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1.
Lui Lam Flonnie Dowell Helmut Brand Guenter Ahlers 《Journal of statistical physics》1991,64(5-6):899-901
2.
Franz Heresch Guenter Allmaier Gottfried Heinisch 《Journal of heterocyclic chemistry》1981,18(2):255-258
The electron impact mass spectrometric fragmentation of trans-3- and trans-4-styrylpyridazine is reported in detail, including a comparison with other aza-stilbenes. With regard to a distinction between the two isomeric styrylpyridazines, the intensity ratio of the M+ and [M-1]+ ions, the general degree of fragmentation and the elimination pathways of nitrogen proved to be most characteristic. 相似文献
3.
William R. Cullen Hao Li Spiros A. Pergantis Guenter K. Eigendorf Andrew A. Mosi 《应用有机金属化学》1995,9(7):507-515
The microorganism Apiotrichum humicola (previously known as Candida humicola) grown in the presence of either arsenate, arsenite, methylarsonic acid or dimethylarsinic acid, produces arsenic-containing metabolites in the growth medium. When L-methionine-methyl-d3 is added to the cultures, the CD3 label is incorporated intact into the metabolites to a considerable extent to form deuterated dimethylarsenic and trimethyl-arsenic species, indicating that S-adenosylmethionine, or some related sulphonium compound, is involved in the biological methylation. Conclusive evidence of CD3 incorporation in the arsenicals found in the growth medium was provided by using a specially developed hydride generation-gas chromatography-mass spectrometry system (HG–GC–MS). 相似文献
4.
热耦合型二级高频脉冲管制冷机实验研究 总被引:2,自引:2,他引:0
降低制冷温度至4 K温区是高频脉冲管制冷机的最新发展要求。本文介绍了一套热耦合型二级高频脉冲管制冷机的性能特性,它可以达到低于15 K以下的最低温度,是目前报道的高频二级脉冲管制冷机能获得的最低温度.通过对制冷机一级预冷、二级输入功率、二级冷量、室温条件等影响的分析,从实验角度揭示了该二级制冷系统的复杂影响,为进一步的深入分析和改进提供了基础。 相似文献
5.
Herbert Muffler Guenter Siegemund Werner Schwertfeger 《Journal of fluorine chemistry》1982,21(2):107-132
4.5-Perfluoro-1.3-dioxolanes are available by reaction of 2(α-chloroalkoxy)perfluoro-carbonyl halides or -ketone with fluoride ions. A mechanism for the intramolecular ring- closure-reaction is proposed. Hydrogen atoms at C-2 in can be exchanged photochemically by chlorine. Starting from the 2-monochloro-derivatives the 2-monofluoro-4.5-perfluoro- 1.3-dioxolanes are formed by reaction with triethylamine- hydrofluoride. 相似文献
6.
Immunoanalytical methods at a very low limit of detection (LOD) and a low limit of quantification (LOQ) are becoming more and more important for environmental analysis and especially for monitoring drinking water quality. Biosensors have suitable characteristics such as efficiency in allowing very fast, sensitive, and cost-effective detection. Here we describe a fully automated immunoassay for estrone with a LOD below 0.20 ng L–1 and a LOQ below 1.40 ng L–1. In contrast to common analytical methods such as GC-MS or HPLC-MS, the biosensor used requires no sample pre-treatment and pre-concentration. The basis of our sensitive assay is the antibody with a high affinity constant towards estrone. The very low amount of antibody per sample results in low validation parameters (LOD, LOQ, and IC50), but this assay for estrone represents the current device-related limitation of the River Analyser (RIANA). 相似文献
7.
Kuehn K Mehta S Fu H Genio E Murphy D Liu F Liu Y Ahlers G 《Physical review letters》2002,88(9):095702
We report new measurements in four cells of the thermal boundary resistance R between copper and (4)He below but near the superfluid-transition temperature T(lambda). For 10(-7)< or =t identical to 1-T/T(lambda))< or =10(-4) fits of R = R(0)t(-x(b))+R(B) to the data yielded x(b) approximately equal to 0.18, whereas a fit to theoretical values based on the renormalization-group theory yielded x(b) = 0.23. Alternatively, a good fit of the theory to the data could be obtained if the amplitude of the prediction was reduced by a factor close to 2. The results raise the question whether the boundary conditions used in the theory should be modified. 相似文献
8.
9.
We present measurements of the orientation theta0(t) of the large-scale circulation (LSC) of turbulent Rayleigh-Bénard convection in cylindrical cells of aspect ratio 1. Theta0(t) undergoes irregular reorientations. It contains reorientation events by rotation through angles delta theta with a monotonically decreasing probability distribution p(delta theta), and by cessations (where the LSC stops temporarily) with a uniform p(delta theta). Reorientations have Poissonian statistics in time. The amplitude of the LSC and the magnitude of the azimuthal rotation rate have a negative correlation. 相似文献
10.
We used the time correlation of shadowgraph images to determine the angle Theta of the horizontal component of the plume velocity above (below) the center of the bottom (top) plate of a cylindrical Rayleigh-Bénard cell of aspect ratio Gamma identical with D/L=1 (D is the diameter and L approximately 87 mm is the height) in the Rayleigh-number range 7 x 10(7)=R=3 x 10(9) for a Prandtl number sigma=6. We expect that Theta gives the direction of the large-scale circulation. It oscillates time periodically. Near the top and bottom plates Theta(t) has the same frequency but is anticorrelated. 相似文献