Study of EPR, optical properties and electrical conductivity of vanadyl doped Bi2O3.PbO.B2O3 glasses

Heavy metal based oxide glasses having composition xBi(2)O(3).(0.30 - x)PbO.0.70B(2)O(3) have been prepared (0.00 < or = x < or = 0.15, mol%) containing 2.0mol% of V(2)O(5) by normal melt-quenching technique. Electron paramagnetic resonance (EPR), optical spectra and dc conductivity of these glasses have been studied. Spin Hamiltonian parameters (SHP) of VO(2+) ions, dipolar hyperfine parameter, P and Fermi contact interaction parameter, K, molecular orbital coefficients (alpha(2) and gamma(2)) and optical band gap have been calculated. It is observed that in these glasses, the tetragonal nature of V(4+)O(6) complex increases with Bi(2)O(3) content. Increase in Bi(2)O(3):PbO ratio results in the contraction of 3d(xy) orbit of the unpaired electron in the vanadium ion, and the SHP are dependent on the theoretical optical basicity, Lambda(th). In present glasses, the conductivity (activation energy) first decreases (increases) with increase in mol% of Bi(2)O(3) content upto x = 0.08 and then shows a maxima (minima) at x = 0.10 and then starts decreasing (increasing) upto x < or = 0.15 with mol% of Bi(2)O(3) content.     

Electron Paramagnetic Resonance,Optical Spectra and DC Conductivity Studies of Vanadyl Doped Bi2O3 · BaO · B2O3 Glasses

Glasses with composition xBi₂O₃ ·(0.30 - x)BaO · 0.70B₂O₃ have been prepared in the range (0.00 ≤ x ≤ 0.15) containing 2.0 mol% of V₂O₅. Electron paramagnetic resonance (EPR), optical transmission and absorption spectra and DC conductivity of these glasses have been studied. The spin Hamiltonian parameters (SHP) of VO²⁺ ions, dipolar hyperfine coupling parameter P, Fermi contact interaction parameter K, and molecular orbital coefficients (α² and γ²) have been calculated. The SHP arc related with the theoretical optical basicity. A_th. The position of the absorption edge and the values of the optical band gap have also been reported. The effect of addition of Bi₂O₃ on the DC conductivity has also been studied.     

Electron paramagnetic resonance, optical and electrical properties of vanadyl doped alkali germanoborate glasses

Glasses with composition xGeO₂.(0.30−x)M₂O.0.70B₂O₃ (M=Li, K) containing 2.0 mol% of V₂O₅ have been prepared in the range 0.00≤x≤0.15 by normal melt quenching method. Electron paramagnetic resonance (EPR), optical transmission and absorption spectra and dc conductivity of these glasses have been studied. Spin Hamiltonian parameters (SHPs) of VO²⁺ ions, dipolar hyperfine coupling parameter, P, Fermi contact interaction parameter, K and molecular orbital coefficients (α² and γ²) have been calculated. In GeO₂·Li₂O·B₂O₃ glasses there is no change in the tetragonality of the V⁴⁺O₆ complex and the size of 3d_xy orbit also remains unchanged with increase in GeO₂ content. In GeO₂·K₂O·B₂O₃ glasses, there is an increase in the tetragonality of the V⁴⁺O₆ complex and the 3d_xy orbit expands with increase in GeO₂ content. Values of the theoretical optical basicity, Λ_th, have also been reported. Optical band gap decreases with increase in GeO₂ content. The dc conductivity of these glasses decreases and the activation energy increases with increase in GeO₂:M₂O ratio.     

Coinage Metal Complexes with Di-tertiary-butyl Sulfide as Precursors with Ultra-Low Decomposition Temperature

We report here the synthesis of [Cu₂(TFA)₄(^tBu₂S)₂] ( 1 ), [Ag₄(TFA)₄(^tBu₂S)₄] ( 2 ) and [AuCl(^tBu₂S)] ( 3 ) (TFA=trifluoroacetate), which decompose in solution medium at ultra-low temperature (e. g., in boiling toluene) to afford phase-pure and highly crystalline Cu₉S₅, Ag₂S and metallic Au nanoparticles, respectively. The low decomposition temperature of these precursors is attributed to the facile decomposition mechanism in the di-tertiary-butyl sulfide ligand. These results are a significant step in the direction of establishing a general low-temperature strategy spanning a range of systems including thermodynamically metastable materials and incorporate them in technologies that are sensitive to the harsh conditions.     

Resonant decay of a Langmuir wave in the presence of dust grains in a cylindrical plasma

The resonant parametric decay of a Langmuir wave into a backward propagating Langmuir wave and an ion acoustic (IA) wave is studied in a cylindrical dusty plasma. The analysis shows that the frequency of the IA mode decreases with the parameter δ_c (where δ_c is the ratio of the ion density to the electron density) for negatively charged dust grains. The growth rate of the resonance decay instability (RDI) and the threshold required for its onset also decrease with δ_c and are strongly dependent on the electron to ion temperature ratio for both positively and negatively charged dust grains. The results obtained also illustrate the dependence of the threshold of the resonance decay instability (μ_th) on the plasma cylinder radius.