排序方式: 共有44条查询结果,搜索用时 15 毫秒
1.
Grotjahn DB Van S Combs D Lev DA Schneider C Incarvito CD Lam KC Rossi G Rheingold AL Rideout M Meyer C Hernandez G Mejorado L 《Inorganic chemistry》2003,42(10):3347-3355
Inter- and intramolecular hydrogen bonding of an N-H group in pyrazole complexes was studied using ligands with two different groups at pyrazole C-3 and C-5. At C-5, groups such as methyl, i-propyl, phenyl, or tert-butyl were present. At C-3, side chains L-CH(2)- and L-CH(2)CH(2)- (L = thioether or phosphine) ensured formation of chelates to a cis-dichloropalladium(II) fragment through side-chain atom L and the pyrazole nitrogen closest to the side chain. The significance of the ligands is that by placing a ligating side chain on a ring carbon (C-3), rather than on a ring nitrogen, the ring nitrogen not bound to the metal and its attached proton are available for hydrogen bonding. As desired, seven chelate complexes examined by X-ray diffraction all showed intramolecular hydrogen bonding between the pyrazole N-H and a chloride ligand in the cis position. In addition, however, intermolecular hydrogen bonding could be controlled by the substituent at C-5: complexes with either a methyl at C-5 or no substituent there showed significant intermolecular hydrogen bonding interactions, which were completely avoided by placing a tert-butyl group at C-5. The acidity of two complexes in acetonitrile solutions was estimated to be closer to that of pyridinium ion than those of imidazolium or triethylammonium ions. 相似文献
2.
Rodrigues JA Abramovitch RA de Sousa JD Leiva GC 《The Journal of organic chemistry》2004,69(9):2920-2928
In preliminary communications, we reported the diastereoselective synthesis of cularine and sarcocapnine via the intramolecular ring closure of nitrenium and oxenium ions, a new highly diastereoselective reductive methylation with (+)-8-phenylmenthyl chloroacetate followed by reduction with sodium borohydride, and a facile entry to the isoquinoline precursors by aza-Wittig electrocyclic ring closure. We now report the full details of the syntheses of (+)-O-demethylcularine, (+)-cularine, (+)-sarcocapnidine, (+)-sarcocapnine, and (+)-crassifoline and describe different methods of synthesis of their precursors. 相似文献
3.
Armida Miranda-Riestra Rosa Estrada-Reyes Erandis D. Torres-Sanchez Silvia Carreo-García Genaro Gabriel Ortiz Gloria Benítez-King 《Molecules (Basel, Switzerland)》2022,27(22)
Melatonin, N-acetyl-5-hydroxytryptamine, is a hormone that synchronizes the internal environment with the photoperiod. It is synthesized in the pineal gland and greatly depends on the endogenous circadian clock located in the suprachiasmatic nucleus and the retina’s exposure to different light intensities. Among its most studied functions are the regulation of the waking-sleep rhythm and body temperature. Furthermore, melatonin has pleiotropic actions, which affect, for instance, the modulation of the immune and the cardiovascular systems, as well as the neuroprotection achieved by scavenging free radicals. Recent research has supported that melatonin contributes to neuronal survival, proliferation, and differentiation, such as dendritogenesis and axogenesis, and its processes are similar to those caused by Nerve Growth Factor, Brain-Derived Neurotrophic Factor, Neurotrophin-3, and Neurotrophin-4/5. Furthermore, this indolamine has apoptotic and anti-inflammatory actions in specific brain regions akin to those exerted by neurotrophic factors. This review presents evidence suggesting melatonin’s role as a neurotrophic factor, describes the signaling pathways involved in these processes, and, lastly, highlights the therapeutic implications involved. 相似文献
4.
Aline Bruna da Silva Juliano Marini Genaro Gelves Uttandaraman Sundararaj Rinaldo Gregório Jr. Rosario E.S. Bretas 《European Polymer Journal》2013
The objective of this work was to prepare novel conductive blends of poly(vinylidene fluoride) (PVDF) with polypyrrole (PPy) and to compare their performance with PVDF/multiwall carbon nanotube (MWCNT) composites and novel PVDF/PPy/MWCNT hybrid systems. All the compositions were prepared by melt mixing using a miniature mixer. The mixtures were characterized by Fourier transformed infrared (FTIR), wide angle X-ray diffraction (WAXD), thermogravimetric analyses (TGA), scanning and transmission electron microscopy (SEM and TEM, respectively) and volume electrical resistivity. For the binary PVDF/PPy and PVDF/MWCNT systems, percolation thresholds of 10 and 0.3 wt%, respectively, were found. In the hybrid systems, however, the percolation threshold for each filler was lower than in the binary systems, but the electrical conductivities were always much higher at all concentrations than the conductivities of the binary systems. Therefore, the addition of both fillers had a synergistic effect on the hybrid system conductivity, which was attributed to its morphology: the PPy increased the homogeneity of the MWCNT distribution and decreased the available free volume for the MWCNT; as a result the MWCNT rolled around the PPy particles bridging them through the PVDF matrix, increasing the quantum tunneling effect and thus, the electrical conductivity of the system. 相似文献
5.
We report the achievement of the first images to our knowledge obtained with a fractal zone plates (FraZPs). FraZPs are diffractive lenses characterized by the fractal structure of their foci. This property predicts an improved performance of FraZPs as image forming devices with an extended depth of field and predicts a reduced chromatic aberration under white-light illumination. These theoretical predictions are confirmed experimentally in this work. We show that the polychromatic modulation transfer function of a FraZP affected by defocus is about two times better than one corresponding to a Fresnel zone plate. 相似文献
6.
The present paper is concerned with the problem of weighted best simultaneous approximations in Banach spaces. The weighted best simultaneous approximations to sequences from S- and BS-suns in the Banach space are characterized in view of the Kolmogorov conditions. Applications are provided for weighted best simultaneous approximations from RS-sets and strict RS-sets. Our results obtained in the present paper extend and improve all earlier known results in this direction. 相似文献
7.
David Ariza-Ruiz Chong Li Genaro López-Acedo 《Journal of Mathematical Analysis and Applications》2014
We give a direct proof of Schauder's fixed point theorem in the setting of geodesic metric spaces, generalizing the classical Schauder's theorem and improving a recent version of this theorem in CAT(κ) spaces. As an application we prove an existence result for a variational inequality in the setting of CAT(κ) spaces. 相似文献
8.
In this work we establish existence of mild solutions for a class of abstract semi-linear functional differential equations of second order and we prove that the set consisting of the mild solutions for these problems is connected. 相似文献
9.
Bo Chen Fangyue Chen Junbiao Guan Genaro J. Mart ''{ i}nez 《Journal of Applied Analysis & Computation》2016,6(4):1164-1179
By introducing a sequence-block transformation and vector-block transformation, we explore the dynamical properties of hybrid cellular automation (HCA) and hybrid cellular automation with memory (HCAM) in the framework of symbolic dynamics. As the local evolution rules of HCA and HCAM are not-uniform, the new uniform cellular automata (CAs) with multiple states are constructed by specifical the block transformations. Furthermore, because the new CA rules are topologically conjugate with the originals, the complex dynamics of the HCA and HCAM rules can be investigated via the new CA rules. 相似文献
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