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1.
Different mass analysers [(quadrupole (Q), time-of-flight (TOF) and multicollector (MC) sector-field (SF)] of ions produced in an inductively coupled plasma were evaluated for the determination of lead isotope ratios in wine samples. A population of 20 wines of different origin including two reference wines from the EC Standards, Measurement and Testing Programme with concentrations varying between 7-140 mug Pb l(-1) was investigated. Wines were analyzed directly by Q ICP MS and MC ICP MS. The poor sensitivity of the TOF instrument, further aggravated by matrix signal suppression, did not allow the acquisition of data for wine samples that contained less than 50 mug l(-1) in the direct sample introduction mode. The separation and preconcentration of lead were therefore required. The precision obtained for the (206)Pb/(207)Pb and (208)Pb/(206)Pb were similar and equal to 0.14-2.7% for Q ICP MS, 0.04-0.17% for TOF ICP MS and 0.01-0.12% for MC ICP MS. The precision for (206)Pb/(204)Pb was 0.44-5.29, 0.15-1.7, 0.08-1.6%, respectively. On the level of accuracy, the data from TOF ICP MS and MC ICP MS were in good agreement. The accuracy of Q ICP MS data was judged satisfactory in comparison with the other techniques but their poor precision was a significant obstacle on the way of using these data for the determination of the geographic origin of wine. 相似文献
2.
Robert Faure Jean-Pierre Galy Emile-Jean Vincent Jos Elguero 《Journal of heterocyclic chemistry》1977,14(8):1299-1304
The substituent effects on azido/tetrazole equilibrium on a series of 2-substituted thiazoles, benzothiazoles, thiadiazoles, benzoxazoles and isoxazoles has been studied by proton magnetic resonance in two solvents (DMSO-d6 and deuteriochloroform). For thiazole an excellent Hammett relationship was found, both for the 4 and 5 positions. 相似文献
3.
A tin(II) squarate Sn2O(C4O4)(H2O) was synthesized by hydrothermal technique. It crystallizes in the monoclinic system, space group C2/m (no. 12) with lattice parameters a=12.7380(9) Å, b=7.9000(3) Å, c=8.3490(5) Å, β=121.975(3)°, V=712.69(7) Å3, Z=4. The crystal structure determined with an R=0.042 factor, consists of [(Sn4O10)(H2O)2] units connected from one another in the [101] and [010] directions via squarate groups to form layers separated by Sn(II) lone pairs. This compound presents the same remarkable structural arrangement as observed in the tin-oxo-fluoride Sn2[Sn2O2F4] inorganic compound with Sn(II) lone pairs E(1) and E(2) concentrated in large rectangular-shape tunnels running along [001] direction. 相似文献
4.
In this study, new biodegradable and biocompatible amphiphilic polymers were obtained by modifying the peripheral hydroxyl groups of branched polyethers and polyesters with organosilicon substituents. The structures of the synthesized polymers were confirmed by NMR and GPC. Organosilicon moieties of the polymers were formed by silatranes and trimethylsilyl blocks and displayed hydrophilic and hydrophobic properties, respectively. The effect of the ratio of hydrophilic to hydrophobic organosilicon structures on the surface activity and biological activity of macromolecules was studied, together with the effect on these activities of the macromolecules’ molecular weight and chemical structure. In particular, the critical micelle concentrations were determined, the effect of the structure of the polymers on their wetting with aqueous solutions on glass and parafilm was described, and the aggregation stability of emulsions was studied. Finally, the effect of the polymer structures on their antifungal activity and seed germination stimulation was examined. 相似文献
5.
J. Galy D. J. Hamilton C. Normand 《The European physical journal. Special topics》2009,175(1):147-152
In the last decade or so, an evolution in experimental relativistic laser-plasma physics has led to highly sophisticated lasers
which are now capable of generating ultra-short pulses and can be focused to intensities in excess of 1021 W cm-2. The laser interaction with solid or gas targets can generate collimated beams of highly energetic electrons, protons and
ions. These high-intensity laser systems, therefore, turn out to be versatile and powerful sources of radiation and high-energy
particles, without recourse to large-scale facilities such as nuclear reactors or particle accelerators. The potential to
induce various kinds of nuclear reactions with laser-induced radiation fields has been demonstrated at several laboratories
in recent years. The present paper lays out a comprehensive overview of nuclear reactions induced by high-intensity laser
matter interactions. Mechanisms for electron, proton and ion acceleration, in addition to secondary bremsstrahlung, positron
and neutron production, are addressed, with a focus on the types of nuclear reactions that are possible and potential applications.
Discussion of the extrapolation of these processes and applications to the next generation of table-top lasers under construction
is also presented. 相似文献
6.
J.?Magill H.?SchwoererEmail author F.?Ewald J.?Galy R.?Schenkel R.?Sauerbrey 《Applied physics. B, Lasers and optics》2003,77(4):387-390
We report the first successful laser-induced transmutation of 129I, one of the key radionuclides in the nuclear fuel cycle. 129I with a half-life of 15.7 million years is transmuted into 128I with a half-life of 25 min through a (, n) reaction using laser-generated Bremsstrahlung. The integral cross-section value for the (, n) reaction is determined. These experiments offer a new approach to studying transmutation reactions with neutral and charged particles without resource to nuclear reactors or particle accelerators. PACS 52.38.Ph; 25.20.Lj 相似文献
7.
8.
Patrick Rozier Laure Vendier Jean Galy 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(9):i111-i113
A single crystal of KVTeO5, potassium vanadium tellurite, has been grown. The present structure determination has been conducted together with the refinement of the NaVTeO5 homologue, sodium vanadium tellurite, for the sake of precise comparison. The network consists of [VTeO5]n ribbons built up by VO4 tetrahedra linking centrosymmetric Te2O6 groups and stacked along the [010] direction; the alkali cations are intercalated in between. The TeIV atom exhibits a typical one‐sided coordination number (CN) of 4, completed by a lone pair, which forms a distorted triangular bipyramid with the four O atoms. 相似文献
9.
R. Faure J. P. Galy G. Giusti E. J. Vincent J. Elguero 《Magnetic resonance in chemistry : MRC》1974,6(9):485-486
Azido-tetrazole equilibrium is observed in the case of a solution of tetrazolo [5,1-b] benzothiazole in CDCl3, using proton magnetic resonance at 250 MHz. Analysis of the spectra obtained yields the chemical shifts and the coupling constants of the two tautomeric forms. 相似文献
10.