efficiency over 1.7 orders of magnitude higher than that of urea and 4 orders of magnitude higher than that of KDP. 相似文献
6.
Angappa Gunasekaran Zahir Irani Thanos Papadopoulos 《The Journal of the Operational Research Society》2014,65(6):806-823
Sustainable operations management (SOM) can be defined as the operations strategies, tactics and techniques, and operational policies to support both economic and environmental objectives and goals. The subject of sustainability has gained much attention from both researchers and practitioners in the past 6–8 years. Most of the articles deal with sustainability from environmental perspectives, but a limited number of them integrate both economic and environmental implications or focus on trading-off between profitability, competitiveness and environmental dimensions. Moreover, there is a limited focus on modelling and analysis (MA) of SOM integrating and balancing the interests of both economic and environmental interests. Therefore, an attempt has been made in this paper to review the extant literature on SOM. The objective is to understand the definition of SOM and present the current status of research in MA, as well as future research directions in the field. Considering the recent focus of the subject, we review the literature on MA of SOM beginning in 2000 in order to make our study current and more relevant for both researchers and practitioners. Finally, a summary of findings and conclusions is reported. 相似文献
7.
Gunasekaran Balamurugan Sundarraman Balaji Rengan Ramesh Nattamai S.P. Bhuvanesh 《应用有机金属化学》2019,33(1)
A panel of six new arene Ru (II)‐NHC complexes 2a‐f , (NHC = 1,3‐diethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1a , 1,3‐dicyclohexylmethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1b and 1,3‐dibenzyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1c ) were synthesized from the transmetallation reaction of Ag‐NHC with [(η6‐arene)RuCl2]2 and characterized. The ruthenium (II)‐NHC complexes 2a‐f were developed as effective catalysts for α‐alkylation of ketones and synthesis of bioactive quinoline using primary/amino alcohols as coupling partners respectively. The reactions were performed with 0.5 mol% catalyst load in 8 h under aerobic condition and the maximum yield was up to 96%. Besides, the different alkyl wingtips on NHC and arene moieties were studied to differentiate the catalytic robustness of the complexes in the transformations. 相似文献
8.
Gunasekaran Raja Chinnasamy Jayabalakrishnan 《Central European Journal of Chemistry》2013,11(6):1010-1018
A series of new ruthenium(II) complexes were synthesized with Schiff bases derived from salicylaldehyde / o-hydroxyacetophenone/ o-vanillin / 2-hydroxy-1-naphthaldehyde with thiosemicarbazide and acetyl furan. They are characterized by elemental analysis, IR, electronic, 1H NMR, 13C NMR and mass spectral studies. The elemental analysis suggests the stoichiometry to be 1:1 (metal:ligand). Four of these complexes were tested for its binding with CT-DNA using absorption spectroscopic studies and two of these complexes exhibit efficient DNA cleavage activity. 相似文献
9.
Karthikeyan Rajendran Surianarayanan Mahadevan Rajendhran Jeyaprakash Gunasekaran Paramasamy Asit Baran Mandal 《Applied biochemistry and biotechnology》2013,171(6):1328-1338
Bacillus badius isolated from soil has been identified as potential producer of penicillin G acylase (PGA). In the present study, batch experiments performed at optimized inoculum size, temperature, pH, and agitation yielded a maximum PGA of 9.5 U/ml in shake flask. The experiments conducted in bioreactor with different oxygen flow rates revealed that 0.66 vvm oxygen flow rate could be sufficient for the maximum PGA activity of 12.7 U/ml. From a detailed investigation on the strategies of the addition of phenyl acetic acid (PAA) for increasing the production of PGA, it was found that the controlled addition of 10 ml of 0.1 % (w/v) PAA once in every 2 h from 6th hour of growth showed the maximum PGA activity of 32 U/ml. Thus, our studies for the first time showed that at concentration above 0.1 % (w/v) PAA, the PGA production decreased. This selective condition paves the way for less costly bioprocess for the production of PGA. 相似文献
10.
Gunasekaran Manonmani Lakshmanan Sandhiya Kittusamy Senthilkumar 《International journal of quantum chemistry》2020,120(11):e26182
The hydrolysis of sulfonylamine (HNSO2) results in the formation of sulfuric acid along with ammonia, and is of significant interest due to their negative impact on environment and life on Earth. The formation of H2SO4 through the reaction of HNSO2 with (H2O)2-4 has been studied using high level electronic structure calculations. This hydrolysis reaction is a step-wise process, in the first step a H-atom from H2O is transferred to the N-atom of HNSO2 which results in the formation of NH2, and in the next step, H2SO4, NH3 and water molecule(s) are formed. The results show that the energy barrier associated with the formation of intermediates and product complexes is reduced by 7 to 10 kcal/mol when the number of water molecules is increased from 2 to 4. The rate constant was calculated using canonical variational transition state theory with small curvature tunneling correction over the temperature range of 200 to 1000 K. At 298 K, the calculated rate constant for the formation of intermediate in the first step is 2.24 × 10−16, 1.03 × 10−12, and 2.10 × 10−11 cm3 mol−1 s−1, respectively, for the reaction with water dimer, trimer and tetramer. The calculated enthalpy and free energy show that the reaction corresponding to the formation of H2SO4 is highly exothermic and exoergic in nature. 相似文献