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(S)-2,4-Dihydroxybutyl-4-hydroxybenzoate was prepared in an extremely simple and practical way with high enantiomeric excess (99% ee) using Jacobsen’s Hydrolytic Kinetic Resolution technique as a key step and source of chirality. 相似文献
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Chandrachood Pranav S. Jadhav Amol R. Garud Dinesh R. Deshpande Nirmala R. Puranik Vedavati G. Kashalkar Rajashree V. 《Research on Chemical Intermediates》2020,46(12):5219-5230
Research on Chemical Intermediates - A series of quinoxaline derivatives were efficiently synthesized by convenient and simple procedure in excellent yields using 1 wt.% of titanium silicate (TS-1)... 相似文献
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Trent D Lund Timothy W West Lilyan Y Tian Lihong H Bu Daniel L Simmons Kenneth DR Setchell Herman Adlercreutz Edwin D Lephart 《BMC neuroscience》2001,2(1):20-13
Background
In learning and memory tasks, requiring visual spatial memory (VSM), males exhibit superior performance to females (a difference attributed to the hormonal influence of estrogen). This study examined the influence of phytoestrogens (estrogen-like plant compounds) on VSM, utilizing radial arm-maze methods to examine varying aspects of memory. Additionally, brain phytoestrogen, calbindin (CALB), and cyclooxygenase-2 (COX-2) levels were determined. 相似文献4.
The first synthesis of 1,3-oxaselenepane derivatives by the reaction of aryl isoselenocyanates with 4-bromobutanol in the presence of sodium hydride in THF as a one-pot reaction is described. The Z/E isomerism for the exocyclic carbon-nitrogen double bond in the selenium heterocycles was observed for the first time. 相似文献
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We propose an iterative gradient descent algorithm for solving scenario-based Mean-CVaR portfolio selection problem. The algorithm is fast and does not require any LP solver. It also has efficiency advantage over the LP approach for large scenario size. 相似文献
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4-Alkyl-2-imino-1,3-oxaselenolanes were prepared in good yields with high regioselectivity under mild conditions by the reaction of selenocarbamates with I2 or NIS. The resulting 4-alkyl-2-imino-1,3-oxaselenolanes on dehydrohalogenation gave 4-alkylidene-2-imino-1,3-oxaselenolanes. The formation of the (Z)- or (E)-isomer of 4-alkylidene-2-imino-1,3-oxaselenolanes, strongly depends on the configuration of the double bond of O-allylselenocarbamates. 相似文献
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DR.G. Domairry A. Mohsenzadeh M. Famouri 《Communications in Nonlinear Science & Numerical Simulation》2009,14(1):85-95
In this paper Jeffery–Hamel flow has been studied and its nonlinear ordinary differential equation has been solved through homotopy analysis method (HAM). The obtained solution in comparison with the numerical ones represents a remarkable accuracy. The results also indicate that HAM can provide us with a convenient way to control and adjust the convergence region. 相似文献
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Selenapenams, selenacephems, and selenazepines were synthesized using a 2-(trimethylsilyl)ethyl (TSE) protection approach in an extremely simple way. TSE protection for selenium is used for the first time in the synthesis of selenium-containing beta-lactam. Novel intramolecular cycloaddition reaction of selenium with alkynes and allenes is used in the present synthesis. 相似文献