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Nowadays much attention is being paid to the determination of trace amounts of noble metals in geological, industrial, biological and environmental samples. The most promising techniques, such as inductively coupled plasma atomic emission spectrometry (ICP-AES), inductively coupled plasma mass spectrometry (ICP-MS) and electrothermal atomic absorption spectrometry (ETAAS) are characterized by high sensitivity. However, the accurate determination of trace noble metals has been limited by numerous interferences generated from the presence of matrix elements. To decrease, or eliminate, these interferences, the sorption preconcentration of noble metals is often used prior to their instrumental detection. A great number of hyphenated methods of noble metal determination using sorption preconcentration have been developed. This review describes the basic types of available sorbents, preconcentration procedures and preparations of the sorbent to the subsequent determination of noble metals. The specific features of instrumental techniques and examples of ETAAS, FAAS, ICP-AES, ICP-MS determinations after the sorption preconcentration of noble metals are considered. The references cited here were selected mostly from the period 1996 - 2006. 相似文献
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A theoretical scheme of a new device consisting of a lensed fiber and a long period grating (LPG) imprinted in a special single mode gradient-index fiber (SSMGIF) is presented. The SSMGIF consists of the single mode uniform core and the graded-index cladding. The performance of the proposed device is based on specific properties of SSMGIF. For high efficiency coupling between number of cladding modes and co-propagating core mode in this special type of the fiber we can use a number of weak LPGs with the same amplitudes of the refractive index modulation and with almost the same lengths. This scheme provides higher coupling efficiency, relaxed longitudinal alignment tolerance, and smaller device size, than an identical scheme with the LPG imprinted in a step-index (SI) fiber. Two different types of fiber lenses (hemispherical and hyperbolic) are presented for comparison. 相似文献
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Solid-phase extraction (SPE) is an effective tool for the preconcentration of trace elements and their separation from various sample constituents. Octadecyl and other alkyl-bonded silica gels are most widely used for these purposes. The fundamentals of the SPE of inorganic ions are reviewed and compared with those of related techniques (liquid-liquid extraction and reversed-phase liquid chromatography). The extraction of ions in the form of chelate compounds, inorganic salts solvated by neutral reagents, and ion-pair compounds is considered. Numerous applications of SPE to the separation and preconcentration of different elements and their species, including on-line combinations with instrumental determination techniques, are described and tabulated. 相似文献
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Costantini G Marini Bettolo Marconi U Kalibaeva G Ciccotti G 《The Journal of chemical physics》2005,122(16):164505
We study a two-dimensional gas of inelastic smooth hard dimers. Since the collisions between dimers are dissipative, being characterized by a coefficient of restitution alpha<1, and no external driving force is present, the energy of the system decreases in time and no stationary state is achieved. However, the resulting nonequilibrium state of the system displays several interesting properties in close analogy with systems of inelastic hard spheres, whose relaxational dynamics has been thoroughly explored. We generalize to inelastic systems a recently method introduced [G. Ciccotti and G. Kalibaeva, J. Stat. Phys. 115, 701 (2004)] to study the dynamics of rigid elastic bodies made up of different spheres held together by rigid bonds. Each dimer consists of two hard disks of diameter d, whose centers are separated by a fixed distance a. By describing the rigid bonds by means of holonomic constraints and deriving the appropriate collision rules between dimers, we reduce the dynamics to a set of equations which can be solved by means of event-driven simulation. After deriving the algorithm we study the decay of the total kinetic energy, and of the ratio between the rotational and the translational kinetic energy of inelastic dimers. We show numerically that the celebrated Haff's homogeneous cooling law t(-2), describing how the kinetic energy of an inelastic hard-sphere system with a constant coefficient of restitution decreases in time, holds even in the case of these nonspherical particles. We fully characterize this homogeneous decay process in terms of appropriate decay constants and confirm numerically the scaling behavior of the velocity distributions. 相似文献
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Atomic cations (26), M+, have been shown to lie within a thermodynamic window for O-atom transport catalysis of the reduction of N2O by CO and have been checked for catalytic activity at room temperature with kinetic measurements using an inductively-coupled plasma/selected-ion flow tube (ICP/SIFT) tandem mass spectrometer. Only 10 of these 26 atomic cations were seen to be catalytic: Ca+, Fe+, Ge+, Sr+, Ba+, Os+, Ir+, Pt+, Eu+, and Yb+. The remaining 16 cations that lie in the thermodynamic window (Cr+, Mn+, Co+, Ni+, Cu+, Se+, Mo+, Ru+, Rh+, Sn+, Te+, Re+, Pb+, Bi+, Tm+, and Lu+) react too slowly at room temperature either in the formation of MO+ or in its reduction by CO. Many of these reactions are known to be spin forbidden and a few actually may lie outside the thermodynamic window. A new measure of efficiency is introduced for catalytic cycles that allows the discrimination between catalytic cations on the basis of the efficiencies of the two legs of the catalytic cycle. Also, a potential-energy landscape is computed for the reduction of N2O by CO catalyzed by Fe+(6D) that vividly illustrates the operation of an ionic catalyst. 相似文献
10.
Oleg V. Mikhailov Marina A. Kazymova Tatyana A. Shumilova Galina A. Chmutova Svetlana E. Solovieva 《Transition Metal Chemistry》2005,30(3):299-304
The complexing process proceeding in the NiII–thiocarbohydrazide (H2N–H–NC(=S)–NH–NH2)–propanone triple system in EtOH solution and nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix has been studied. It has been found that in the first case, template synthesis leading, as a minimum, to formation of three coordination compounds of NiII with (N,N,S,S)-donor tetradentate ligands having NiL1, NiL2 and NiL3compositions where L1 is 4,6,6-trimethyl-2,3,7,8-tetraazanonen-3-di(thiohydrazide)-1,9, L2 is 4,6,6,12-tetrametyl-1,9-dithio-2,3,7,8,10,11-hexaazatridekadien-3,11-hydrazide-1 and L3 is 2,8,10,10,16-pentamethyl-5,13-dithio-3,4,6,7,11,12,14,15-octaazaheptadekatrien-2,7,15 is observed, whereas in the gelatin-immobilized matrix, a complexing process in the system considered does not occur. 相似文献