A Comment on Change of Nusselt Number Sign in a Channel Flow Filled by a Fluid-Saturated Porous Medium with Constant Heat Flux Boundary Conditions

The aim of this Letter is to show that, the Nusselt number sign might be changed without changing of heat transfer direction at the wall of channels, even for flows without viscous dissipation.     

Interaction between green tea extract and 99mTc-pertechnetate on in vivo distribution

People drink various types of tea without knowing the side effects of biological and chemical contents and radiopharmaceutical interactions. In current study, it is aimed to evaluate the effects of green tea extract in different extraction solvents on the radiolabeling of the blood constituents with ^99mTc and on the biodistribution of radiopharmaceutical sodium pertechnetate (Na^99mTcO₄) in male Wistar Albino rats. The extraction of green tea was performed in different solvents. Biodistribution studies were performed on male rats which were treated via gavage with green tea extract in different extraction solvents or saline (0.9 % NaCl) as a control group for 7 days. The radiolabeling of blood constituents performed incubating with SnCl₂ and ^99mTc. According to experimental results, radiolabeling blood components with ^99mTc were not modified in the usage of the different extraction solvents for green tea extraction, but a significant alteration (P < 0.05) of biodistribution of Na^99mTcO₄ was observed after treatment with green tea extract in distilled water. Although there is no considerable effect on radiolabeling of blood components, there is an outstanding change on the biodistribution studies especially with green tea extract in distilled water. The identified change monitored in this study may cause to reduce the risk of misdiagnosis and/or avoid the repetition of the examinations in nuclear medicine.     

Characterization of methanol extracts from <Emphasis Type="Italic">Quercus hartwissiana</Emphasis> wood and bark

The MeOH extracts of wood and bark from Quercus hartwissiana have been investigated by GC-MS after derivatization, as well as by classical spectroscopic methods. The results for the free compounds revealed that ellagic acid, catechin, gallic acid, quercitol, and also long chain fatty acids, sugars, and sitosterol were the essential compounds in wood and bark, most of them being present in differing amounts. Quercitol, a characteristic compound for the oak wood tannin, was also recognized and determined in oak bark extracts in this study. Amounting to 1/4^th to 1/3^rd of the free compounds, the bark had the highest catechin content. While the content of sugars, such as fructose and glucose, increased in sapwood and bark extracts remarkably, the amounts of these compounds decreased in extracts of heartwood. The profile of the bound compounds contained sugars (i.e., arabinose, xylose, and, above all, glucose), ellagic and gallic acids, quercitols, and inositols. Compared with the composition of free compounds, the hydrolyzed extracts showed relatively higher amounts of sugars, especially glucose, gallic acid and quercitol.     

Study of spectator tagging in the reaction np → ppπwith a deuteron beam

The reaction has been studied in a kinematically complete experiment at a single beam momentum GeV/c (T = 759MeV). All four ejectiles have been detected in the large-acceptance time-of-flight spectrometer COSY-TOF. We analyzed the data along the lines of the spectator model as a means to isolate the quasi-free reaction. The spectator proton was identified by its momentum and flight direction thus yielding access to the associated Fermi motion of the bound neutron. A comparison is carried out with Monte Carlo simulations based on two different parameterizations of the deuteron wave function. Up to a Fermi momentum of roughly 150MeV/c no significant deviations between experimental and simulated data of various observables were found from which we conclude that the deuteron can indeed be taken as a valid substitute for the neutron.     

An Electrochemical Sensor Fabricated by Sonochemical Approach for Determination of the Antipsychotic Drug Haloperidol

A nanocomposite (Ho₂O₃NPs/BNT) was synthesized by decorating holmium(III)oxide nanoparticles (H₂O₃NPs) on bentonite (BNT) through a realizable sonochemical approach for the electrochemical detection of haloperidol (Hlp). A glassy carbon electrode was modified with this nanocomposite. The Ho₂O₃NPs/BNT modified electrode outperformed bare and other modified electrodes in terms of electrochemical performance for Hlp detection in a pH 8.0 phosphate buffer. The proposed electrochemical platform showed a wide linear range (0.01 μM–24 μM), low detection limit (2.4 nM), and high sensitivity by square wave voltammetry. In addition, the proposed electrochemical sensor met the clinical criteria in terms of stability, selectivity, and repeatability.     

Experimental investigation of inclined liquid water jet flow onto vertically located superhydrophobic surfaces

In this study, the behaviour of an inclined water jet, which is impinged onto hydrophobic and superhydrophobic surfaces, has been investigated experimentally. Water jet was impinged with different inclination angles (15°–45°) onto five different hydrophobic surfaces made of rough polymer, which were held vertically. The water contact angles on these surfaces were measured as 102°, 112°, 123°, 145° and 167° showing that the last surface was superhydrophobic. Two different nozzles with 1.75 and 4 mm in diameters were used to create the water jet. Water jet velocity was within the range of 0.5–5 m/s, thus the Weber number varied from 5 to 650 and Reynolds number from 500 to 8,000 during the experiments. Hydrophobic surfaces reflected the liquid jet depending on the surface contact angle, jet inclination angle and the Weber number. The variation of the reflection angle with the Weber number showed a maximum value for a constant jet angle. The maximum value of the reflection angle was nearly equal to half of the jet angle. It was determined that the viscous drag decreases as the contact angle of the hydrophobic surface increases. The drag force on the wall is reduced dramatically with superhydrophobic surfaces. The amount of reduction of the average shear stress on the wall was about 40%, when the contact angle of the surface was increased from 145° to 167°. The area of the spreading water layer decreased as the contact angle of the surface increased and as the jet inclination angle, Weber number and Reynolds number decreased.     

DNA-templated control of chirality and efficient energy transport in supramolecular DNA architectures with aggregation-induced emission

Two conjugates of tetraphenylethylene with d-2′-deoxyuridine (1d) and l-2′-deoxyuridine (1l) were synthesized to construct new supramolecular DNA-architectures by self-assembly. The non-templated assemblies of 1d and 1l show strong aggregation-induced emission and their chirality is exclusively controlled by the configuration of their sugar part. In contrast, the chirality of the DNA-templated assemblies is governed by the configuration of the DNA, and there is no configuration-selective binding of 1d to d-A₂₀ and 1l to l-A₂₀. The quantum yield of the assembly of 1d along the single-stranded DNA A₂₀ is 0.40; approximately every second available binding site on the DNA template is occupied by 1d. The strong aggregation-induced emission of these DNA architectures can be efficiently quenched and the excitation energy can be transported to Atto dyes at the 5′-terminus. A multistep energy transport “hopping” precedes the final energy transfer to the terminal acceptor. The building block 1d promotes this energy transport as stepping stones. This was elucidated by reference DNA double strands in which 1d was covalently incorporated at two distinct sites in the sequences, one near the Atto dye, and one farther away. This new type of completely self-assembled supramolecular DNA architecture is hierarchically ordered and the DNA template controls not only the binding but also the energy transport properties. The high intensity of the aggregation-induced emission and the excellent energy transport properties make these DNA-based materials promising candidates for optoelectronic applications.

DNA architectures with tetraphenylethylene are assembled in a non-covalent way. The strong aggregation-induced emission of the chromophores is quenched and the energy is transported to Atto dyes by a multistep energy “hopping”.     

Single \mathrm{\ensuremath{\pi^{-}}} production in np collisions for excess energies up to 90 MeV

The quasifree reaction was studied in a kinematically complete experiment by bombarding a liquid-hydrogen target with a deuteron beam of momentum 1.85GeV/c and analyzing the data along the lines of the spectator model. In addition to the three charged ejectiles the spectator proton was also detected in the large-acceptance time-of-flight spectrometer COSY-TOF. It was identified by its momentum and flight direction thus yielding access to the Fermi motion of the bound neutron and to the effective neutron 4-momentum vector _n which differed from event to event. A range of almost 90MeV excess energy above threshold was covered. Energy-dependent angular distributions, invariant-mass spectra as well as fully covered Dalitz plots were deduced. Sizeable pp FSI effects were found as were contributions of p and d partial waves. In comparison with existing literature data the results provide a sensitive test of the spectator model. The behavior of the elementary cross-section σ₀₁ close to threshold is discussed in view of new cross-section data.