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排序方式: 共有122条查询结果,搜索用时 15 毫秒
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Richard Gawel Kazimierz Przybylski Massimo Viviani 《Journal of Thermal Analysis and Calorimetry》2014,116(2):895-903
The objective of this work is to analyse the chemical stability of BaCe0.85Y0.15O3?δ –Ce0.85Y0.15O2?δ (BCY15–YDC15) composite materials at 600 °C and to compare the aforementioned chemical stability with that of pure BCY15. The composite powders were obtained by mixing together powders of BCY15 and YDC15 in the following volume fractions: 90 % BCY15 + 10 % YDC15, 70 % BCY15 + 30 % YDC15, 30 % BCY15 + 70 % YDC15, 20 % BCY15 + 80 % YDC15 and 10 % BCY15 + 90 % YDC15. After that both powders and sintered samples of the BCY15 and the BCY15–YDC15 composites were saturated in two different atmospheres at 600 °C: CO2/H2O (3.1 mol% H2O) and N2/H2O (46.8 mol% H2O). The effects of the previously mentioned atmospheres on the physicochemical properties of the samples were investigated via differential thermal analysis (DTA) combined with thermogravimetric analysis (TG). Furthermore, mass spectrometry was used to analyse the chemical composition of the gases released from the samples during the DTA–TG heating process. The surface and cross-section morphology of the samples were examined by scanning electron microscopy. Moreover, the phase composition of each sample was studied via X-ray Diffraction. From the combined analysis, it can be concluded that the addition of YDC15 in the composite samples leads to an increase in resistance against the corrosive effects of CO2. Furthermore, it was determined that all samples maintain stability in the presence of H2O at 600 °C. 相似文献
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Michele Lo Giudice Giuseppe Varone Cosimo Ieracitano Nadia Mammone Giovanbattista Gaspare Tripodi Edoardo Ferlazzo Sara Gasparini Umberto Aguglia Francesco Carlo Morabito 《Entropy (Basel, Switzerland)》2022,24(1)
The differential diagnosis of epileptic seizures (ES) and psychogenic non-epileptic seizures (PNES) may be difficult, due to the lack of distinctive clinical features. The interictal electroencephalographic (EEG) signal may also be normal in patients with ES. Innovative diagnostic tools that exploit non-linear EEG analysis and deep learning (DL) could provide important support to physicians for clinical diagnosis. In this work, 18 patients with new-onset ES (12 males, 6 females) and 18 patients with video-recorded PNES (2 males, 16 females) with normal interictal EEG at visual inspection were enrolled. None of them was taking psychotropic drugs. A convolutional neural network (CNN) scheme using DL classification was designed to classify the two categories of subjects (ES vs. PNES). The proposed architecture performs an EEG time-frequency transformation and a classification step with a CNN. The CNN was able to classify the EEG recordings of subjects with ES vs. subjects with PNES with 94.4% accuracy. CNN provided high performance in the assigned binary classification when compared to standard learning algorithms (multi-layer perceptron, support vector machine, linear discriminant analysis and quadratic discriminant analysis). In order to interpret how the CNN achieved this performance, information theoretical analysis was carried out. Specifically, the permutation entropy (PE) of the feature maps was evaluated and compared in the two classes. The achieved results, although preliminary, encourage the use of these innovative techniques to support neurologists in early diagnoses. 相似文献
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Summary A method for interpolating between the (F)HNC and (F)PY approaches in order to take into account elementary contributions
has been presented in two preceding papers concerned with the properties of zero-temperature quantum fluids, described by
short-range correlated wave functions. In the present paper, both for Bose and for Fermi systems, the technique is extended
to the case in which the two-body radial distribution function contains a long-range tail, going asr
−4. The results obtained for the energy per particle and momentum distribution of liquid4He, polarized hydrogen and3He are presented in correspondence to variational wave functions containing only two-particle correlations.
Riassunto In due precedenti lavori è stata sviluppata una tecnica di interpolazione tra le approssimazioni (F)HNC e (F)PY per tenere conto dei cosiddetti contributi elementari nel calcolo delle proprietà dei fluidi quantistici a temperatura zero e descritti da funzioni d’onda con fattori di correlazione a corto raggio. Nel presente lavoro il metodo è esteso, per sistemi sia bosonici che fermionici, al caso in cui la funzione radiale di distribuzione contenga una coda con andamentor −4. Sono presentati i risultati ottenuti per l’energia per particella e la distribuzione di quantità di moto dell’4He liquido, dell’idrogeno polarizzato e dell’3He liquido, in corrispondenza a funzioni d’onda variazionali contenenti solo correlazioni di coppia.
Резюме В двух предыдущих работах был предложен метод интерполяции между (F)HNC и (F)PY подходами. В этих работах рассматривались свойства квантовых жидкостей при нулевой температуре, которые описываются волновыми функциями с короткодействующими корреляциями. В данной работе, для Бозеи Ферми-систем, предложенная тенхика обобщается на случай, когда двух-частичная радиальная функция распределения содержит длиннодействующий хвост, который спадает какr −4. Приводятся результаты для энергии на одну частицу и импульсное распределение для жидкого4He, поляризованного водорода и3H, причем соответствующие вариационные волновые функции содержат только двух-частичные корреляции.相似文献
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A three-dimensional numerical simulation has been performed to study the growth of Ge0.98Si0.02 by the Traveling Solvent Method. We attempted to suppress the buoyancy convection, in the Ge0.98Si0.02 melt zone, by applying axial and rotating magnetic fields. The effects of the applied magnetic field intensity, on the transport structures in the melt (flow and concentration fields, heat and mass transfer), have been investigated in detail. The steady-state full Navier–Stokes equations, as well as energy, mass species transport and continuity equations are numerically solved using the finite element method. By applying an axial magnetic field of various intensities (2, 10, and 22 mT), we found that as the axial magnetic field increases, the silicon distribution nearby the growth interface becomes more uniform. In the case of a rotating magnetic field, with different applied rotational speeds (2, 7 and 10 rpm), we found that such kind of magnetic field has a marked effect on the silicon concentration, which changes its shape from a convex one to a nearly flat shape as the magnetic field intensity increases. An alternative method to reduce or suppress buoyancy convection, in the melt zone, is the growing of the sample in a microgravity environment, with a gravity level of at least 10?4 the earth normal gravity level; in this case the results revealed smooth and almost perfect straight concentration contours, due to the buoyancy convection weakness. 相似文献
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We compute the infinitesimal deformations of two families of restricted simple modular Lie algebras of Cartan-type: the Witt–Jacobson and the Special Lie algebras. 相似文献
9.
Spectroscopic Properties of Amine‐substituted Analogues of Firefly Luciferin and Oxyluciferin
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Michio Kakiuchi Soichiro Ito Minoru Yamaji Vadim R. Viviani Shojiro Maki Takashi Hirano 《Photochemistry and photobiology》2017,93(2):486-494
Spectroscopic and photophysical properties of firefly luciferin and oxyluciferin analogues with an amine substituent (NH2, NHMe and NMe2) at the C6' position were studied based on absorption and fluorescence measurements. Their π‐electronic properties were investigated by DFT and TD‐DFT calculations. These compounds showed fluorescence solvatochromism with good quantum yields. An increase in the electron‐donating strength of the substituent led to the bathochromic shift of the fluorescence maximum. The fluorescence maxima of the luciferin analogues and the corresponding oxyluciferin analogues in a solvent were well correlated with each other. Based on the obtained data, the polarity of a luciferase active site was explained. As a result, the maximum wavelength of bioluminescence for a luciferin analogue was readily predicted by measuring the photoluminescence of the luciferin analogue in place of that of the corresponding oxyluciferin analogue. 相似文献
10.
I.B. Simanovskii A. Viviani F. Dubois J.-C. Legros 《The European physical journal. Special topics》2011,192(1):175-184
The nonlinear development of oscillatory instability under the joint action of buoyant and thermocapillary effects in a multilayer
system, is investigated. The nonlinear convective regimes are studied by the finite difference method. Two different types
of boundary conditions – periodic boundary conditions and rigid heat-insulated lateral walls, are considered. It is found
that in the case of periodic boundary conditions, the competition of both mechanisms of instability may lead to the development
of specific types of flow: buoyant-thermocapillary traveling wave and pulsating traveling wave. In the case of rigid heat-insulated
boundaries, various types of nonlinear flows – symmetric and asymmetric oscillations, have been found. 相似文献