Thermodynamics of the evaporation of dimethylzinc, dimethylselenium, and their equimolecular solutions

Using data on the calorimetry of evaporation and the temperature dependence of vapor pressure, we establish that an equimolecular solution dimethylzinc-dimethylselenium acts as a single-component system in the temperature interval of 273?C346 K in the liquid phase and dissociates into its constituents in transitioning to the gas phase.     

Motexafin gadolinium reacts with ascorbate to produce reactive oxygen species

Motexafin gadolinium (MGd) oxidizes ascorbate, in neutral buffer and in cell culture, forming reactive oxygen species and a coordination polymer with oxalate.     

Organoantimony(V) cyanoximates: synthesis,spectra and crystal structures

A series of 25 new organoantimony(V) cyanoximates has been synthesized and studied using IR, visible, and NMR spectroscopy and X-ray analysis. Crystal structures were determined for compounds (C6H5)4Sb[ONC(CN)C(O)NH2] (1) and (C6H5)4Sb[ONC(CN)C(O)N(CH3)2] (2). Both complexes crystallized in the monoclinic space group P2(1)/c (Z = 4) with unit cell parameters (A, grad) of a = 14.921(3), b = 10.165(2), c = 17.571(7), beta = 113.26(6) for compound 1, and a = 16.415(4), b = 10.406(3), c = 17.152(3), beta = 17.152(3), beta = 117.79(2) for compound 2. For 5438 and 5056 independent reflections the refinement yielded R-factors 0.022 and 0.037 for the structures of 1 and 2, respectively. Cyanoxime anions are bound to the antimony(V) atoms in a monodentate fashion via the oxygen atoms of the oxime groups. The ligands adopt trans-anti configuration in these compounds. The coordination polyhedron in both complexes is a distorted trigonal bipyramid with the axial location of the cyanoxime ligand. A similar binding mode of other anions in synthesized organoantimony(V) complexes has been offered on the basis of the similarity of their IR spectra to those of the compounds whose structures were determined crystallographically. The exact assignment of vibrations involving the oxime group was carried out using synthesized 15N(53%), isotopomers.     

Drift motion of domain boundaries in garnet ferrites in an acoustic wave field

The drift motion of a 180° domain boundary in garnet ferrites with two nonequivalent sublattices is studied in an elastic stress field induced by an acoustic wave propagating in the domain boundary plane. The dependences of the drift velocity on the amplitude and polarization of the acoustic wave are obtained, and the drift motion conditions for a strip domain structure are determined.     

Dynamics of the intermediate state and domain walls in an external oscillating magnetic field

We study the dynamics of 90-degree domain walls in the intermediate state of antiferromagnets, the state being realized in a first-order spin-flop transition in an external magnetic field. We show that an additional oscillating external magnetic field leads to a drift in the domain walls and find the dependence of the drift velocity on the amplitude, frequency, and polarization of the oscillating field. Finally, we discuss the possibility of the domain structure drifting as a whole. Zh. éksp. Teor. Fiz. 112, 1374–1385 (October 1997)     

Cylindrical domain structure in metamagnets and its stability conditions

The possibility of the existence of a cylindrical magnetic domain structure near the first-order phase transition line is investigated theoretically in metamagnets, compounds with anisotropy energy substantially exceeding the exchange interaction energy. The domain structure of such compounds is related to the kinetics of the transition from the paramagnetic to the antiferromagnetic state. The static properties of isolated cylindrical magnetic domains and their equilibrium lattices are studied using an energetic approach. It is shown that for a low-temperature metamagnetic phase transition domains of the existence of a cylindrical domain structure, lattices and isolated cylindrical magnetic domains, abut, on the domain of plane-parallel domain structure existence from both sides. The features of their behavior are determined as a function of the magnitude of the external magnetic fields.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 84–88, March, 1988.The author is grateful to Yu. I. Gorobets for supporting the research and for useful remarks, and also to D. A. Yablonskii and I. M. Vitebskii for fruitful discussions.