全文获取类型
收费全文 | 1148篇 |
免费 | 38篇 |
国内免费 | 5篇 |
专业分类
化学 | 743篇 |
晶体学 | 6篇 |
力学 | 34篇 |
数学 | 145篇 |
物理学 | 263篇 |
出版年
2023年 | 13篇 |
2022年 | 16篇 |
2021年 | 33篇 |
2020年 | 20篇 |
2019年 | 25篇 |
2018年 | 20篇 |
2017年 | 24篇 |
2016年 | 39篇 |
2015年 | 27篇 |
2014年 | 32篇 |
2013年 | 62篇 |
2012年 | 64篇 |
2011年 | 70篇 |
2010年 | 39篇 |
2009年 | 35篇 |
2008年 | 60篇 |
2007年 | 56篇 |
2006年 | 49篇 |
2005年 | 54篇 |
2004年 | 38篇 |
2003年 | 46篇 |
2002年 | 38篇 |
2001年 | 18篇 |
2000年 | 28篇 |
1999年 | 10篇 |
1998年 | 7篇 |
1997年 | 14篇 |
1996年 | 14篇 |
1995年 | 6篇 |
1994年 | 14篇 |
1993年 | 17篇 |
1992年 | 18篇 |
1991年 | 8篇 |
1990年 | 22篇 |
1989年 | 15篇 |
1988年 | 19篇 |
1987年 | 10篇 |
1986年 | 14篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1982年 | 10篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 9篇 |
1975年 | 4篇 |
1973年 | 6篇 |
排序方式: 共有1191条查询结果,搜索用时 13 毫秒
1.
The magnetic properties of existing amorphous iron based materials, i.e., Fe--metalloid, Fe--early transition metals and Fe--rare
earth alloys, are briefly discussed for some representative alloys. The spin orientation of amorphous Fe--metalloid alloys
has been determined by the angular dependence of hyperfine interactions. It is shown that in iron--early transition metals
ferromagnetic order is not long-ranged, but determined by magnetic clusters. The magnetic hyperfine field distributions of
Fe-rich iron--early transition metals consist of a high and a low field tail. The magnetic structure has been investigated
for two representative Fe--RE (RE = Er, Ce) amorphous alloys. For the first time, the magnetic coupling phenomenon in amorphous/crystalline
multilayers has been discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
2.
A. Sánchez-Lavega A. Salazar A. Ocariz L. Pottier E. Gomez L.M. Villar E. Macho 《Applied Physics A: Materials Science & Processing》1997,65(1):15-22
Received: 16 September 1996/Accepted: 6 January 1997 相似文献
3.
This study demonstrates the separation of active ingredients in acne formulations (salicylic acid, cloramphenicol and resorcinol in presence of azulene) by capillary zone electrophoresis. Factors affecting their separations were the buffer pH and concentration, applied voltage, sample preparation, and presence of additives. Optimun results were obtained with a 50 mM sodium tetraborate-50 mM sodium phosphate, pH 9.0. The carrier electrolyte gave baseline separation with good resolution, short migration times (<6 min), great reproducibility and accuracy. Calibration plots were linear over at least three orders of magnitude of analyte concentrations, the lower limits of detection being within the range 0.39-1.25 μg ml−1. The procedure was fast and reliable and commercial pharmaceuticals could be analysed without prior sample clean-up procedure. 相似文献
4.
Summary Measurements on sea surface films were conducted during five separate experimental periods in the following marine areas:
the Sicilian Channel, the Gulf of Maine (spring and fall periods), Bermuda, and the Pacific Ocean West of Southern California.
The measurements consisted in surface elevation sampling using an interferential microwave probe with frequency spectra evaluation.
Wave spectra were performed for both clean and film-covered sea surface conditions to determine the wave attenuation ratio
within the 2–20 Hz spectral range. The method is able to detect, chart and characterize sea surface films. Theoretical analyses
of the results yield several viscoelastic film parameters: the modulus of elasticity, the relaxation frequency and the maximum
of the damping ratio as a function of wave frequency. The analysed data are interpreted to infer film weathering effects,
surface concentration of film-forming constituents, and compactness of the organic sea surface film. 相似文献
5.
Soderstrom E McKenna JA Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(25):2980-2983
6.
Stewart C Zieminski A Blessing S Crittenden R Draper P Dzierba A Heinz R Krider J Marshall T Martin J Sambamurti A Smith P Sulanke T Gomez R Dauwe L Haggerty H Malamud E Nikolic M Hagopian S Abrams R Ares J Goldberg H Halliwell C Margulies S McLeod D Salminen A Solomon J Wu G Ellsworth R Goodman J Gupta S Yodh G Watts T Abramov V Antipov Y Baldin B Denisov S Glebov V Gorin Y Kryshkin V Petrukhin A Polovnikov S Sulyaev R 《Physical review D: Particles and fields》1990,42(5):1385-1395
7.
S. R. Grace 《Mathematische Nachrichten》1989,142(1):297-305
New theorems on the oscillatory and asymptotic behavior of solutions of the damped differential equations with deviating arguments of the form are established. 相似文献
8.
Loomis S. Chen Grace J. Chen Chirst Tamborski 《Journal of organometallic chemistry》1980,193(3):283-292
Experimental conditions have now been developed whereby o-bromophenyllithium(II) may be prepared in excellent yields and used as an organometallic intermediate for the synthesis of a variety of ortho bromo substituted phenyl compounds (o-BrC6H4X). THe thermal stability, decomposition products and reactions of II wre studied. REactions between II and a variety of substrates, e.g., CO2, dimethylformamide, fluorinated esters, hexafluorobenzene, and organosilicon chlorides were examined. 相似文献
9.
Sol-gel Cu//MgOSiO2 catalysts were prepared gelling tetraethoxysilane (TEOS), magnesium ethoxide and copper acetylacetonate at pH 3 and pH 9. The catalysts shown specific surface areas ca. 500 m2/g and 140 m2/g for pH 9 and pH 3 preparations respectively. Si(OH) and Si(OH)2 hydroxy groups were observed by MAS-RMN spectroscopy in both preparations. CO2-TPD and NH3-TPD desorption thermograms showed that acid and basic sites were formed on the catalysts surface. It has been found that the catalysts having the highest density of basic sites were the catalysts showing the highest activity for the CO oxidation. It is proposed that the catalytic activity depends of the relative Cu=1/Cu=2 stability given by the support acidity. 相似文献
10.
Peter Wipf Stefan Werner Grace H.C. Woo Corey R.J. Stephenson Maciej A.A. Walczak Claire M. Coleman Leslie A. Twining 《Tetrahedron》2005,61(48):11488-11500
The multi-component condensation of organozirconocene, aldimine and zinc carbenoid was applied to the stereoselective synthesis of cyclopropane amino acid derivatives. These compounds served as scaffolds for the preparation of a 46-member library. The C- and N-termini of the cyclopropane amino acid derivatives were diversified by condensations with ten amines and ten acylating agents, respectively. To improve yields and accelerate library synthesis, most products were prepared under microwave irradiation and purified by polymer-bound scavengers and SPE methodology. All compounds were analyzed by LC-MS and a representative selection was fully characterized. 相似文献