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1.
Time differential perturbed angular correlation measurements of the 133–482 keVγ-γ cascade of181Ta in Hf-doped YBa2Cu3O7−x
are presented. The181Hf precurser nuclei are incorporated into the sample by thermal neutron irradiation. Two quadrupole interaction frequencies
are observed in the as-irradiated sample:v
Q1=161±10 MHz with intensityf
1=75%, asymmetry parameterη
1=0.32 and damping parameter Λ1=0.42, andv
Q2=1108±40 MHz withf
2=25%,η
2=0.62, and Λ2=0.60. On annealing the sample in air at various temperaturesT
a and quenching to room temperature,f
1 remained nearly constant forT
a<600°C andv
Q1 for all annealing temperatures indicating that these are insensitive to oxygen stoichiometry. This frequency is interpreted
to be due to181Hf substitutingY sites. BeyondT
a=600°C,f
1 increased and reached a constant value of 90% forT
a=800°C. The value ofv
Q2 showed a slight variation between 1086 and 1160 MHz, whilef
2 remained nearly constant at 25% forT
a<600°C. This component is identified to be due to181Hf substituting Cu 1 sites in the Cu-O chains of YBCO. Above 600°Cv
Q2 decreased and reached a value of 808 MHz beyond 750°C. 相似文献
2.
Fragmentation patterns resulting from electron impact ionization of 3-(2′-hydroxyethyl)quinolin-2(1H)-one, three of its monosubstituted derivatives and four of its disubstituted derivatives were studied. The molecular ion of quinolinone-2-etbanol undergoes initial fragmentation with the loss of OH·, H2O, CO, ·CHO, CH2O, CH2OH·, CH2?CHOH and HCNO species. The [M – CHO]+ ion is tentatively suggested to have been formed by the expulsion of H· from the [M – CO]+· ion and the [M - CHO]+ peak may be considered as diagnostic of a 2-quinolone-3-ethanol. 相似文献
3.
A new and convenient synthesis of 2-isopropylfuro-(2,3-b)quinolines () from 3-(3-methylbut-1-enyl)-2-quinolones () is described. A neat synthesis of the alkaloids (±)-lunacrine (), (±)-lunasine () and (±)-demethoxylunacrine () is also reported. 相似文献
4.
[reaction: see text] A novel and powerful reagent system R(3)Al-R'(3)SiOTf for the one-pot alkylation-silylation reaction of epoxides was discovered, and the reactions of various epoxides with the new reagent system have been demonstrated to occur stereospecifically giving rise to the corresponding alkylation-silylation products in excellent yields. 相似文献
5.
Raquel Simancas Anand Chokkalingam Shanmugam P. Elangovan Zhendong Liu Tsuneji Sano Kenta Iyoki Toru Wakihara Tatsuya Okubo 《Chemical science》2021,12(22):7677
Zeolites have been successfully employed in many catalytic reactions of industrial relevance. The severe conditions required in some processes, where high temperatures are frequently combined with the presence of steam, highlight the need of considering the evolution of the catalyst structure during the reaction. This review attempts to summarize the recently developed strategies to improve the hydrothermal framework stability of zeolites.This review attempts to summarize the recently developed strategies to improve the hydrothermal framework stability of zeolites. 相似文献
6.
The influence of initial heat treatment on anomalous Cr precipitation within high temperature solubility region of the Fe–9Cr alloy has been investigated using positron lifetime studies. Air-quenched samples with pre-existing dislocations exhibited a distinct annealing stage in positron lifetime between 800 and 1100?K corresponding to Cr-precipitation. During this stage, Transmission Electron Microscopy showed fine precipitates of average size 4 nm, dispersed throughout the sample and from Energy-dispersive X-ray spectroscopy (EDS) analysis they are found to be Cr-enriched. The presence of dislocations is found to be responsible for Cr precipitation. 相似文献
7.
Manikandan Chitrarasu Govindaraj Senthilnathan Ganesan Kilivelu 《Journal of heterocyclic chemistry》2021,58(9):1749-1754
We have prepared substituted flexible dimeric pyridinium bromide using conventional and greener approach. Solvent-free solid phase (greener) approach is superior than the conventional owing to nontoxic, easy workup procedure, and 20 times lesser reaction time. Toxic organic solvents and column chromatography are avoided. Aldol condensation reaction is studied with various substituted aromatic aldehyde and compared with available recent literatures. Synthesized substituted flexible dimeric pyridinium salts acted as potential catalysts because of their better performance even in low concentration, recyclability, and activation of two molecules of aldehydes at the same time for aldol condensation reaction. 相似文献
8.
Shanmugam Kotteswaran Sundaramoorthy Kannadhasan Perumalsamy Ramasamy 《Journal of Solid State Electrochemistry》2021,25(7):1949-1958
Journal of Solid State Electrochemistry - The phenyl-conjugated oligoene dye 2-cyano3-(4-diphenylaminophenyl)prop-2-enoic acid (SKS) was synthesized by chemical method, and its structure was... 相似文献
9.
Lakshmanan Sivalingam Govindaraj Dharman Mahalakshmi K. Thirumurugan K. Ramalakshmi N. Antony S. Arul 《Structural chemistry》2021,32(4):1597-1609
Structural Chemistry - Chalcone derivatives (7a–k) have been synthesized and characterized by 1H-NMR, 13C-NMR, mass, and elemental analysis. The synthesized compounds 7a, 7d, and 7g have been... 相似文献
10.
Pitchiah Esakki Karthik Chinnaiah Jeyabharathi Shanmugam Senthil Kumar Kanala Lakshmi Narasimha Phani 《Journal of Solid State Electrochemistry》2013,17(12):3055-3061
It is shown that the gold surface is catalytically deactivated and smoothened upon removal of the Prussian blue (PB)–gold nanocomposite formed on the gold surface. Atomic force microscopy proves surface smoothening after PB removal. The voltammetric responses of Ru(NH3)6Cl3 on the smoothened surface remain unaffected, but the reactions that involve multistep and inner-sphere electron transfer are affected on the smoothened surface as exemplified by hydroquinone, ferrous oxalate redox reactions, and oxygen reduction. These effects are attributed to catalytic deactivation as a consequence of removal of the active sites. Figure
It is shown that the gold surface is catalytically deactivated and smoothened upon removal of the Prussian blue (PB)–gold nanocomposite formed on the gold surface. Atomic force microscopy proves surface smoothening after PB removal. The voltammetric responses of Ru(NH3)6.Cl3 on smoothened surface remain unaffected, but the reactions that involve multistep and inner-sphere electron transfer are affected on the smoothened surface as exemplified by hydroquinone, ferrous oxalate redox reactions, and oxygen reduction. These effects are attributed to catalytic deactivation as a consequence of removal of the active sites. Graphical abstract shows the Au surface smoothening as a consequence of Prussian blue-gold nanocomposite (Au-PB) formation and removal 相似文献