全文获取类型
收费全文 | 1985篇 |
免费 | 86篇 |
国内免费 | 6篇 |
专业分类
化学 | 1287篇 |
晶体学 | 19篇 |
力学 | 58篇 |
数学 | 286篇 |
物理学 | 427篇 |
出版年
2023年 | 24篇 |
2022年 | 44篇 |
2021年 | 49篇 |
2020年 | 37篇 |
2019年 | 42篇 |
2018年 | 34篇 |
2017年 | 25篇 |
2016年 | 72篇 |
2015年 | 59篇 |
2014年 | 67篇 |
2013年 | 121篇 |
2012年 | 131篇 |
2011年 | 130篇 |
2010年 | 85篇 |
2009年 | 111篇 |
2008年 | 108篇 |
2007年 | 131篇 |
2006年 | 104篇 |
2005年 | 95篇 |
2004年 | 70篇 |
2003年 | 51篇 |
2002年 | 71篇 |
2001年 | 47篇 |
2000年 | 57篇 |
1999年 | 33篇 |
1998年 | 19篇 |
1997年 | 26篇 |
1996年 | 23篇 |
1995年 | 20篇 |
1994年 | 9篇 |
1993年 | 13篇 |
1992年 | 20篇 |
1991年 | 17篇 |
1990年 | 18篇 |
1989年 | 16篇 |
1988年 | 16篇 |
1987年 | 13篇 |
1986年 | 12篇 |
1985年 | 10篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1974年 | 3篇 |
1935年 | 1篇 |
排序方式: 共有2077条查询结果,搜索用时 15 毫秒
1.
2.
Design and development of a two‐dimensional system based on hydrophilic and reversed‐phase liquid chromatography with on‐line sample treatment for the simultaneous separation of excreted xenobiotics and endogenous metabolites in urine 下载免费PDF全文
Diego García‐Gómez Encarnación Rodríguez‐Gonzalo Rita Carabias‐Martínez 《Biomedical chromatography : BMC》2015,29(8):1190-1196
In the present work we describe a two‐dimensional liquid chromatographic system (2D‐LC) with detection by mass spectrometry (MS) for the simultaneous separation of endogenous metabolites of clinical interest and excreted xenobiotics deriving from exposure to toxic compounds. The 2D‐LC system involves two orthogonal chromatographic modes, hydrophilic interaction liquid chromatography (HILIC) to separate polar endogenous metabolites and reversed‐phase (RP) chromatography to separate excreted xenobiotics of low and intermediate polarity. Additionally, the present proposal has the novelty of incorporating an on‐line sample treatment based on the use of restricted access materials (RAMs), which permits the direct injection of urine samples into the system. The work is focused on the instrumental coupling, studying all possible options and attempting to circumvent the problems of solvent incompatibility between the RAM device and the two chromatographic columns, HILIC and RP. The instrumental configuration developed, RAM‐HILIC‐RPLC‐MS/MS, allows the simultaneous assessment of urinary metabolites of clinical interest and excreted compounds derived from exposure to toxic agents with minimal sample manipulation. Thus, it may be of interest in areas such as occupational and environmental toxicology in order to explore the possible relationship between the two types of compounds. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
Brandão Pedro Francisco Ramos Rui Miguel Rodrigues José António 《Analytical and bioanalytical chemistry》2018,410(26):6873-6880
Analytical and Bioanalytical Chemistry - Formaldehyde is often applied in the industrial production of different products, such as textiles, insulation materials, or cosmetics, due to its... 相似文献
4.
A piecewise linearization method based on the linearization of nonlinear ordinary differential equations in small intervals, that provides piecewise analytical solutions in each interval and smooth solutions everywhere, is developed for the study of the limit cycles of smooth and non-smooth, conservative and non-conservative, nonlinear oscillators. It is shown that this method provides nonlinear maps for the displacement and velocity which depend on the previous values through the nonlinearity and its partial derivatives with respect to time, displacement and velocity, and yields non-standard finite difference formulae. It is also shown by means of five examples that the piecewise linearization method presented here is more robust and yields more accurate (in terms of displacement, energy and frequency) solutions than the harmonic balance procedure, the method of slowly varying amplitude and phase, and other non-standard finite difference equations. 相似文献
5.
A practical access to alkyl- and aryl-substituted (E)-2-(azidomethyl)alkenoates and related azido compounds from the corresponding allylic bromides in aqueous acetone is described. An alternative method to obtain the starting bromides based on heterogeneous catalysis under mild conditions was also investigated. 相似文献
6.
7.
Let a text of u characters over an alphabet of size σ be compressible to n phrases by the LZ78 algorithm. We show how to build a data structure based on the Ziv–Lempel trie, called the LZ-index, that takes 4nlog2n(1+o(1)) bits of space (that is, 4 times the entropy of the text for ergodic sources) and reports the R occurrences of a pattern of length m in worst case time O(m3logσ+(m+R)logn). We present a practical implementation of the LZ-index, which is faster than current alternatives when we take into consideration the time to report the positions or text contexts of the occurrences found. 相似文献
8.
We consider the problems of (1) longest common subsequence (LCS) of two given strings in the case where the first may be shifted by some constant (that is, transposed) to match the second, and (2) transposition-invariant text searching using indel distance. These problems have applications in music comparison and retrieval. We introduce two novel techniques to solve these problems efficiently. The first is based on the branch and bound method, the second on bit-parallelism. Our branch and bound algorithm computes the longest common transposition-invariant subsequence (LCTS) in time O((m2+loglogσ)logσ) in the best case and O((m2+logσ)σ) in the worst case, where m and σ, respectively, are the length of the strings and the size of the alphabet. On the other hand, we show that the same problem can be solved by using bit-parallelism and thus obtain a speedup of O(w/logm) over the classical algorithms, where the computer word has w bits. The advantage of this latter algorithm over the present bit-parallel ones is that it allows the use of more complex distances, including general integer weights. Since our branch and bound method is very flexible, it can be further improved by combining it with other efficient algorithms such as our novel bit-parallel algorithm. We experiment on several combination possibilities and discuss which are the best settings for each of those combinations. Our algorithms are easily extended to other musically relevant cases, such as δ-matching and polyphony (where there are several parallel texts to be considered). We also show how our bit-parallel algorithm is adapted to text searching and illustrate its effectiveness in complex cases where the only known competing method is the use of brute force. 相似文献
9.
Gonzalo Contreras 《Bulletin of the Brazilian Mathematical Society》1995,26(2):211-228
We find some estimates for the derivatives of equilibrium states of subshifts of finite type. We prove the differentiability (with respect to the potential) of integrals of certain discontinuous functions for the equilibrium state of a potential.research supported by CNPq, Brazil 相似文献
10.