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1.
2.
Let Hn be an n-dimensional Haar subspace of
and let Hn−1 be a Haar subspace of Hn of dimension n−1. In this note we show (Theorem 6) that if the norm of a minimal projection from Hn onto Hn−1 is greater than 1, then this projection is an interpolating projection. This is a surprising result in comparison with Cheney and Morris (J. Reine Angew. Math. 270 (1974) 61 (see also (Lecture Notes in Mathematics, Vol. 1449, Springer, Berlin, Heilderberg, New York, 1990, Corollary III.2.12, p. 104) which shows that there is no interpolating minimal projection from C[a,b] onto the space of polynomials of degree n, (n2). Moreover, this minimal projection is unique (Theorem 9). In particular, Theorem 6 holds for polynomial spaces, generalizing a result of Prophet [(J. Approx. Theory 85 (1996) 27), Theorem 2.1]. 相似文献
3.
Grzegorz Stachowiak 《Order》1988,5(3):257-259
The number of linear extensions among the orientations of a bipartite graph is maximum just if the orientation itself is bipartite, the natural one. 相似文献
4.
Wiosetek-Reske AM Wysocki S Bak GW 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):1172-1178
The absorption and fluorescence spectra of N-nonyl acridine orange are determined at room temperature (298 K) in cyclohexane, benzene, carbon tetrachloride, chloroform, chlorobenzene and dichloromethane. The ground state of dipole moment was obtained by impedance measurements using Guggenheim-Debeye's method. The experimental excited state dipole moment of N-nonyl acridine orange was determined using Bakhshiev's and Kawski-Chamma-Viallet's formulae and solvent polarity parameter proposed by Reichardt. These experimental results were completed with theoretical results using quantum chemical methods. The experimental (muexp=10.76 D) and theoretical (mucal=9.9 D) dipole moments in the ground and excited state (muexp*=14.56 D) were compared. 相似文献
5.
The surprising formation of C22H32N2S2 from the title compound 1 at 45°C involves the interaction of the basic adamantanethione S-methylide () with its acidic precursor , in the course of which the anion undergoes electrocyclic ring opening; the acid and base functions offer the clue to a prolific chemistry of the thiadiazoline and the thiocarbonyl ylide . 相似文献
6.
7.
A revision to Chemical Markup Language (CML) is presented as a XML Schema compliant form, modularized into nonchemical and chemical components. STMML contains generic concepts for numeric data and scientific units, while CMLCore retains most of the chemical functionality of the original CML 1.0 and extends it by adding handlers for chemical substances, extended bonding models and names. We propose extension via new namespaced components for chemical queries, reactions, spectra, and computational chemistry. The conformance with XML schemas allows much greater control over datatyping, document validation, and structure. 相似文献
8.
MNDO calculations of heats of formation, dipole moments, ionization potentials, and structures are reported for a wide range of compounds containing chlorine in its characteristic valence state (ClI) and one or more of the elements H, B, Be, C, N, O, and F. The calculated errors in the heats of formation and the dipole moments are not significantly greater than those previously reported for compounds containing no chlorine. First vertical ionization potentials were on average 0.95 eV too high. The ordering of higher cationic states was found to be correct, even for species such as Cl2O, Cl2, and HOCl, where ab initio–Koopmans' theorem calculations predict the incorrect ordering. The calculated energies and geometries of compounds such as CIF3 are qualitatively incorrect, probably because of the lack of 3d atomic orbitals in the orbital basis set. 相似文献
9.
We study arithmetical properties of homotopy groups of thel-adic completion of Quillen'sK-theory space of number field, with a view on the Dwyer-Friedlander comparison map into étaleK-theory. The relation of these groups toK-theory is a complete analogy to the relation of continuous étale cohomology to étale cohomology. We identify the torsion subgroup of the resulting
term with the subgroup of divisible elements inK
2n
(F). We prove that this
term is sent isomorphically into étaleK-theory, giving some further evidence for the Lichtenbaum-Quillen conjectures. 相似文献
10.
Renata Kolano? Teresa Borowiak Grzegorz Dutkiewicz 《Journal of Molecular Structure》2005,737(1):75-81
The X-ray and spectroscopic results clearly indicate that the (+)-2-thiono-17-oxosparteine (1) and (+)-2,17-ditihionosparteine (2) are conformationally rigid. In order to analyze deviations of lactam/thiolactam groups from planarity induced by ring constraints, the Dunitz-Winkler approach has been used. The lactam and thiolactam groups are close to planarity, only the lactam group in one of the two independent molecules of 1 is markedly non-planar. The bond angles in the thiolactam and lactam groups are highly diverse. Rings A and C adopt a distorted sofa conformation in both compounds. The distortions in the molecules of 2 as compared with those in the related monothiolactams correspond to the unusual chemical shifts of H5(eq), H5(ax) and H11, as well as to the extremely low J5ax-6 and extremely large J5eq-6 coupling constants. Also chemical shifts show a similar regularity being extremely high and low for C2 and C17, respectively. 相似文献