全文获取类型
收费全文 | 2807篇 |
免费 | 32篇 |
国内免费 | 8篇 |
专业分类
化学 | 2095篇 |
晶体学 | 3篇 |
力学 | 25篇 |
数学 | 281篇 |
物理学 | 443篇 |
出版年
2016年 | 30篇 |
2015年 | 32篇 |
2014年 | 43篇 |
2013年 | 60篇 |
2012年 | 60篇 |
2011年 | 67篇 |
2010年 | 44篇 |
2009年 | 28篇 |
2008年 | 52篇 |
2007年 | 88篇 |
2006年 | 50篇 |
2005年 | 44篇 |
2004年 | 71篇 |
2003年 | 43篇 |
2002年 | 61篇 |
2001年 | 44篇 |
2000年 | 48篇 |
1999年 | 31篇 |
1998年 | 36篇 |
1997年 | 28篇 |
1996年 | 29篇 |
1995年 | 40篇 |
1994年 | 36篇 |
1993年 | 31篇 |
1992年 | 33篇 |
1991年 | 31篇 |
1988年 | 43篇 |
1987年 | 35篇 |
1986年 | 37篇 |
1985年 | 53篇 |
1984年 | 41篇 |
1982年 | 29篇 |
1981年 | 42篇 |
1980年 | 27篇 |
1979年 | 32篇 |
1978年 | 36篇 |
1977年 | 41篇 |
1976年 | 35篇 |
1975年 | 31篇 |
1974年 | 37篇 |
1973年 | 27篇 |
1972年 | 36篇 |
1965年 | 43篇 |
1964年 | 94篇 |
1963年 | 127篇 |
1962年 | 161篇 |
1961年 | 148篇 |
1960年 | 143篇 |
1959年 | 26篇 |
1958年 | 45篇 |
排序方式: 共有2847条查询结果,搜索用时 0 毫秒
1.
2.
We study conditions on the matrix mask of a vector subdivision scheme ensuring that certain polynomial input vectors yield polynomial output again. The conditions are in terms of a recurrence formula for the vectors which determine the structure of polynomial input with this property. From this recurrence, we obtain an algorithm to determine polynomial input of maximal degree. The algorithm can be used in the design of masks to achieve a high order of polynomial reproduction. 相似文献
3.
Guido Pintacuda Andrei Kaikkonen Gottfried Otting 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,171(2):387-243
Paramagnetic metal ions with fast-relaxing electronic spin and anisotropic susceptibility tensor provide a rich source of structural information that can be derived from pseudo-contact shifts, residual dipolar couplings, dipole-dipole Curie spin cross-correlation, and paramagnetic relaxation enhancements. The present study draws attention to a cross-correlation effect between nuclear relaxation due to anisotropic chemical shielding (CSA) and due to the anisotropic dipolar shielding (DSA) caused by the electronic Curie spin. This CSA x DSA cross-correlation contribution seems to have been overlooked in previous interpretations of paramagnetic relaxation enhancements. It is shown to be sufficiently large to compromise the 1/r6 distance dependence usually assumed. The effect cannot experimentally be separated from auto-correlated DSA relaxation. It can increase or decrease the observed paramagnetic relaxation enhancement. Under certain conditions, the effect can dominate the entire paramagnetic relaxation, resulting in nuclear resonances narrower than in the absence of the paramagnetic center. CSAxDSA cross-correlation becomes important when paramagnetic relaxation is predominantly due to the Curie rather than the Solomon mechanism. Therefore the effect is most pronounced for relaxation by metal ions with large magnetic susceptibility and fast-relaxing electron spin. It most strongly affects paramagnetic enhancements of transverse relaxation in macromolecules and of longitudinal relaxation in small molecules. 相似文献
4.
Gottfried Mayer Vitali Vogel Bas G. G. Lohmeijer Jean‐Franois Gohy Jacomina A. Van Den Broek Winfried Haase Ulrich S. Schubert Dieter Schubert 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):4458-4465
Micelles prepared from amphiphilic block copolymers in which a poly(styrene) segment is connected to a poly(ethylene oxide) block via a bis‐(2,2′:6′,2″‐terpyridine‐ruthenium) complex have been intensely studied. In most cases, the micelle populations were found to be strongly heterogeneous in size because of massive micelle/micelle aggregation. In the study reported in this article we tried to improve the homogeneity of the micelle population. The variant preparation procedure developed, which is described here, was used to prepare two “protomer”‐type micelles: PS20‐[Ru]‐PEO70 and PS20‐[Ru]‐PEO375. The dropwise addition of water to a solution of the compounds in dimethylformamide was replaced by the controlled addition of water by a syringe pump. The resulting micelles were characterized by sedimentation velocity and sedimentation equilibrium analyses in an analytical ultracentrifuge and by transmission electron microscopy of negatively stained samples. Sedimentation analysis showed virtually unimodal size distributions, in contrast to the findings on micelles prepared previously. PS20‐[Ru]‐PEO70 micelles were found to have an average molar mass of 318,000 g/mol (corresponding to 53 protomers per micelle, which is distinctly less than after micelle preparation by the standard method) and an average hydrodynamic diameter (dh) of 18 nm. For PS20‐[Ru]‐PEO375 micelles, the corresponding values were M = 603,000 g/mol (31 protomers per micelle) and dh = 34 nm. The latter particles were found to be identical to the “equilibrium” micelles prepared in pure water. Both micelle types had a very narrow molar mass distribution but a much broader distribution of s values and thus of hydrodynamic diameters. This indicates a conformational heterogeneity that is stable on the time scale of sedimentation velocity analysis. The findings from electron microscopy were in disagreement with those from the sedimentation analysis both in average micelle diameter and in the width of the distributions, apparently because of imperfections in the staining procedure. The preparation procedure described also may be useful in micelle formation from other types of protomers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4458–4465, 2004 相似文献
5.
T. N. Mamedov V. N. Duginov A. V. Stoykov I. L. Chaplygin D. Herlach U. Zimmermann V. N. Gorelkin J. Major M. Schefzik 《JETP Letters》1998,68(1):64-70
The residual polarization of negative muons in crystal silicon samples with phosphorus (P: 1.6×1013 cm−3) and antimony (Sb: 2×1018 cm−3) impurities is investigated. The measurements are made in a 1000 G magnetic field oriented in a direction transverse to the
muon spin in the temperature range 4–300 K. The relaxation rate and shift of the precession frequency in the silicon sample
with the phosphorus impurity are measured more accurately than previously. It is found that in antimony-doped silicon the
acceptor center
μ
A1 at temperatures below 30 K can be in both ionized and neutral states. The experimental data are interpreted on the basis
of spin-lattice relaxation of the magnetic moment of an acceptor center, formation of acceptor-donor pairs, and recombination
of charge carriers at the acceptor. Preliminary measurements showed a nonzero residual polarization of negative muons in germanium.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 1, 61–66 (10 July 1998) 相似文献
6.
Alexander Zimmermann 《Algebras and Representation Theory》2004,7(1):19-34
In an earlier paper, Raphaël Rouquier and the author introduced the group of self-equivalences of a derived category. In the case of a Brauer tree algebra, we determined a nontrivial homomorphism of the Artin braid group to this group of self-equivalences. The class of Brauer tree algebras include blocks of finite group rings over a large enough field with cyclic defect groups. In the present paper we give an integral version of this homomorphism. Moreover, we identify some interesting arithmetic subgroups with natural groups of self-equivalences of the derived category. 相似文献
7.
The synthesis of a specific isotopomer, C6D4H(ortho)-H(ortho)D4C6 of biphenyl is reported. The intramolecular dipolar coupling of the protons leads to a well-resolved single-crystal proton
nuclear magnetic resonance (NMR) spectrum and allows one to study the dynamics of the phenyl rings in a unique way. At room
temperature and above, the most conspicuous dynamical mode consists of 180° ring flips. The present data together with previous
measurements of the total flip rate allow us to conclude that the rings flip almost exclusively independently of each other.
Between the incommensurate (IC) phase transition of biphenyl at 38 K andT=250 K, the prominent namical mode consists of oscillatory twists ϕ(t) of the two rings. The data allow us to infer the mean square, (φ2), of these twists. (φ2) is found to grow linearly withT for 50<T<200 K. From the slope of (φ2) vs.T the frequency (the wave number[(v)\tilde]\tilde v) is derived. The result is[(v)\tilde] = 20\tilde v = 20 cm−1. ForT<38 K, the spectra give direct evidence of the IC phase transition and its nature (stripelike rather than quiltlike). The
temperature dependence of the magnitude of the order parameter of the IC phase is obtained. 相似文献
8.
Bruno Zimmermann 《Monatshefte für Mathematik》2002,135(3):253-258
We give a list including all finite groups G which admit smooth orientation preserving actions on homology 3-spheres (arbitrary actions, i.e. possibly with fixed points;
if the action is free then the group G has periodic cohomology and the classification of such groups is well known). The main work in this direction is due to M.
Reni. In the present paper, we complete and extend his results for the case of nonsolvable groups G.
Received 19 March 2001; in revised form 15 September 2001 相似文献
9.
J. Walz S. B. Ross C. Zimmermann L. Ricci M. Prevedelli T. W. Hänsch 《Hyperfine Interactions》1996,100(1):133-144
Experiments with electrons and ions in a combined trap are reported. The unique capability to confine particles with opposite charge and very different mass simultaneously in the same spatial region makes the combined trap a promising device for future synthesis of antihydrogen. 相似文献
10.
The hyperfine structure of various absorption lines of molecular iodine with wavenumbers between 12980 and 13890 cm–1 has been resolved using Doppler-free polarization spectroscopy. The wavenumbers of theo-component of 17 rovibrational lines of I2 due to the transitionB
3
ou
+
–X1
g
+
with even rotational quantum numbers have been determined with an accuracy of 0.001 cm–1. A comparison of the centers of gravity of these 17 lines with the values of the iodine atlas of Gerstenkorn et al. yields a difference of
thus corroborating the data of the iodine atlas in the red region within limits of error. 相似文献