Copolymerization of N‐tert‐Butylacrylamide with Ethylene Glycol Dimethacrylate

N‐tert‐butylacrylamide (NtBA) was copolymerized with ethylene glycol dimethacrylate (EDMA) in butanone solution over a wide composition and conversion range, using dibenzoyl peroxide (Bz₂O₂) as a free‐radical initiator. The copolymer composition was determined from the nitrogen content. Using only low conversion (≤20%) collected for the copolymerization reactions, monomer reactivity ratios were estimated using the Kelen‐Tüdos graphical method and were found to be r₁=0.26 (NtBA) and r₂=7.05 (EDMA). In order to get a better insight into the mechanism of nanoporous copolymers of NtBA with EDMA preparation by thermal degradation of copolymers of N‐acryl‐N,N′‐di‐tert‐butylurea (A‐DitBuU) with EDMA, nonporous copolymers (model compound), of the same chemical structure and composition, were prepared by performing copolymerization of NtBA with EDMA up to the high conversion of 97–100%. Thermal behavior of nanoporous and nonporous copolymers of NtBA with EDMA was studied.     

Structural Differences Between Copolymers of Acryl‐ and Methacryl‐dicyclohexylurea with Ethylene Glycol Dimethacrylate and their Thermal Degradation Products

The present paper describes structural characteristics of crosslinked copolymers of acryl‐dicyclohexylurea (A‐DCU) and methacryl‐dicyclohexylurea (MA‐DCU) with ethylene glycole dimethacrylate (EDMA). Both copolymers decompose when heated at temperatures between 180–250°C under the separation cyclohexylisocyanate (C₆H₁₁NCO) yielding nanoporous copolymers of poly(A‐CHA‐co‐EDMA) and poly(MA‐CHA‐co‐EDMA). The comparison was also made between structural characteristics of crosslinked nanoporous copolymers of poly(A‐CHA‐co‐EDMA) and poly(MA‐CHA‐co‐EDMA) and nonporous crosslinked model compounds poly(A‐CHA‐co‐EDMA) and poly(MA‐CHA‐co‐EDMA).     

Circulation micro-ebulliometer for determination of pressure above mixtures containing solvent and non-volatile component

All-glass micro-ebulliometer with circulation of liquid phase has been constructed for determination of total pressure over solutions of polymers; charge of liquid phase is approximately 8 mL. Vapour pressure of pure toluene was measured to prove its proper functioning, and then pressure versus composition was determined for the polymer + toluene, + hexane, and + chloroform mixtures at different temperatures. Correlations of two data sets with use of the UNIQUAC equation were carried out as illustration of quality data.     

Local heat transfer from a hot plate to a water jet

Jet impingement boiling is very efficient in cooling of hot surfaces as a part of the impinging liquid evaporates. Because of its importance to many cooling procedures, investigations on basic mechanisms of jet impingement boiling heat transfer are needed. Until now, most of the experimental studies, carried out under steady-state conditions, used a heat flux controlled system and were limited by the critical heat flux (CHF). The present study focuses on steady-state experiments along the entire boiling curve for hot plate temperatures of up to 700°C. A test section has been built up simulating a hot plate. It is divided into 8 independently heated modules of 10 mm length to enable local heat transfer measurements. By means of temperature controlled systems for each module local steady-state experiments in the whole range between single phase heat transfer and film boiling are possible. By solving the two dimensional inverse heat conduction problem, the local heat flux and the corresponding wall temperature on the surface of each module can be computed. The measurements show important differences between boiling curves measured at the stagnation line and those obtained in the parallel flow region. At the stagnation line, the transition boiling regime is characterised by very high heat fluxes, extended to large wall superheats. Inversely, boiling curves in the parallel flow region are very near to classical ones obtained for forced convection boiling. The analysis of temperature fluctuations measured at a depth of 0.8 mm from the boiling surface enables some conclusions on the boiling mechanism in the different boiling regimes.     

Pearson-type I distribution function for polydisperse polymer systems. Molar mass distribution

This paper presents an attractive feature of the distribution function, which uses a relatively simple expression for approximating probability density. The Pearson-type I distribution function is used to represent the molar mass distribution (MMD) function for polymers for which the number average (M(n)), mass average (M(w)), z-average (M(z)), and (z+1)-average (M(z)(+1)) values are available. In continuation, the Pearson-type I distribution is applied as the model MMD function in which model parameters (M(n), M(w), M(z), and M(z)(+1)) are fitted from experimentally determined MMD. As the result, different molar mass averages are estimated with satisfactory agreement with experimental data.     

Phase behavior in copolymer blends of poly (p-chlorostyrene-co-o-chlorostyrene) and phenylsulfonylated poly (2,6-dimethyl-1,4-phenylene oxide)

The miscibility of random copolymers of o-chlorostyrene and p-chlorostyrene [P (oClSt-co-pClSt)] with partially phenylsulfonylated poly (2,6-dimethyl-1,4-phenylene oxide) (SPPO) copolymers has been studied, using differential scanning calorimetry (DSC) to establish T_g behavior. It already has been established that the isomeric effect of the chlorine substitution on miscibility is large. Thus the para-chloro-substituted styrenic homopolymer is miscible with all SPPOs containing more than ～ 5 mol % phenylsulfonylation, whereas the ortho-chloro-substituted homopolymer is immiscible with the entire range of SPPO copolymer compositions (and also with the respective homopolymers). As a result of this asymmetric behavior of the homopolymers, the width of the window of miscibility in blends now investigated containing copolymers with high pClSt content and SPPO is much greater than in the corresponding blends containing copolymers with large mole fraction of oClSt. These differences are reflected in the corresponding χ parameters calculated from analysis of the data. It was also found that the miscibility is temperature dependent and that the regime in the copolymer-copolymer composition plane shrank as the equilibrium temperature increased, results indicative of LCST behavior. © 1994 John Wiley & Sons, Inc.