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1.
P. Quevauviller M. Lachica E. Barahona A. Gomez G. Rauret A. Ure H. Muntau 《Fresenius' Journal of Analytical Chemistry》1998,360(5):505-511
Single extraction tests are commonly used to study the eco-toxicity and mobility of metals in soils, e.g. to assess the bioavailable
metal fraction (and thus to estimate the related phyto-toxic and nutritional deficiency effects) and the environmentally accessible
trace metals upon disposal of e.g. sediment on to a soil (e.g. contamination of ground waters). However, the lack of uniformity
in the different procedures does not allow the results to be compared worldwide nor the procedures to be validated. This paper
describes the interlaboratory testing of EDTA- and DTPA-extraction procedures for soil analysis, followed by the preparation
of a calcareous soil reference material (CRM 600), the homogeneity and stability studies and the analytical work performed
for the certification of the EDTA- and DTPA- extractable contents of some trace metals (following the standardized extraction
procedures).
Received: 21 May 1997 / Revised: 4 July 1997 / Accepted: 9 July 1997 相似文献
2.
This work describes the use of a dual-standard analysis approach termed the time-average ratio (TAR) in affinity capillary electrophoresis (ACE) to estimate binding constants of receptors to ligands. In this form of analysis the TAR is the migration time of the receptor divided by the average of the sum of the migration times of two non-interacting standards. This change in TAR as a function of the concentration of ligand yields a value for the binding constant. This concept is demonstrated using three model systems: carbonic anhydrase B (CAB, EC 4.2.1.1) and arylsulfonamides, vancomycin (Van) and ristocetin (Rist) from Streptomyces orientalis and Nocardia lurida, respectively, and d-Ala- d-Ala terminus peptides. Three ACE techniques are used to examine the three systems: standard ACE, flow-through partial-filling ACE (FTPFACE), and on-column derivatization coupled to ACE. The findings described here demonstrate that ACE data analyzed using the TAR form of analysis yield binding constants between receptors and ligands comparable to those estimated using other ACE forms of analysis. A comparison to three other forms of analysis is described. 相似文献
3.
4.
Lung A Stuart LM Bosted PE Andivahis L Alster J Arnold RG Chang CC Dietrich FS Dodge WR Gearhart R Gomez J Griffioen KA Hicks RS Hyde-Wright CE Keppel C Kuhn SE Lichtenstadt J Miskimen RA Peterson GA Petratos GG Rock SE Rokni SH Sakumoto WK Spengos M Swartz K Szalata Z Tao LH 《Physical review letters》1993,70(6):718-721
5.
L. Gomez D. Jacquemart N. Lacome J.-Y. Mandin 《Journal of Quantitative Spectroscopy & Radiative Transfer》2009,110(18):2102-2114
Absolute intensities of 414 lines are measured in eight bands of the 7.7 μm spectral region of the 12C2H2 molecule, with an average accuracy of 5%. Vibrational transition dipole moment squared values and empirical Herman–Wallis coefficients are obtained in order to model the rotational dependence of the transition dipole moment squared, except for some forbidden bands for which smoothed values are given. These data are used to calculate a line list for atmospheric or astrophysical applications. 相似文献
6.
R. Benbrik M. Gomez Bock S. Heinemeyer O. Stål G. Weiglein L. Zeune 《The European Physical Journal C - Particles and Fields》2012,72(10):1-23
We confront the discovery of a boson decaying into two photons, as reported recently by ATLAS and CMS, with the corresponding predictions in the Minimal Supersymmetric Standard Model (MSSM) and the Next-to-Minimal Supersymmetric Standard Model (NMSSM). We perform a scan over the relevant regions of parameter space in both models and evaluate the MSSM and NMSSM predictions for the dominant Higgs production channel and the photon–photon decay channel. Taking into account the experimental constraints from previous direct searches, flavor physics, electroweak measurements as well as theoretical considerations, we find that a Higgs signal in the two photon channel with a rate equal to, or above, the SM prediction is viable over the full mass range 123?M H ?127 GeV, both in the MSSM and the NMSSM. We find that besides the interpretation of a possible signal at about 125 GeV in terms of the lightest $\mathcal {CP}$ -even Higgs boson, both the MSSM and the NMSSM permit also a viable interpretation where an observed state at about 125 GeV would correspond to the second-lightest $\mathcal {CP}$ -even Higgs boson in the spectrum, which would be accompanied by another light Higgs with suppressed couplings to W and Z bosons. We find that a significant enhancement of the γγ rate, compatible with the signal strengths observed by ATLAS and CMS, is possible in both the MSSM and the NMSSM, and we analyse in detail different mechanisms in the two models that can give rise to such an enhancement. We briefly discuss also our predictions in the two models for the production and subsequent decay into two photons of a $\mathcal {CP}$ -odd Higgs boson. 相似文献
7.
E. Cruz-Zaragoza G. Kitis B. Torres Gomez G. S. Polymeris N. Tsirliganis 《辐射效应与固体损伤》2013,168(5):267-278
The mineral fraction from dehydrated nopal leaves (Opuntia ficus indica) belonging to the Cactaceae family was extracted and selected by sizes of 10 and 74 μm and exposed to 60Co gamma radiation at different doses in the range 70 Gy–20 kGy. The glow-curves from these polyminerals show a thermoluminescence (TL) band with one very intense peak at a temperature around 150 °C and a second one emerging in the high temperature region, moving in a large zone of temperature values according to the preparation used and the level of irradiation. The XRD analysis shows a composition of both biominerals as whewellite and weddellite and a mineral fraction as anorthoclase and quartz. The main TL characteristics of the polymineral content of the nopal was analyzed, i.e. the TL response at different doses and fading during storage at room temperature. The activation energy of the traps responsible for the TL emission was also investigated and a possible continuous distribution of traps is discussed. A review of the scientific literature shows that this is the first time that a TL study on nopal ionized by irradiation has been carried out. 相似文献
8.
Summary Measurements on sea surface films were conducted during five separate experimental periods in the following marine areas:
the Sicilian Channel, the Gulf of Maine (spring and fall periods), Bermuda, and the Pacific Ocean West of Southern California.
The measurements consisted in surface elevation sampling using an interferential microwave probe with frequency spectra evaluation.
Wave spectra were performed for both clean and film-covered sea surface conditions to determine the wave attenuation ratio
within the 2–20 Hz spectral range. The method is able to detect, chart and characterize sea surface films. Theoretical analyses
of the results yield several viscoelastic film parameters: the modulus of elasticity, the relaxation frequency and the maximum
of the damping ratio as a function of wave frequency. The analysed data are interpreted to infer film weathering effects,
surface concentration of film-forming constituents, and compactness of the organic sea surface film. 相似文献
9.
10.
S. Aubin J. A. Behr R. Collister V. V. Flambaum E. Gomez G. Gwinner K. P. Jackson D. Melconian L. A. Orozco M. R. Pearson D. Sheng G. D. Sprouse M. Tandecki J. Zhang Y. Zhao 《Hyperfine Interactions》2013,214(1-3):163-171
We present a method for measuring the nuclear anapole in a string of francium isotopes. The anapole is a parity non-conserving electromagnetic moment that enables parity-forbidden transitions between ground state hyperfine levels of an atom. The experiment is run by the FrPNC collaboration and relies on a beam of artificially-produced francium from the ISAC facility at TRIUMF. 相似文献