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1.
Grange AH Genicola FA Sovocool GW 《Rapid communications in mass spectrometry : RCM》2002,16(24):2356-2369
Concentration factors of 1000 and more reveal dozens of compounds in extracts of water supplies. Library mass spectra for most of these compounds are not available, and alternative means of identification are needed. Determination of the elemental compositions of the ions in mass spectra makes feasible searches of commercial and chemical literature that often lead to compound identification. Instrumental capabilities that constrain the utility of a mass spectrometer for determining ion compositions for compounds that elute from a chromatographic column are scan speed, mass accuracy, linear dynamic range, and resolving power. Mass peak profiling from selected ion recording data (MPPSIRD) performed with a double-focusing mass spectrometer provides the best combination of these capabilities. This technique provides unique ion compositions for ions of higher mass from compounds eluting from a gas chromatograph than can be obtained by orthogonal acceleration time-of-flight (oa-TOF) or Fourier transform ion cyclotron resonance mass spectrometry. Multiple compositions are usually possible for an ion with a mass exceeding 150 Da within the error limits of the mass measurement. The correct composition is selected based on measured exact masses of the mass peak profiles resulting from isotopic ions higher in mass by 1 and 2 Da and accurate measurement of the summed abundances of these isotopic ions relative to the monoisotopic ion. A profile generation model (PGM) automatically determines which compositions are consistent with measured exact masses and relative abundances. The utility of oa-TOF and double-focusing mass spectrometry using ion composition elucidation (MPPSIRD plus the PGM) are considered for determining ion compositions of two compounds found in drinking water extracts and a third compound from a monitoring well at a landfill. Published in 2002 by John Wiley & Sons, Ltd. 相似文献
2.
Gadolinium‐Decorated Silica Microspheres as Redox‐Responsive MRI Probes for Applications in Cell Therapy Follow‐Up
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Dr. Monica Muñoz Úbeda Dr. Fabio Carniato Dr. Valeria Catanzaro Sergio Padovan Dr. Cristina Grange Dr. Stefano Porta Dr. Carla Carrera Prof. Lorenzo Tei Dr. Giuseppe Digilio 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(23):7716-7720
The redox microenvironment within a cell graft can be considered as an indicator to assess whether the graft is metabolically active or hypoxic. We present a redox‐responsive MRI probe based on porous silica microparticles whose surface has been decorated with a Gd‐chelate through a disulphide bridge. Such microparticles are designed to be interspersed with therapeutic cells within a biocompatible hydrogel. The onset of reducing conditions within the hydrogel is paralleled by an increased clearance of Gd, that can be detected by MRI. 相似文献
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G. J. Spühler K. J. Weingarten R. Grange L. Krainer M. Haiml V. Liverini M. Golling S. Schön U. Keller 《Applied physics. B, Lasers and optics》2005,81(1):27-32
We present two novel semiconductor saturable absorber mirror (SESAM) designs which can exhibit more than ten times lower saturation
fluence than classical SESAM devices. Design considerations and characterization data are presented. These devices are particularly
suited for passively mode-locked lasers with ultra-high repetition rates. 相似文献
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L. M. Gandía M. A. Vicente P. Oelker P. Grange A. Gil 《Reaction Kinetics and Catalysis Letters》1998,64(1):145-151
A Na-montmorillonite was intercalated with manganese- and samarium-manganese-aluminium solutions. The pillared montmorillonites
were characterized by X-ray diffraction and nitrogen adsorption. The presence of manganese and samarium-manganese citrates
in the intercalation process modify the distance between the clay sheets and the microporous structure of the pillared montmorillonites. 相似文献
8.
Aguilar-Arevalo AA Anderson CE Brice SJ Brown BC Bugel L Conrad JM Dharmapalan R Djurcic Z Fleming BT Ford R Garcia FG Garvey GT Mirabal J Grange J Green JA Imlay R Johnson RA Karagiorgi G Katori T Kobilarcik T Linden SK Louis WC Mahn KB Marsh W Mauger C Metcalf W Mills GB Moore CD Mousseau J Nelson RH Nguyen V Nienaber P Nowak JA Osmanov B Pavlovic Z Perevalov D Polly CC Ray H Roe BP Russell AD Schirato R Shaevitz MH Sorel M Spitz J Stancu I Stefanski RJ Tayloe R Tzanov M Van de Water RG 《Physical review letters》2010,105(18):181801
The MiniBooNE experiment at Fermilab reports results from a search for ˉν_{μ}→ˉν_{e} oscillations, using a data sample corresponding to 5.66×102? protons on target. An excess of 20.9±14.0 events is observed in the energy range 475相似文献
9.
This “in situ” and real time study is an approach to the role of matrix dislocations in the nucleation of the α or β phases in titanium single crystals. When the dislocations interact, forming tangles, subboundaries…, the residual stresses, present at the transformation temperature, trigger the new phase. If the dislocations are isolated at the transformation temperature they are destabilized by the large crystalline anisotropy resulting from the vibrational entropy dependence with the temperature. These dislocations disappear and do no act as preferential nucleation sites. 相似文献
10.
2-Butyl-4-(methylseleno)-1-[[2′-(1H-tetrazol-5-yl)-1,1′-biphenyl-4-yl]methyl]-1H-imidazole-5-carboxylic acid (4) and 2-butyl-4-(phenylseleno)-1-[[2′-(1H-tetrazol-5-yl)-1,1′-biphenyl-4-yl]methyl]-1H-imidazole-5-carboxylic acid (5) have been prepared and tested for AT1 receptor antagonist properties. Both compounds proved to be potent AT1 receptor antagonists, with pKb estimates indicating that these selenides are very effective at blocking AT1 receptor mediated responses. 相似文献