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1.
In spite of the higher reactivity of styrene with respect to ethene for the alternating copolymerization with carbon monoxide, catalyzed by chiral (dihydrooxazole)(phosphino)palladium complexes, ethene is preferentially (and randomly) enchained in terpolymerization experiments; enantioface selection for styrene is comparably high in both copolymerization and terpolymerization processes. 相似文献
2.
Anil Kumar PG Pregosin PS Schmid TM Consiglio G 《Magnetic resonance in chemistry : MRC》2004,42(9):795-800
Three new salts of Rh(I), [Rh(1,5-COD)(Biphemp)]X, Biphemp = (6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine), X = BF4-, 2a, PF6-, 2b, and CF3SO3-, 2c, were prepared and studied using PGSE diffusion, 1H-19F HOESY and inverse 103Rh (amongst other) NMR methods. Although the immediate coordination sphere of the cation does not sense the change in the anion, the PGSE diffusion and 1H-19F HOESY data suggest that, in addition to some ion pairing, each of the anions in 2 demonstrates selectivity in its approach towards the cation. 相似文献
3.
C. Birattari M. Bonardi M. C. Cantone S. Ciappellano P. Cortesi G. Testolin 《Journal of Radioanalytical and Nuclear Chemistry》1991,150(1):129-142
Three different cereal cultivated fields (rice, maize/wheat, wheat/barley) were selected and soil samples were collected in order to study the behaviour of the radiocesium deposited over the crops after the Chernobyl accident fall-out (April 1986) together with its distribution at different ground depths. For each field, soil samples were removed during the sowing (Oct–Nov '86), in Spring (Apr '87) and during the harvest time (Jun–Sept '87). The40K concentration and stable potassium content in soil was also evaluated by nuclear spectrometry and by atomic absorption spectrometry. Beside soil sample measurements, the cultivated cereals produced in the 1986 harvest (rice, maize, wheat) were analyzed to evaluate the deposited contamination, and in order to evaluate the contamination during the growth and naturation we also analyzed whole plants (roots, stalks, grains) of the cultivated cereals (rice, wheat, barley) in 1987. Results are presented and discussed. 相似文献
4.
Piero Pino Felix Oldani Giambattista Consiglio 《Journal of organometallic chemistry》1983,250(1):491-497
In the hydroformylation of ethylene with approximately equimolar H2/D2 mixtures and Rh4(CO)12 or Co2(CO)8 as the catalyst precursor about 50% of propionaldehyde-d1 was formed. The propionaldehyde-d0/d2 ratio was ~ 3 for rhodium and ~ 2.6 for the cobalt catalyst. On the basis of the results and assuming that there is no rapid M(H)2/M(D)2 scrambling, activation of hydrogen through M(H)2 or M(H)2(olefin) complexes can be excluded. 相似文献
5.
Dr. Giambattista Testolin Dr. Jana Richter Antje Ritter Dr. Hans Prochnow Prof. Dr. Jesko Köhnke Prof. Dr. Mark Brönstrup 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(54):e202201297
The rise of antibiotic resistance causes a serious health care problem, and its counterfeit demands novel, innovative concepts. The combination of photopharmacology, enabling a light-controlled reversible modulation of drug activity, with antibiotic drug design has led to first photoswitchable antibiotic compounds derived from established scaffolds. In this study, we converted cystobactamids, gyrase-inhibiting natural products with an oligoaryl scaffold and highly potent antibacterial activities, into photoswitchable agents by inserting azobenzene in the N-terminal part and/or an acylhydrazone moiety near the C-terminus, yielding twenty analogs that contain mono- as well as double-switches. Antibiotic and gyrase inhibition properties could be modulated 3.4-fold and 5-fold by light, respectively. Notably, the sensitivity of photoswitchable cystobactamids towards two known resistance factors, the peptidase AlbD and the scavenger protein AlbA, was light-dependent. While irradiation of an analog with an N-terminal azobenzene with 365 nm light led to less degradation by AlbD, the AlbA-mediated inactivation was induced. This provides a proof-of-principle that resistance towards photoswitchable antibiotics can be optically controlled. 相似文献
6.
Giambattista Marini 《manuscripta mathematica》1993,79(1):335-341
In this paper we will prove a criterion for hyperelliptic Jacobians. LetD be a translation invariant vector field on an indecompssable principally polarized abelian variety (i.p.p.a.v.) (X, Θ), letDΘ be the divisor of the sectionDΘ∈H
0 (Θ,O(Θ)|Θ). We have that (X, Θ) is the Jacobian of an hyperelliptic curve iff (Theorem 1) all the component ofDΘ are non reduced and the singular locus of Θ has dimension less thang-2.
We will prove our theorem by showing that under the above geometrical condition it is possible to construct a Kodomcev-Petviashvili
(K.P.) equation which is satisfied by the theta function corresponding to the principal polarization onX. 相似文献
7.
Giambattista Giacomin Eric Luçon Christophe Poquet 《Journal of Dynamics and Differential Equations》2014,26(2):333-367
We consider the (noisy) Kuramoto model, that is a population of $N$ oscillators, or rotators, with mean-field interaction. Each oscillator has its own randomly chosen natural frequency (quenched disorder) and it is stirred by Brownian motion. In the limit $N \rightarrow \infty $ this model is accurately described by a (deterministic) Fokker–Planck equation. We study this equation and obtain quantitatively sharp results in the limit of weak disorder. We show that, in general, even when the natural frequencies have zero mean the oscillators synchronize (for sufficiently strong interaction) around a common rotating phase, whose frequency is sharply estimated. We also establish the stability properties of these solutions (in fact, limit cycles). These results are obtained by identifying the stable hyperbolic manifold of stationary solutions of an associated non disordered model and by exploiting the robustness of hyperbolic structures under suitable perturbations. When the disorder distribution is symmetric the speed vanishes and there is a one parameter family of stationary solutions, as pointed out by Sakaguchi (Prog Theor Phys 79:39–46, 1988): in this case we provide more precise stability estimates. The methods we use apply beyond the Kuramoto model and we develop here the case of active rotator models, that is the case in which the dynamics of each rotator in absence of interaction and noise is not simply a rotation. 相似文献
8.
Simona Bronco Giambattista Consiglio Silvia Di Benedetto Matthias Fehr Felix Spindler Antonio Togni 《Helvetica chimica acta》1995,78(4):883-886
Cationic Pd-complexes modified by dicyclohexyl{(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyl}phosphine ( 1a ) give very active catalytic systems for the regioregular isotactic specific copolymerization of propene with CO. Other alk-1-enes also give stereoregular and regioregular copolymers, even if with lower productivity. The copolymers are isolated as poly(4-alkyl-tetrahydrofuran-2,2,5,5-tetrayl-2-oxy-2-methylenes) B in the solid state and give the isomeric poly(2-alkyl-1-oxopropane-1,3-diyls) A by dissolution in (CF3)2CHOH. Solid polymer A (R = Et) is formed back at least partially when the dissolved material is reprecipitated from MeOH. The use of the related (ferrocenyl)diphosphine ligands 1b ? e and 2 as the catalyst modifier shows that the presence of both elements of chirality and of large substituents on the P-atoms of the ligand is necessary to achieve good stereocontrol, and that the large difference in basicity between the two P-atoms is probably the reason for the good catalytic activity. 相似文献
9.
[(?) (R)-1,2-bis (Diphenylphosphino)-1-phenylethane]nickel (II) chloride was found to catalyze the asymmetric alkylation of some chiral and achiral allylic alcohols with Grignard reagents, leading to the formation of optically active olefins. Enantiomer discrimination of the substrate takes place in the alkylation of chiral allylic alcohols. 相似文献
10.
Giambattista Scarpi 《Meccanica》1969,4(3):225-233
Summary After a few basic remarks, equations of unsteady slow of second-order incompressible fluids are given for the axifymmetrical case. The solution is worked out to give the expression of velocity and discharge, when the hydraulic slope represents any periodic function of time; the average energy dissipated in a period is also calculated. Particularly, when the hydraulic slope reduces to the expression a sin t+b cos t only, the dependence of pressure on r is also given, and it is recognized and emphasized that some components of the stress tensor oscillate with a frequency which is twice the frequency of motion.
Sommario Dopo brevi richiami, si scrivono le equazioni del moto vario per un fluido incomprimibile del secondo ordine, nel caso di simmetria assiale. Viene trovata la soluzione, esprimendo la velocità e la portata, nel caso in cui la pendenza motrice sia una qualsiasi funzione periodica del tempo; si calcola anche l'energia dissipata mediamente in un periodo. Nel caso particolare in cui la pendenza motrice si riduca all'espressione a sin t+b cos t, si dà la dipendenza della pressione da r, riconoscendo e mettendo in evidenza che alcune componenti del tensore degli sforzi oscillano con frequenza doppia rispetto a quella del moto.相似文献